Geomorphic evolution of a storm-dominated carbonate ramp (c. 549 Ma), Nama Group, Namibia

The well-exposed Hoogland Member (c. 549 Ma) of the northern Nama Group (Kuibis Subgroup), Namibia, represents a storm-dominated carbonate ramp developed in a foreland basin of terminal Proterozoic age. The ramp displays facies gradients involving updip grainstones which pass downdip into broad, spatially extensive tracts of microbial laminites and finely laminated mudstones deposited above and below storm wave base. Trough cross-bedded, coarse grainstones are shown to transit downdip into finer-grained calcarenites, irregular microbial laminites and mottled laminites. Siliciclastic siltstones and shales were deposited further downdip. Platform growth was terminated through smothering by orogen-derived siliciclastic deposits. Ramp morphology was controlled by several different processes which acted across many orders of magnitude (millimetres to kilometres), including in situ growth of mats and reefs, scouring by wave-produced currents, and transport and infilling of coarse-grained carbonates and fine-grained carbonates and clastics. At the smallest scale, ‘roughening’ of the sea-floor through heterogeneous trapping and binding by microbial mats was balanced by smoothing of the sea-floor through accumulation of loose sediment to fill the topographic lows within the upward-propagating mat. At the next scale up, parasequence development involved roughening of the sea-floor through shoal growth and grainstone progradation, balanced by sea-floor smoothing through shale infilling of resulting downdip accommodation, as well as the metre-scale topographic depressions within the mosaic of shoal-water facies. At even larger (sequence/platform) scales, roughening of the sea-floor occurred through aggradation and progradation of thick carbonates, balanced by infilling of the foreland basin with orogen-derived siliciclastic sediments. At all scales a net balance was achieved between sea-floor roughening and sea-floor smoothing to maintain a more or less constant ramp profile

Organic molecules in the Sheepbed Mudstone, Gale Crater, Mars

The Sample Analysis at Mars (SAM) instrument on board the Mars Science Laboratory Curiosity rover is designed to conduct inorganic and organic chemical analyses of the atmosphere and the surface regolith and rocks to help evaluate the past and present habitability potential of Mars at Gale Crater. Central to this task is the development of an inventory of any organic molecules present to elucidate processes associated with their origin, diagenesis, concentration, and long-term preservation. This will guide the future search for biosignatures. Here we report the definitive identification of chlorobenzene (150–300 parts per billion by weight (ppbw)) and C_2 to C_4 dichloroalkanes (up to 70 ppbw) with the SAM gas chromatograph mass spectrometer (GCMS) and detection of chlorobenzene in the direct evolved gas analysis (EGA) mode, in multiple portions of the fines from the Cumberland drill hole in the Sheepbed mudstone at Yellowknife Bay. When combined with GCMS and EGA data from multiple scooped and drilled samples, blank runs, and supporting laboratory analog studies, the elevated levels of chlorobenzene and the dichloroalkanes cannot be solely explained by instrument background sources known to be present in SAM. We conclude that these chlorinated hydrocarbons are the reaction products of Martian chlorine and organic carbon derived from Martian sources (e.g., igneous, hydrothermal, atmospheric, or biological) or exogenous sources such as meteorites, comets, or interplanetary dust particles

Preliminary Investigations of Early Proterozoic western River and Burnside River Formations : Evidence For Foredeep Origin of Kilohigok Basin, District of Mackenzie

In the Kilohigok Basin, the Western River and Burnside River formations comprise three successively overlying tectono-stratigraphic sedimentary units of regional extent: a basal shallow water siliciclastic/carbonate platform, overlain by deepwater flysch, in turn overlain by shallow marine and fluvial molasse. This stratigraphy represents an initial stable shelf (passive margin?) whose outer, southerly edge rapidly subsided contemporaneous with arching and subaerial exposure of its interior. Shelf drowning represents the onset of foredeep subsidence subparallel to the trend of Thelon Tectonic Zone. Arching and subsidence were perpendicular to the tectonic transport direction of intrabasinal nappes. indicating that convergence and uplift a long Thelon Tectonic Zone were probably responsible for foredeep subsidence within Ki lohigok Basin. Following drowning, the platform was buried by deepwater deposits ( flysch); with progressive uplift and basin filling, the foredeep entered the molasse phase and fluvial sediments prograded towards the foreland. The foredeep model places constraints on the origin of Thelon Tectonic Zone and provides a more comprehensive understanding of the tectonic evolution of the Slave Province and its relation to the Wopmay Orogen

Controls on development and diversity of Early Archean stromatolites

The ≈3,450-million-year-old Strelley Pool Formation in Western Australia contains a reef-like assembly of laminated sedimentary accretion structures (stromatolites) that have macroscale characteristics suggestive of biological influence. However, direct microscale evidence of biology—namely, organic microbial remains or biosedimentary fabrics—has to date eluded discovery in the extensively-recrystallized rocks. Recently-identified outcrops with relatively good textural preservation record microscale evidence of primary sedimentary processes, including some that indicate probable microbial mat formation. Furthermore, we find relict fabrics and organic layers that covary with stromatolite morphology, linking morphologic diversity to changes in sedimentation, seafloor mineral precipitation, and inferred microbial mat development. Thus, the most direct and compelling signatures of life in the Strelley Pool Formation are those observed at the microscopic scale. By examining spatiotemporal changes in microscale characteristics it is possible not only to recognize the presence of probable microbial mats during stromatolite development, but also to infer aspects of the biological inputs to stromatolite morphogenesis. The persistence of an inferred biological signal through changing environmental circumstances and stromatolite types indicates that benthic microbial populations adapted to shifting environmental conditions in early oceans

