Metodologia U-PB em zircão com o uso de LAM-MC-ICPMS

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Idade U-Pb e Geoquímica do Traqui-Andesito Toleítico de Gouveia (MG) Comparadas com Rochas Básicas Toleíticas Regionais Pedro Lessa e Formiga: Fragmentos de uma Large Igneous Province (LIP) Toniana

Em Gouveia (MG), uma rocha subvulcânica traqui-andesítica toleítica de alto-K, guardando fenocristais de plagioclásio e sanidina e matriz também rica em feldspatos, com biotita, epidoto magmático e quartzo, aflora na forma de corpos irregulares e diques subverticalizados. A idade U-Pb de 938,5 +/- 4,5 Ma encontrada para o traqui-andesito de Gouveia é praticamente a mesma das rochas metabásicas da suíte Pedro Lessa (933 +/- 20 Ma) e dos diques Formiga (940 +/- 50 Ma), apontando para o agrupamento de todas essas rochas em um mesmo evento magmático. O tratamento conjunto da geoquímica da rocha traqui-andesítica com a das rochas regionais toleíticas Pedro Lessa e Formiga, revela cogeneticidade entre estes litotipos. O magma basáltico gerador destas rochas, com assinatura OIB (típica de pluma), é de origem provável da fusão parcial de um peridotito portador de granada, teria passado por contaminação litosférica e se diferenciado por meio do processo de cristalização fracionada até o traqui-andesito investigado. Esse magmatismo básico/intermediário encontra-se inserido no contexto magmático de uma large igneous province (LIP – província ígnea gigante) toniana reconstruída nos cratons São Francisco e Congo

U-Pb zircon in situ dating with LA-MC-ICP-MS using a mixed detector configuration

The LA-MC-ICP-MS method applied to U-Pb in situ dating is still rapidly evolving due to improvements in both lasers and ICP-MS. To test the validity and reproducibility of the method, 5 different zircon samples, including the standard Temora-2, ranging in age between 2.2 Ga and 246 Ma, were dated using both LAMC- ICP-MS and SHRIMP. The selected zircons were dated by SHRIMP and, after gentle polishing, the laser spot was driven to the same site or on the same zircon phase with a 213 nm laser microprobe coupled to a multi-collector mixed system. The data were collected with a routine spot size of 25 μm and, in some cases, of 15 and 40 μm. A careful cross-calibration using a diluted U-Th-Pb solution to calculate the Faraday reading to counting rate conversion factors and the highly suitable GJ-1 standard zircon for external calibrations were of paramount importance for obtaining reliable results. All age results were concordant within the experimental errors. The assigned age errors using the LA-MC-ICP-MS technique were, in most cases, higher than those obtained by SHRIMP, but if we are not faced with a high resolution stratigraphy, the laser technique has certain advantages

Contrasting provenance and timing of metamorphism fromparagneisses of the Ara?ua?-Ribeira orogenic system, Brazil : hints for Western Gondwana assembly.

