Gold(I)-Catalyzed Cascade Cyclization Reactions of Allenynes for the Synthesis of Fused Cyclopropanes and Acenaphthenes

A gold‐catalyzed reaction of phenylene‐tethered allenynes with benzofurans gave 1‐(naphth‐1‐yl)cyclopropa[b]benzofuran derivatives, whereas the reaction of 1‐allenyl‐2‐ethynyl‐3‐methylbenzene derivatives in the absence of benzofurans gave acenaphthenes in good yields. These results can be rationalized by nucleophilic attack of the alkyne moiety on an activated allene to form a vinyl cation intermediate

Auto-Positioning and Haptic Stimulations via A 35 mm Square Pmut Array

This work reports an engineered platform for the non-contact haptic stimulation on human skins by means of an array of piezoelectric micromachined ultrasonic transducer (pMUT) via the beamforming scheme. Compared to the state-of-art reports, three distinctive achievements have been demonstrated: (1) individual single pMUT unit based on lithium niobate (LN) with measured high SPL (sound pressure level) of 133 dB at 2 mm away; (2) a beamforming scheme simulated and experimentally proved to generate ∼2.3x higher pressure near the focal point; and (3) the combination of auto-positioning and haptic stimulations on volunteers with the smallest reported physical device size to achieve haptic sensations. As such, this work could have practical applications in the broad areas to stimulate haptic sensations, such as AR (Augmented Reality), VR (Virtual Reality), and robotics

Drone-Mounted Low-Frequency pMUTS for > 6-Meter Rangefinder in Air

This paper reports a low-frequency piezoelectric micromachined ultrasonic transducer (pMUT) with a small attenuation coefficient to realize the long-distance range finding applications in air. Pulse-detection measurements of one pair of pMUT devices show a >6-meter traveling distance in air under a 37.32 kHz driving frequency. As an example, two pMUT chips are mounted on two drones as the transceiver and receiver, respectively. Measurements of the separation distance are conducted based on the time-of-flight (ToF) principle with up to 32 fps (frames per second) for real-time detections. This demo of drone-mounted pMUT system illustrates the advantages of pMUT in terms of compactness and low power consumption for applications in drones including obstacle avoidance, inter collision prevention, aerial coordination, and acoustic-based vision

Continuous Volumetric Indoor Temperature Monitoring via PMUTs

This work presents a continuous volumetric indoor air temperature measurement scheme using PMUTs (piezoelectric micromachined ultrasonic transducers). Advancements as compared to state-of-art works include: (1) 'volumetric' temperature monitoring instead traditional 'pointwise' temperature information; (2) accurate temperature readings spanning an operational distance of 5 m as validated by a commercial thermometer for 3 days; and (3) capable of detecting global average temperature and local temperature events by installing networked/grid PMUT pairs. This innovative sensing technique could be applicable for the precision control of future building/living environments

9-Meter-Long 3d Ultrasonic Objects Detection via Packaged Lithium-Niobate PMUTs

This paper reports a 9-meter-long ultrasonic 3D detector based on a packaged lithium niobate PMUTs (piezoelectric micromachined ultrasonic transducers). Compared with the state-of-the-art reports, three distinctive achievements have been demonstrated: (1) high uniformity and wide bandwidth PMUTs by optimized package designs for highly efficient ultrasonic energy transfer; (2) a long-range receiving beamforming detection scheme on a 4×4 PMUT array for up to 9 m detection rang - comparable to the longest reported range via PMUTs; and (3) 3D detection of multiple static/moving objects with the field of view exceeding 50°. As such, this device is valuable for various applications such as obstacle avoidance when both low power consumption and small form factor are desirable, including aerial drones

Gold(I)‐Catalyzed Cascade Cyclization Reactions of Allenynes for the Synthesis of Fused Cyclopropanes and Acenaphthenes

A gold‐catalyzed reaction of phenylene‐tethered allenynes with benzofurans gave 1‐(naphth‐1‐yl)cyclopropa[b]benzofuran derivatives, whereas the reaction of 1‐allenyl‐2‐ethynyl‐3‐methylbenzene derivatives in the absence of benzofurans gave acenaphthenes in good yields. These results can be rationalized by nucleophilic attack of the alkyne moiety on an activated allene to form a vinyl cation intermediate

Fostering A Data Infrastructure for The Humanities and Social Sciences: A Case Study in Japan_20220915

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Investigation of Material Constants of CaTiO₃ Doped (K,Na)NbO₃ Film by MEMS-Based Test Elements

A CaTiO3-doped (K,Na)NbO3 (KNN-CT) film is a lead-free piezoelectric film that is expected to substitute Pb(Zr,Ti)O3 (PZT) film in piezoelectric micro electro mechanical systems (MEMS). However, the full set of the material constants (elastic constants, piezoelectric constants and dielectric constants) of the KNN-CT film have not been reported yet. In this study, all the material constants of a sputter-deposited blanket KNN-CT film were investigated by the resonance responses of MEMS-based piezoelectric resonators and the phase velocities of leaky Lamb waves on a self-suspended membrane. The phase velocities measured by a line-focus-beam ultrasonic material characterization (LFB-UMC) system at different frequencies were fitted with theoretical ones, which were calculated from the material constants, including fitting parameters. A genetic algorithm was used to find the best-fitting parameters. All the material constants were then calculated. Although some problems arising from the film quality and the nature of deliquescence are observed, all the material constants were obtained exhibiting accuracy within 16 m/s in the phase velocity of leaky Lamb wave

Health survey of numbness/pain and its associated factors in Kotohira, Japan.

We conducted a survey of adults in Kotohira, a town of about 10,000 people located in the Nakatado District of Kagawa Prefecture, Japan. The survey was distributed to 8184 individuals, and effective responses were received from 3863 persons (response rate, 47.2%) during the survey period. Results regarding numbness and pain showed numbness alone in 7.7%, pain alone in 7.2%, both numbness and pain in 6.0%, and neither numbness nor pain in 79.6%. Spine and spinal cord damage was reported present by 5.4%, and absent by 94.6%. Analysis using the Short-Form Health Survey questionnaire, with comparison between subjects reporting both numbness and pain in the extremities and subjects with either numbness or pain alone, showed lower scores for in Short-Form Health Survey subscales (physical functioning, role [physical, emotional], bodily pain, vitality, and mental health). Subjects with numbness alone generally reported no disability in daily life. In a secondary survey, analysis of neurological findings by specialists identified 6 cases of "pain following spinal cord damage" in which spinal cord-related pain developed in the hands or feet. This represented 0.15% of the survey population starting from the primary survey

Construction of Tricyclic Nitrogen Heterocycles by Gold(I)‐Catalyzed Cascade Cyclization of Allenynes and Its Application to Polycyclic π‐Electron Systems

A novel approach to the direct construction of tricyclic nitrogen heterocycles based on gold-catalyzed cascade cyclization of aminoallenynes is described. The expected biscyclization reaction of hydroxyisobutyryl-protected aminoallenynes was efficiently promoted by a catalytic amount of BrettPhosAuNTf₂ in the presence of iPrOH to produce 1, 2-dihydrobenzo[cd]indole derivatives in good yields. When the reaction was combined with Friedel–Crafts acylation or palladium-catalyzed N-arylation, the resulting tricyclic products were efficiently converted into nitrogen-containing polycyclic aromatic compounds (N-PACs) with highly conjugated π-electron systems. A newly obtained hexacyclic indolium salt showed characteristic concentration-dependent absorption and emission properties