Cathodoluminescence of nanocrystalline Y2O3:Eu3+ with various Eu3+ concentrations

© The Author(s) 2014. Published by ECS. This is an open access article distributed under the terms of the Creative Commons Attribution 4.0 License (CC BY, http://creativecommons.org/licenses/by/4.0/), which permits unrestricted reuse of the work in any medium, provided the original work is properly cited.This article has been made available through the Brunel Open Access Publishing Fund.Herein a study on the preparation and cathodoluminescence of monosized spherical nanoparticles of Y2O3:Eu3+ having a Eu3+ concentration that varies between 0.01 and 10% is described. The luminous efficiency and decay time have been determined at low a current density, whereas cathodoluminescence-microscopy has been carried out at high current density, the latter led to substantial saturation of certain spectral transitions. A novel theory is presented to evaluate the critical distance for energy transfer from Eu3+ ions in S6 to Eu3+ ions in C2 sites. It was found that Y2O3:Eu3+ with 1–2% Eu3+ has the highest luminous efficiency of 16lm/w at 15keV electron energy. Decay times of the emission from 5D0 (C2) and 5D1 (C2) and 5D0 (S6) levels were determined. The difference in decay time from the 5D0 (C2) and 5D1 (C2) levels largely explained the observed phenomena in the cathodoluminescence-micrographs recorded with our field emission scanning electron microscope

Cathodoluminescence of Double Layers of Phosphor Particles

This article has been made available through the Brunel Open Access Publishing Fund.We present radiance measurements of particle layers of ZnO:Zn, Y2O3:Eu and Y2O2S:Eu bombarded with electrons at anode voltages between 1 and 15 kV. The layers described in this work refer to single component layers, double layers and two component mixtures. The phosphor layers are deposited on ITO-coated glass slides by settling; the efficiency of the cathodoluminescence is determined by summing the radiances and luminances in the reflected and transmitted modes respectively. The efficiency of a double layer of Y2O3:Eu on top of ZnO:Zn at high electron energy is significantly larger than the efficiency of a corresponding layer in which the two components are mixed. This result is interpreted in terms of the penetration-model, which predicts a larger efficiency for a high-voltage phosphor on top of a low-voltage phosphor. When a layer of the low-voltage phosphor ZnO:Zn is on top of the high-voltage phosphor Y2O3:Eu, we also observe a higher efficiency than that of the corresponding layer with both components mixed. In this case the efficiency increases due to suppression of charging in the Y2O3:Eu layer. Double layers of ZnO:Zn and Y2O2S:Eu did not show enhanced efficiency, because the size of the Y2O2S:Eu particles was too large to evoke the penetration effect. © The Author(s) 2014. Published by ECS

Bayesian model selection for electromagnetic kaon production on the nucleon

We present the results of a Bayesian analysis of a Regge model to describe the background contribution for K+ Lambda and K+ Sigma0 photoproduction. The model is based on the exchange of K+(494) and K*+(892) trajectories in the t-channel. We utilise the Bayesian evidence Z to determine the best model variant for each channel. The Bayesian evidence integrals were calculated using the Nested Sampling algorithm. For different prior widths, we find decisive Bayesian evidence (\Delta ln Z ~ 24) for a K+ Lambda photoproduction Regge model with a positive vector coupling and a negative tensor coupling constant for the K*+(892) trajectory, and a rotating phase factor for both trajectories. Using the chi^2 minimisation method, one could not draw this conclusion from the same dataset. For the K+ Sigma0 photoproduction Regge model, on the other hand, the difference between the evidence integrals is insufficient to pinpoint one model variant.Comment: 13 pages, 4 figure

Local air quality management and climate change: tools for joined up policy

All tiers of UK Government are required to include a range of environmental objectives in developing land use and transportation plans. The current trend towards regionalisation of governance brings with it uncertainty and debate. Part of this debate must include determination of the optimum scale for implementing land use and transportation plans to incorporate environmental objectives. This thesis is the result of developing tools to assist in this debate, using the environmental objectives relating to local air quality management and global climate change. A major outcome of this research is the development of robust techniques and tools for the estimation of atmospheric emissions and subsequent air quality impact from land use, including industry, and transportation activities. An extensive number of evaluation techniques have been used to verify the robustness of these tools. These tools have been applied to a geographically diverse part of the UK representing a sub-regional level of governance and have been demonstrated to be applicable at the regional scale. The tools have been used to provide a spatially detailed and source specific profile of emissions of key pollutants over a period from 1990 to 2020 allowing for the consideration of devolving the climate change objectives for reducing greenhouse gas emissions from the national to local scale. There is a balance between source size and the extent of geographical area (scale of governance) to ensure meaningful emission reduction measures can be implemented equitably. The tools have also been used to test the impact on local air quality of reducing emissions through assessment of a number of land use and transportation scenarios. The results indicate meeting climate change objectives will deliver more in terms of local air quality management than vice versa. There is expected to be a future limit to local air quality management in terms of reducing emissions and a need to reduce population exposure through land use planning. The issue of source scale may be overcome by adopting off setting policies. The results of this research suggest the inclusion of local air quality management and climate change objectives in land use and transportation planning could be achieved at the regional or sub-regional scale, rather than local (district) scale of governance

Cathodoluminescence studies of phosphors in a scanning electron microscope

Cathodoluminescence studies are reported of phosphors in a field emission scanning electron microscope (FESEM). A number of phosphor materials have been studied and exhibited a pronounced comet-like structure at high scan rates, because the particle continued to emit light after the beam had moved onto subsequent pixels. Image analysis has been used to study the loss of brightness along the tail and hence to determine the decay time of the materials. This technique provides a simple and convenient way to study the decay times of individual particles

Mapping the Shores of the Brown Dwarf Desert. I. Upper Scorpius

We present the results of a survey for stellar and substellar companions to 82 young stars in the nearby OB association Upper Scorpius. This survey used nonredundant aperture mask interferometry to achieve typical contrast limits of ΔK ~5-6 at the diffraction limit, revealing 12 new binary companions that lay below the detection limits of traditional high-resolution imaging; we also summarize a complementary snapshot imaging survey that discovered seven directly resolved companions. The overall frequency of binary companions (~35 +5 -4% at separations of 6-435 AU) appears to be equivalent to field stars of similar mass, but companions could be more common among lower mass stars than for the field. The companion mass function has statistically significant differences compared to several suggested mass functions for the field, and we suggest an alternate lognormal parameterization of the mass function. Our survey limits encompass the entire brown dwarf mass range, but we only detected a single companion that might be a brown dwarf; this deficit resembles the so-called brown dwarf desert that has been observed by radial velocity planet searches. Finally, our survey’s deep detection limits extend into the top of the planetary mass function, reaching 8-12 MJup for half of our sample. We have not identified any planetary companions at high confidence (≳99.5%), but we have identified four candidate companions at lower confidence (≳97.5%) that merit additional follow-up to confirm or disprove their existence

Statistical Properties of Interacting Bose Gases in Quasi-2D Harmonic Traps

The analytical probability distribution of the quasi-2D (and purely 2D) ideal and interacting Bose gas are investigated by using a canonical ensemble approach. Using the analytical probability distribution of the condensate, the statistical properties such as the mean occupation number and particle number fluctuations of the condensate are calculated. Researches show that there is a continuous crossover of the statistical properties from a quasi-2D to a purely 2D ideal or interacting gases. Different from the case of a 3D Bose gas, the interaction between atoms changes in a deep way the nature of the particle number fluctuations.Comment: RevTex, 10pages, 4 figures, E-mail: [email protected]