5,068 research outputs found
Structural assignments of stereoisomeric cyclobutanones by substituent increments on chemical shifts
Classifying representations by way of Grassmannians
Let be a finite dimensional algebra over an algebraically closed
field. Criteria are given which characterize existence of a fine or coarse
moduli space classifying, up to isomorphism, the representations of
with fixed dimension and fixed squarefree top . Next to providing a
complete theoretical picture, some of these equivalent conditions are readily
checkable from quiver and relations. In case of existence of a moduli space --
unexpectedly frequent in light of the stringency of fine classification -- this
space is always projective and, in fact, arises as a closed subvariety
of a classical Grassmannian. Even when the full moduli
problem fails to be solvable, the variety is seen to
have distinctive properties recommending it as a substitute for a moduli space.
As an application, a characterization of the algebras having only finitely many
representations with fixed simple top is obtained; in this case of `finite
local representation type at a given simple ', the radical layering is shown to be a classifying invariant for the
modules with top . This relies on the following general fact obtained as a
byproduct: Proper degenerations of a local module never have the same
radical layering as
Top-stable degenerations of finite dimensional representations I
Given a finite dimensional representation of a finite dimensional
algebra, two hierarchies of degenerations of are analyzed in the context of
their natural orders: the poset of those degenerations of which share the
top with - here denotes the radical of the algebra - and the
sub-poset of those which share the full radical layering
with . In particular, the article
addresses existence of proper top-stable or layer-stable degenerations - more
generally, it addresses the sizes of the corresponding posets including bounds
on the lengths of saturated chains - as well as structure and classification
The phantom menace in representation theory
Our principal goal in this overview is to explain and motivate the concept of
a phantom in the representation theory of a finite dimensional algebra
. In particular, we exhibit the key role of phantoms towards
understanding how a full subcategory of the category
of all finitely generated left -modules is
embedded into , in terms of maps leaving or entering .
Contents: 1. Introduction and prerequisites; 2. Contravariant finiteness and
first examples; 3. Homological importance of contravariant finiteness and a
model application of the theory; 4. Phantoms. Definitions, existence, and basic
properties; 5. An application: Phantoms over string algebras
Kinetics and mechanism of the conversion of cyclobutenones to vinylketens
The structure–rate relationships for the electrocyclic ring opening of phenylated and alkylated cyclobutenones to vinylketens, though not fully understood, resemble those which are observed in cyclobutene ring openings
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