324 research outputs found

    Le Corbusier’s Fatal Flaws – A Critique of Modernism

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    NEG Coating at RHIC

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    Low secondary electron yield engineered surface for electron cloud mitigation

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    Secondary electron yield (SEY or δ) limits the performance of a number of devices. Particularly, in high-energy charged particle accelerators, the beam-induced electron multipacting is one of the main sources of electron cloud (e-cloud) build up on the beam path; in radio frequency wave guides, the electron multipacting limits their lifetime and causes power loss; and in detectors, the secondary electrons define the signal background and reduce the sensitivity. The best solution would be a material with a low SEY coating and for many applications δ < 1 would be sufficient. We report on an alternative surface preparation to the ones that are currently advocated. Three commonly used materials in accelerator vacuum chambers (stainless steel, copper, and aluminium) were laser processed to create a highly regular surface topography. It is shown that this treatment reduces the SEY of the copper, aluminium, and stainless steel from δmax of 1.90, 2.55, and 2.25 to 1.12, 1.45, and 1.12, respectively. The δmax further reduced to 0.76-0.78 for all three treated metals after bombardment with 500 eV electrons to a dose between 3.5 × 10-3 and 2.0 × 10-2 C·mm-2

    Pressure Rise in Run6 and Related Issues

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    Effects of Surface Monolayers on the Electron-Transfer Kinetics and Adsorption of Methyl Viologen and Phenothiazine Derivatives on Glassy Carbon Electrodes

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    Five organic redox systems were examined in aqueous electrolytes on polished and chemically modified glassy carbon (GC), to evaluate the effects of surface structure on the heterogeneous transfer rate constant, k°. Methyl viologen reduction to its cation radical exhibited a voltammetric peak potential difference which was insensitive to surface modification, with k°decreasing by only 50% when a chemisorbed monolayer was present. Methylene blue and three other phenothiazines adsorbed to polished GC, but the adsorption was suppressed by surface modification. For all four phenothiazines, chemisorbed or physisorbed monolayers of electroinactive species had minor effects on k°, with a compact nitrophenyl monolayer decreasing k°by 50%. This minor change in k°was accompanied by a major decrease in adsorption, apparently due to inhibition of dipole-dipole or π-π interactions between the phenothiazine and GC. Chlorpromazine oxidation to its cation radical was studied in more detail, under conditions where adsorption was suppressed. A plot of the natural log of the observed rate constant vs the monolayer thickness for a variety of chemisorbed monolayers was linear, with a slope of -0.22 Å -1 . The observations are consistent with a through-bond electron-tunneling mechanism for electron transfer to all five redox systems studied. The tunneling constant for CPZ of 0.22 Å -1 is between that reported for electron tunneling through conjugated polyene spacers (0.14 Å -1 ) and that reported for phenyl-methylene spacers (0.57 Å -1 ), on the basis of long-range electron transfer in rigid molecules. Through a variety of efforts from many laboratories, significant progress has been made toward understanding the electrochemical behavior of widely used carbon electrodes. 1-7 Since sp 2 carbon surfaces are difficult to prepare reproducibly and are prone to degradation via oxidation and impurity adsorption, our understanding of the behavior of carbon electrodes has lagged that of metal electrodes, particularly mercury ones. This situation improved dramatically after more attention was paid to surface preparation and the number of uncontrolled surface variables was reduced. In particular, several landmarks indicating reproducible performance of sp 2 carbon electrodes, mainly glassy carbon (GC), have been achieved: 1. Determination of the rapid heterogeneous electron-transfer rate constants (k°), for outer-sphere systems (e.g., Ru(NH 3 ) 6 +3/+2 k°&gt; 0.2 cm/s), 8,9 comparable to those observed on Au and Pt. 10 2. Preparation of low-oxide (O/C &lt; 2%) carbon surfaces which retain their low oxide levels for at least one month in air. 11,12 3. Structural characterization of organic monolayers and submonolayers on carbon with Raman spectroscopy. [13][14][15] 4. Correlation of specific surface sites with electrocatalytic activity for various redox systems, including ascorbic acid, NADH, Fe 3+/2+ , etc. 8,[16][17][18][19] 5

    A Reinforcement Learning Badminton Environment for Simulating Player Tactics (Student Abstract)

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    Recent techniques for analyzing sports precisely has stimulated various approaches to improve player performance and fan engagement. However, existing approaches are only able to evaluate offline performance since testing in real-time matches requires exhaustive costs and cannot be replicated. To test in a safe and reproducible simulator, we focus on turn-based sports and introduce a badminton environment by simulating rallies with different angles of view and designing the states, actions, and training procedures. This benefits not only coaches and players by simulating past matches for tactic investigation, but also researchers from rapidly evaluating their novel algorithms.Comment: Accepted by AAAI 2023 Student Abstract, code is available at https://github.com/wywyWang/CoachAI-Projects/tree/main/Strategic%20Environmen

    Validation of the Action Research Arm Test using item response theory in patients after stroke

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    Objective: To validate the unidimensionality of the Action Research Arm Test (ARAT) using Mokken analysis and to examine whether scores of the ARAT can be transformed into interval scores using Rasch analysis. Subjects and methods: A total of 351 patients with stroke were recruited from 5 rehabilitation departments located in 4 regions of Taiwan. The 19-item ARAT was administered to all the subjects by a physical therapist. The data were analysed using item response theory by non-parametric Mokken analysis followed by Rasch analysis. Results: The results supported a unidimensional scale of the 19-item ARAT by Mokken analysis, with the scalability coefficient H = 0.95. Except for the item pinch ball bearing 3rd finger and thumb'', the remaining 18 items have a consistently hierarchical order along the upper extremity function's continuum. In contrast, the Rasch analysis, with a stepwise deletion of misfit items, showed that only 4 items (grasp ball'', grasp block 5 cm(3)'', grasp block 2.5 cm(3)'', and grip tube 1 cm(3)'') fit the Rasch rating scale model's expectations. Conclusion: Our findings indicated that the 19-item ARAT constituted a unidimensional construct measuring upper extremity function in stroke patients. However, the results did not support the premise that the raw sum scores of the ARAT can be transformed into interval Rasch scores. Thus, the raw sum scores of the ARAT can provide information only about order of patients on their upper extremity functional abilities, but not represent each patient's exact functioning
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