Bentonite mechanical evolution – experimental work for the support of model development and validation

The objectives of the Beacon experimental studies are to provide input data and parameters for development and validation of models and to reduce uncertainties about conditions and phenomena influencing bentonite homogenisation. Both the homogenisation of an initially inhomogeneous bentonite system and the persistence or development of inhomogeneities in the bentonite system under various mechanical and hydraulic conditions are investigated. Eight experiment teams perform tests involving different bentonite materials and different hydraulic and mechanical boundary conditions. The experiments performed within Beacon address the hydro-mechanical behaviour of macroscopically homogeneous bentonite materials, (the influence of initial granulometry and of hydro-mechanical paths on the final properties of bentonite, constant load and constant volume tests on the Czech Cerny vrch bentonite), the issue of swelling into a limited void (experiments performed in constant volume cells partially filled with bentonite, at different scales and with different emphases), binary mixtures or artificial inhomogeneities (experiments using bentonite block/pellet or pellet/powder mixtures, and the influence of the degree of saturation on the shearing behaviour at a bentonite – steel interface. This report is the first Beacon WP4 deliverable on experimental work and presents the status at Beacon mid-term

Experimental investigation on Malaysian kaolin under monotonic and cyclic loading: inspection of undrained Miner’s rule and drained cyclic preloading

The results of an experimental investigation on Malaysian kaolin under monotonic and cyclic loading are presented. In the tests, a wide range of initial conditions was varied in order to investigate their influence on the mechanical behavior of the kaolin. The response under monotonic loading was analyzed by means of undrained monotonic triaxial tests with different initial mean effective pressures and overconsolidation ratios. The experimental plan under cyclic loading includes an oedometer test with multiple unloading-reloading cycles and twenty-one undrained cyclic triaxial tests with either isotropic or anisotropic consolidation. In the latter tests, the influence of the initial stress ratio, deviatoric stress amplitude, drained cyclic preloading and sequence of packages of cycles with different deviatoric stress amplitudes has been investigated. The experimental results suggest that the variation of the aforementioned test conditions leads to remarkable changes in the accumulation rates of pore water pressure and strains. In addition, it was found that the so-called Miner’s rule (independence of accumulated strains on loading sequence) is not valid under undrained cyclic conditions. A modified Stewart’s approach was proposed for the estimation of the accumulated pore water pressure and strains on undrained cyclic tests with packages of cycles with different deviatoric stress amplitudes, demonstrating that constitutive models developed using single-magnitude loading packages can be used in simulations of problems with variable cyclic loading magnitude

The influence of cyclic preloadings on cyclic response of Zbraslav sand

This article presents a comprehensive experimental investigation on Zbraslav sand under monotonic and cyclic loading. Initially, the material response at large strains was investigated by means of undrained monotonic triaxial tests with different initial mean effective stresses and relative densities. A set of oedometric compression tests with multiple unloading–reloading cycles and different initial relative densities was as well included to evaluate the material compressibility. In addition, several undrained cyclic triaxial tests were performed and analyzed under a wide range of initial conditions. In the aforementioned tests, the undrained cyclic resistance was investigated considering different types of drained or undrained cyclic preloadings and reconsolidation stages. The experimental results suggested that drained cyclic preloadings remarkably modified the subsequent rate of pore water pressure accumulation and increased the number of cycles to reach the defined failure criterion without affecting the stress–strain response. On the other hand, undrained cyclic preloadings presented a threshold which separated positive and negative effects in the subsequent undrained cyclic resistance. A comparison of the undrained cyclic resistance variation depending on the number of drained or undrained cyclic preloadings was also included

Adsorption of ammonium, nitrate, and phosphate on hydrochars and biochars

Biochar (BC) and hydrochar (HC) have attracted considerable attention owing to their versatile characteristics and proven effectiveness in diverse technical fields. Solid BC is generated as a result of the dry carbonisation process of pyrolysis, in contrast to the slurry HC, which is produced during the hydrothermal carbonisation process. In this study, we evaluated the adsorption potential of two hydrochar samples (HCs) and three biochar samples (BCs) produced from sugar cane bagasse. The adsorption capacity of these samples was tested for ammonium, nitrate, and phosphate ions under various conditions. The BCs and HCs were subjected to characterisation using a CHNS/O analyser, the zeta potential, and Fourier transform infrared (FTIR). Elevating the pyrolysis temperature of the biochar resulted in changes in the fixed carbon and ash contents, while the volatile matter and H/C and O/C atomic ratios decreased. As the residence time increased, the H/C ratio and volatile matter content of the hydrochars (HCs) decreased. However, the fixed carbon content, ash content, and O/C and C/N ratios exhibited an increase. Thermodynamics, adsorption isotherms, and pH were also taken into consideration. The FTIR spectra analysis indicated that the carboxyl and ester functional groups present in both the BCs and HCs displayed reduced peak intensities subsequent to the adsorption of the three ions. While the adsorption was exothermic, we noticed that the adsorption capacity increased with temperature. The results indicate that sorption was homogenous across all binding sites, as evidenced by the optimal fit to the Langmuir isotherm. The research findings indicate that the adsorption capacity of various BC and HC adsorbents is significantly influenced by the surface area of the adsorbents in the case of nitrate and phosphate, but in the case of ammonia, adsorption is dictated by the functional polar groups present on the adsorbent surface.</p