Physicochemical properties of concentrated Martian surface waters

Understanding the processes controlling chemical sedimentation is an important step in deciphering paleoclimatic conditions from the rock records preserved on both Earth and Mars. Clear evidence for subaqueous sedimentation at Meridiani Planum, widespread saline mineral deposits in the Valles Marineris region, and the possible role of saline waters in forming recent geomorphologic features all underscore the need to understand the physical properties of highly concentrated solutions on Mars in addition to, and as a function of, their distinct chemistry. Using thermodynamic models predicting saline mineral solubility, we generate likely brine compositions ranging from bicarbonate-dominated to sulfate-dominated and predict their saline mineralogy. For each brine composition, we then estimate a number of thermal, transport, and colligative properties using established models that have been developed for highly concentrated multicomponent electrolyte solutions. The available experimental data and theoretical models that allow estimation of these physicochemical properties encompass, for the most part, much of the anticipated variation in chemistry for likely Martian brines. These estimates allow significant progress in building a detailed analysis of physical sedimentation at the ancient Martian surface and allow more accurate predictions of thermal behavior and the diffusive transport of matter through chemically distinct solutions under comparatively nonstandard conditions

Quantitative Paleobathymetry of Early Proterozoic (1.9 B.Y.) Continental Slope, Rocknest Formation, Wopmay Orogen, N.W.T., Canada

The Rocknest Formation is an early Proterozoic (1.9 b.y.) westward-facing, rimmed carbonate shelf that evolved from a ramp developed on quartzites of the underlying Odjick Formation. Shelf interior facies are cyclic peritidal dolomites; shelf edge facies are reefal stromatolitic boundstones and intraclast/ooid grainstones, and slope facies are turbidites, slope breccias, and shelf edge breccias. The carbonates are overlain by black shales and graywackes of the Recluse Group

Aspects of the Rocknest Formation, Asiak Thrust-fold Belt, Wopmay Orogen, District of Mackenzie

Field study of the Rocknest Formation during 1981 and 1982, and laboratory study during the fall of 1982 has produced several interesting findings which are summarized in this report. Topics are: 1) subdivision of Rocknest Formation into ten informal members, 2) Rocknest shelf cyclicity and paleogeography, 3) shelf-to- slope transitions, 4) paleoclimate, and 5) evidence of possible microbial remnants in stromatolite bioherms of the Odjick/Rocknest transition beds. Future fieldwork is outlined

Opportunity Mars Rover mission: Overview and selected results from Purgatory ripple to traverses to Endeavour crater

Opportunity has been traversing the Meridiani plains since 25 January 2004 (sol 1), acquiring numerous observations of the atmosphere, soils, and rocks. This paper provides an overview of key discoveries between sols 511 and 2300, complementing earlier papers covering results from the initial phases of the mission. Key new results include (1) atmospheric argon measurements that demonstrate the importance of atmospheric transport to and from the winter carbon dioxide polar ice caps; (2) observations showing that aeolian ripples covering the plains were generated by easterly winds during an epoch with enhanced Hadley cell circulation; (3) the discovery and characterization of cobbles and boulders that include iron and stony-iron meteorites and Martian impact ejecta; (4) measurements of wall rock strata within Erebus and Victoria craters that provide compelling evidence of formation by aeolian sand deposition, with local reworking within ephemeral lakes; (5) determination that the stratigraphy exposed in the walls of Victoria and Endurance craters show an enrichment of chlorine and depletion of magnesium and sulfur with increasing depth. This result implies that regional-scale aqueous alteration took place before formation of these craters. Most recently, Opportunity has been traversing toward the ancient Endeavour crater. Orbital data show that clay minerals are exposed on its rim. Hydrated sulfate minerals are exposed in plains rocks adjacent to the rim, unlike the surfaces of plains outcrops observed thus far by Opportunity. With continued mechanical health, Opportunity will reach terrains on and around Endeavour's rim that will be markedly different from anything examined to date

Reconstruction of eolian bed forms and paleocurrents from cross-bedded strata at Victoria Crater, Meridiani Planum, Mars

Outcrop exposures imaged by the Opportunity rover at Victoria Crater, a 750 m diameter crater in Meridiani Planum, are used to delineate sedimentary structures and further develop a dune-interdune depositional model for the region. The stratigraphy at Victoria Crater, observed during Opportunity's partial traverse of its rim, includes the best examples of meter-scale eolian cross bedding observed on Mars to date. The Cape St. Mary promontory, located at the southern end of the rim traverse, is characterized by meter-scale sets of trough cross bedding, suggesting northward migrating sinuous-crested bed forms. Cape St. Vincent, which is located at the opposite end of the traverse, shows tabular-planar stratification indicative of climbing bed forms with meter- to decameter-scale dune heights migrating southward. Promontories located between Cape St. Mary and Cape St. Vincent contain superposed stratigraphic units with northward and southward dipping beds separated by outcrop-scale bounding surfaces. These bounding surfaces are interpreted to be either reactivation and/or superposition surfaces in a complex erg sea. Any depositional model used to explain the bedding must conform to reversing northward and southward paleomigration directions and include multiple scales of bed forms. In addition to stratified outcrop, a bright diagenetic band is observed to overprint bedding and to lie on an equipotential parallel to the preimpact surface. Meter-scale cross bedding at Victoria Crater is similar to terrestrial eolian deposits and is interpreted as a dry dune field, comparable to Jurassic age eolian deposits in the western United States