The Ara?ua? orogen and the Ribeira belt make up a complex Neoproterozoic-Cambrian orogenic system, the Ara?ua?-Ribeira orogenic system(AROS) located fromthe eastern to southeastern Brazil. Along the AROS, the Ediacaran Rio Doce magmatic arc represents a geotectonic connection between the Ara?ua? and the Ribeira orogenic domains. Although the nature and evolution of the Rio Doce plutonic rocks is regionally well established, it lacks detailed studies on the paragneisses found along the western and central regions of this magmatic arc. Besides information on the nature and provenance of their sedimentary protoliths, the paragneisses provide data to unravel the palaeogeographic scenario fromthe precursor to arc-related basins. Six samples of Al-rich gneisses covering a large AROS region were selected for electron microprobe (EMP) mineral analyses in order to obtain geothermobarometric data and monazite ages, as well as for Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry (LA-ICP-MS) isotopic analyses on zircon (U-Pb, Lu-Hf) and monazite (U-Pb). The different age spectra fromdetrital zircon grains and contrasting Hf isotopic signatures suggest a complex sedimentary history. Located in thewestern sector of the study region, the samples RC-02 and RC-34, with an 80% age peak of detrital zircon grains from 2158 Ma to 1830 Ma, ?Hf(t) from ?2.2 to ?22.7, and Hf TDM model ages from 3530 Ma to 2440 Ma, suggest sediment sources located in the S?o Francisco craton basement. The samples RC-03, also fromthewestern sector, and RC-46 fromthe southern sector, have a more complex assemblage of detrital zircon grains with an 87% age peak from 987 Ma to 592 Ma, ?Hf(t) from +14.9 to ?2.9, and Hf TDM model ages from 2220Ma to 720 Ma, indicating provenance from mainly juvenile sources of distinct ages. Candidates to be juvenile sources for RC-03 and RC-46 sedimentary protoliths are the Rhyacian Juiz de Fora and Pocrane complexes in the basement of the Rio Doce arc, the Neoproterozoic Rio Negro arc systemof the Ribeira belt, and AROS ophiolite complexes. Samples RC-30 and RC-38 from the eastern sector of the study region, with most detrital zircon ages between 650 Ma and 552 Ma and very negative ?Hf(t) (?25.3 to ?16.5), suggest main sediment sources in the Rio Doce arc. By extending U-Pb analyses on metamorphic zircon and monazite, we have identified a complex timing of metamorphism, represented by metamorphic ages ranging from 621 Ma to 480 Ma, with the main collisional activity between 580Ma and 540 Ma. Geothermobarometric studies on garnet porphyroblasts, syn-kinematic to the D2 regional foliation, show a retrograde metamorphic path typical of continental collision belts, starting with P-T conditions of Tmax = 733 ?C and Pmax = 6.43 kbar. Our data also suggest: i) the studied paragneisses represent distinct Neoproterozoic basin stages, shifting from passive to active margin settings; ii) if the Rio Negro arc system really provided sediments for the basin stage represented by the RC-03 and RC-46 paragneisses, it would have amalgamated with the AROS before 614 Ma; iii) the final amalgamation of Western Gondwana took place around 540 Ma in the focused region; iv) an important re-heating period (520?480 Ma) can be related to the AROS gravitational collapse, afterWestern Gondwana assembly

U-Pb zircon in situ dating with LA-MC-ICP-MS using a mixed detector configuration

The LA-MC-ICP-MS method applied to U-Pb in situ dating is still rapidly evolving due to improvements in both lasers and ICP-MS. To test the validity and reproducibility of the method, 5 different zircon samples, including the standard Temora-2, ranging in age between 2.2 Ga and 246 Ma, were dated using both LA-MC-ICP-MS and SHRIMP. The selected zircons were dated by SHRIMP and, after gentle polishing, the laser spot was driven to the same site or on the same zircon phase with a 213 nm laser microprobe coupled to a multi-collector mixed system. The data were collected with a routine spot size of 25 μm and, in some cases, of 15 and 40 μm. A careful cross-calibration using a diluted U-Th-Pb solution to calculate the Faraday reading to counting rate conversion factors and the highly suitable GJ-1 standard zircon for external calibrations were of paramount importance for obtaining reliable results. All age results were concordant within the experimental errors. The assigned age errors using the LA-MC-ICP-MS technique were, in most cases, higher than those obtained by SHRIMP, but if we are not faced with a high resolution stratigraphy, the laser technique has certain advantages

Age, provenance and tectonic setting of the high-grade Jequitinhonha Complex, Araçuaí Orogen, eastern Brazil

