37 research outputs found
The electrical current effect in phase separated La5/8-yPryCa3/8MnO3: Charge order melting vs. Joule heating
We have studied the effect of electric field on transport properties of the
prototypical phase separated manganite La5/8-yPryCa3/8MnO3 with y=0.34. Our
results show that the suggested image in which the charge ordered state is
melted by the appliance of an electric current and/or voltage has to be
revised. We were able to explain the observed resistivity drop in terms of an
artifact related to Joule heating and the particular hysteresis that the system
under study display, common to many other phase separated manganites.Comment: 2 figures. Accepted in J. Appl. Phy
Magnetoresistive memory in phase separated LaCaMnO
We have studied a non volatile memory effect in the mixed valent compound
LaCaMnO induced by magnetic field (H). In a previous work
[R.S. Freitas et al., Phys. Rev. B 65 (2002) 104403], it has been shown that
the response of this system upon application of H strongly depends on the
temperature range, related to three well differentiated regimes of phase
separation occurring below 220 K. In this work we compare memory capabilities
of the compound, determined following two different experimental procedures for
applying H, namely zero field cooling and field cooling the sample. These
results are analyzed and discussed within the scenario of phase separation.Comment: 4 pages, 2 figure
Magnetocaloric effect in manganites: metamagnetic transitions for magnetic refrigeration
We present a study of the magnetocaloric effect in La5/8-yPryCa3/8MnO3
(y=0.3) and Pr0.5Ca0.09Sr0.41MnO3 manganites. The low temperature state of both
ystems is the result of a competition between the antiferromagnetic and
ferromagnetic phases. The samples display magnetocaloric effect evidenced in an
adiabatic temperature change during a metamagnetic transition from an
antiferromagnetic to a ferromagnetic phase . As additional features,
La5/8-yPryCa3/8MnO3 exhibits phase separation characterized by the coexistence
of antiferromagnetic and ferromagnetic phases and Pr0.5Ca0.09Sr0.41MnO3
displays inverse magnetocaloric effect in which temperature decreases while
applying an external magnetic field. In both cases, a significant part of the
magnetocaloric effect appears from non-reversible processes. As the traditional
thermodynamic description of the effect usually deals with reversible
transitions, we developed an alternative way to calculate the adiabatic
temperature change in terms of the change of the relative ferromagnetic
fraction induced by magnetic field. To evaluate our model, we performed direct
measurement of the sample's adiabatic temperature change by means of a
differential thermal analysis. An excellent agreement has been obtained between
experimental and calculated data. These results show that metamagnetic
transition in manganites play an important role in the study of magnetic
refrigeration.Comment: Acepted to be published in Applied Physics Letter
Correlation between magnetic and transport properties of phase separated LaCaMnO
The effect of low magnetic fields on the magnetic and electrical transport
properties of polycrystalline samples of the phase separated compound
LaCaMnO is studied. The results are interpreted in the
framework of the field induced ferromagnetic fraction enlargement mechanism. A
fraction expansion coefficient af, which relates the ferromagnetic fraction f
with the applied field H, was obtained. A phenomenological model to understand
the enlargement mechanism is worked out.Comment: 3 pages, 3 figures, presented at the Fifth LAW-MMM, to appear in
Physica B, Minor change
Thermodynamic modeling of phase separation in manganites
We present a phenomenological model based on the thermodynamics of the phase
separated state of manganites, accounting for its static and dynamic
properties. Through calorimetric measurements on LaPrCaMnO the low temperature free energies of the coexisting
ferromagnetic and charge ordered phases are evaluated. The phase separated
state is modeled by free energy densities uniformly spread over the sample
volume. The calculations contemplate the out of equilibrium features of the
coexisting phase regime, to allow a comparison between magnetic measurements
and the predictions of the model. A phase diagram including the static and
dynamic properties of the system is constructed, showing the existence of
blocked and unblocked regimes which are characteristics of the phase separated
state in manganites.Comment: 7 pages, 5 figures, Submitted to Phys. Rev.
Low temperature irreversibility induced by thermal cycles on two prototypical phase separated manganites
We have studied the effect of irreversibility induced by repeated thermal
cycles on the electric transport and magnetization of polycrystalline samples
of La0.5Ca0.5MnO3 and La0.325Pr0.3Ca0.375MnO3. An increase of the resistivity
and a decrease of the magnetization at different temperature ranges after
cycling is obtained in the temperature range between 300 K and 30 K. Both
compounds are known to exhibit intrinsic submicrometric coexistence of phases
and undergo a sequence of phase transitions related to structural changes.
Changes induced by thermal cycling can be partially inhibited by applying
magnetic field and hydrostatic pressure.
Our results suggest that the growth and coexistence of phases with different
structures gives rise to microstructural tracks and strain accommodation,
producing the observed irreversibility. Irrespective of the actual ground state
of each compound, the effect of thermal cycling is towards an increase of the
amount of the insulating phase in both compounds.Comment: to appear in Journal of Alloys and Compounds (2003
Reversible switching of room temperature ferromagnetism in CeO2-Co nanoparticles
We investigated the reversible ferromagnetic (FM) behavior of pure and Co
doped CeO2 nanopowders. The as-sintered samples displayed an increasing
paramagnetic contribution upon Co doping. Room temperature FM is obtained
simply by performing thermal treatments in vacuum at temperatures as low as
500^{\circ}C and it can be switched off by performing thermal treatments in
oxidizing conditions. The FM contribution is enhanced as we increase the time
of the thermal treatment in vacuum. Those systematic experiments establish a
direct relation between ferromagnetism and oxygen vacancies and open a path for
developing materials with tailored properties.Comment: 20 pages, 3 figures; Applied Physics Letters Vol. 100, Issue 17,
APR201
A Real Space Description of Field Induced Melting in the Charge Ordered Manganites: II. the Disordered Case
We study the effect of A site disorder on magnetic field induced melting of
charge order (CO) in half doped manganites using a Monte-Carlo technique.
Strong A-site disorder destroys CO even without an applied field. At moderate
disorder, the zero field CO state survives but has several intriguing features
in its field response. Our spatially resolved results track the broadening of
the field melting transition due to disorder and explain the unusual dependence
of the melting scales on bandwidth and disorder. In combination with our
companion paper on field melting of charge order in clean systems we provide an
unified understanding of CO melting across all half doped manganites.Comment: 9 pages, pdflatex, 10 embedded png fig
A Real Space Description of Magnetic Field Induced Melting in the Charge Ordered Manganites: I. The Clean Limit
We study the melting of charge order in the half doped manganites using a
model that incorporates double exchange, antiferromagnetic superexchange, and
Jahn-Teller coupling between electrons and phonons. We primarily use a real
space Monte Carlo technique to study the phase diagram in terms of applied
field and temperature , exploring the melting of charge order with
increasing and its recovery on decreasing . We observe hysteresis in
this response, and discover that the `field melted' high conductance state can
be spatially inhomogeneous even without extrinsic disorder. The hysteretic
response plays out in the background of field driven equilibrium phase
separation. Our results, exploring , , and the electronic parameter
space, are backed up by analysis of simpler limiting cases and a Landau
framework for the field response. This paper focuses on our results in the
`clean' systems, a companion paper studies the effect of cation disorder on the
melting phenomena.Comment: 16 pages, pdflatex, 11 png fig