Predicting Solar Cell Performance from Terahertz and Microwave Spectroscopy

Mobilities and lifetimes of photogenerated charge carriers are core properties of photovoltaic materials and can both be characterized by contactless terahertz or microwave measurements. Here, the expertise from fifteen laboratories is combined to quantitatively model the current voltage characteristics of a solar cell from such measurements. To this end, the impact of measurement conditions, alternate interpretations, and experimental inter laboratory variations are discussed using a Cs,FA,MA Pb I,Br 3 halide perovskite thin film as a case study. At 1 sun equivalent excitation, neither transport nor recombination is significantly affected by exciton formation or trapping. Terahertz, microwave, and photoluminescence transients for the neat material yield consistent effective lifetimes implying a resistance free JV curve with a potential power conversion efficiency of 24.6 . For grainsizes above amp; 8776;20 nm, intra grain charge transport is characterized by terahertz sum mobilities of amp; 8776;32 cm2 V amp; 8722;1 s amp; 8722;1. Drift diffusion simulations indicate that these intra grain mobilities can slightly reduce the fill factor of perovskite solar cells to 0.82, in accordance with the best realized devices in the literature. Beyond perovskites, this work can guide a highly predictive characterization of any emerging semiconductor for photovoltaic or photoelectrochemical energy conversion. A best practice for the interpretation of terahertz and microwave measurements on photovoltaic materials is presente

Bi-directional terahertz emission from gold-coated nanogratings by excitation via femtosecond laser pulses

We report on the investigation of terahertz (THz) emission from gold-coated nanogratings (500 nm grating constant) upon femtosecond laser irradiation (785 nm, 150 fs, 1 kHz, a parts per thousand currency sign1 mJ/pulse). Unlike common assumptions, THz emission is not only observed in case of rear side irradiation (through substrate (Welsh et al. in Phys. Rev. Lett. 98:026803, 2007; Welsh and Wynne in Opt. Express 17:2470-2480, 2009)) of the nanograting, but also in case of front side excitation (through air). Furthermore in both cases, THz emission propagates in the direction of laser beam propagation and reverse. Based on these findings, we suggest a new approach to describe the newly observed phenomena. Using a highly sensitive and fast superconducting transition edge sensor (TES) as calorimeter, it was possible to directly measure the absolute energy of the emitted THz pulses in a defined spectral and spatial range, enabling for the first time a quantitative analysis of the THz emission process