O Complexo Jequitinhonha é uma unidade sedimentar extensa da porção nordeste do orógeno Araçuaí, metamorfizada na transição entre as fácies anfibolito-granulito há cerca de 580-540 Ma. A unidade é composta por paragnaisses kinzigíticos com intercalações de grafita-gnaisse, quartzito e rochas calcissilicáticas. Dados U-Pb de zircão detrítico de uma amostra de quartzito e novos dados geoquímicos (nove amostras) e isotópicos (Sm-Nd) (dez amostras) são aqui apresentados. De maneira concomitante a dados previamente publicados, esses dados mostram que: (1) a geoquímica dos paragnaisses sugere uma afiliação do tipo margem passiva para as rochas metassedimentares; (2) zircões detríticos apresentam populações de idade U-Pb entre 0,9 e 2,5 Ga; e (3) dados isotópicos de Nd apresentam idades modelo T DM entre 1,6 e 1,8 Ga e εNd (575 Ma) ao redor de -7,5. Esses dados revelam uma mistura de fontes, envolvendo magmatismo de rift Criogeniano a Mesoproterozoico e o embasamento Paleoproterozoico-Arqueano do paleocontinente São Francisco-Congo, e sugerem uma forte correlação entre o Complexo Jequitinhonha e o Grupo Macaúbas, compondo a mais importante bacia precursora do orógeno Araçuaí. Além da natureza exclusivamente sedimentar do complexo, fatias ofiolíticas não foram encontradas na área, reforçando a interpretação da terminação ensiálica de um golfo e que o paleocontinente São Francisco-Congo não foi separado ao norte da região, agindo como uma única peça durante o Neoproterozoico.The Jequitinhonha Complex of the northeastern Araçuaí orogen is an extensive sedimentary unit metamorphosed in the amphibolite-granulite facies transition around 580-545 Ma. The unit consists of Al-rich (kinzigitic) paragneisses with decametric intercalations of graphite gneisses and quartzites, and centimetric to metric lenses of calcsilicate rocks. A new detrital zircon U-Pb age spectrum is reported for a sample of quartzite, and whole-rock geochemical (major and trace elements, 9 samples) and Sm-Nd isotope data (10 samples) for Jequitinhonha Complex paragneiss. Together with published data these show that: (1) the geochemistry of paragneiss samples of the Jequitinhonha Complex are similar to those of passive margin sedimentary protoliths; (2) detrital zircon data yield U-Pb age populations between ca. 0.9 and 2.5 Ga; and (3) Sm-Nd TDM model ages range from 1.6 to 1.8 Ga and εNd(575 Ma) around -7.5. The data reveal a mixture of Cryogenian to Mesoproterozoic rift-related igneous rocks with the Palaeoproterozoic-Archaean basement rocks of the São Francisco-Congo palaeocontinent as the main source areas, and also support the correlation between the Jequitinhonha Complex and the passive margin units of the upper Macaúbas Group, constituting the precursor basin of the orogen. Our results, with the absence of ophiolites in the Jequitinhonha Complex, reinforce the interpretation that the São Francisco-Congo palaeocontinent was not divided to the north of the focused region, suggesting an ensialic termination of a gulf during the Neoproterozoic

Granites of the intracontinental termination of a magmatic arc : an example from the Ediacaran Ara?ua? orogen, southeastern Brazil.

The Ara?ua? orogen of southeastern Brazil together with the West Congo belt of central West Africa form the Ara?ua??West Congo orogen generated during closure of a terminal segment of the Neoproterozoic Adamastor Ocean. Corresponding to an embayment in the S?o Francisco?Congo Craton, this portion of the Adamastor was only partially floored by oceanic crust. The convergence of its margins led to the development of the Rio Doce magmatic arc between 630 Ma and 580 Ma. The Rio Doce magmatic arc terminates in the northern portion of the Ara?ua? orogen. Granitic plutons exposed in the northern extremity of the arc provide a rare opportunity to studymagmatismat arc terminations, and to understand the interplay between calc-alkalinemagma production and crustal recycling. The plutons forming the terminus of the arc consist of granodiorites, tonalites and monzogranites similar to a magnesian, slightly peraluminous, calcic- (68%) to calc-alkaline (24%), with minor alkali-calcic (8%) facies, medium- to high-K magmatic series. Although marked by negative Nb?Ta, Sr and Ti anomalies, typically associatedwith subduction-relatedmagmas, the combined Sr, Nd and Hf isotopic data characterize a crustal signature related to anatexis of metamorphosed igneous and sedimentary rocks, rather than fractional crystallization of mantle-derived magmas. Zircon U?Pb ages characterizes two groups of granitoids. The older group, crystallized between 630 and 590 Ma, experienced a migmatization event at ca. 585 Ma. The younger granitoids, emplaced between 570 and 590 Ma, do not show any evidence for migmatization. Most of the investigated samples show good correlation with the experimental compositional field of amphibolite dehydration-melting, with some samples plotting into the field of greywacke dehydration-melting. The studied rocks are not typical I-type or S-type granites, being particularly similar to transitional I/S-type granitoids described in the Ordovician Famatinian arc (NW Argentina). We suggest a hybrid model involving dehydrationmelting of meta-igneous (amphibolites) and metasedimentary (greywackes) rocks for magma production in the northern termination of the Rio Doce arc. The real contribution of each end-member is, however, a challenging work still to be done