The Influence of Birch (Betula pendula) False Heartwood on the Mechanical Properties of Wood-Plastic Composites. Kase (Betula pendula) v\ue4\ue4rl\ufclipuidu m\uf5ju puitplastkomposiitide mehaanilistele omadustele

Doctoral thesis 29/2019 Doktorit\uf6\uf6 29/201

Impact of Aspen and Black Alder Substitution in Birch Plywood

Increasing demand pressures on the fibre supply are forcing manufacturers to explore using new species in plywood. Here we investigated aspen and black alder, alone and in combination with birch faces, and with different veneer thicknesses in plywood production. The aim of this study was to evaluate the effect of different veneer thicknesses, lay-up systems, and hardwood veneer combinations on plywood mechanical properties. Impacts on modulus of rupture (MOR), modulus of elasticity (MOE), glue consumption, and density properties were observed. All process parameters were the same as for pure birch plywood. Not surprisingly, birch plywood had the highest MOR and MOE, followed by aspen and black alder. Aspen had the highest glue consumption and birch the lowest, when applied with a spreader roll, but the common practice of using relatively thick 2.6 mm aspen veneers resulted in the lowest glue consumption per mm of product. The effects of wood species and veneer thickness on MOR, density, and glue consumption were analysed for panel thicknesses from 6.5 to 18 mm to guide manufacturers in choosing their species and construction to optimize cost, MOR and stiffness, weight, and glue consumption. In conclusion, birch gave the best strength properties while aspen gave the best price and weight combination

Durability of modified wood and bio-based materials under outdoor conditions

Conference abstract for Final COST Action FP1407 International Conference - Living with modified woodPages 48-4

Effect of Hemp Fiber Surface Treatment on the Moisture/Water Resistance and Reaction to Fire of Reinforced PLA Composites

The effects of surface pretreatment (water and alkali) and modification with silane on moisture sorption, water resistance, and reaction to fire of hemp fiber reinforced polylactic acid (PLA) composites at two fiber loading contents (30 and 50 wt.%) are investigated in this work. Moisture adsorption was evaluated at 30, 50, 75 and 95% relative humidity, and water resistance was determined after a 28-day immersion period. The cone calorimetry technique was used to investigate response to fire. The fiber surface treatment resulted in the removal of cell wall components, which increased fiber individualization and homogeneity as shown in scanning microscopic pictures of the composite cross-section. Although the improved fiber/matrix bonding increased the composite’s water resistance, the different fiber treatments generated equal moisture adsorption results for the 30 wt.% reinforced composites. Overall, increasing the fiber amount from 30 to 50 wt.% increased the composite sensitivity to moisture/water, mainly due to the availability of more hydroxyl groups and to the development of a higher pore volume, but fire protection improved due to a reduction in the rate of thermal degradation induced by the reduced PLA content. The new Oswin’s model predicted the composite adsorption isotherm well. The 30 wt.% alkali and silane treated hemp fiber composite had the lowest overall adsorption (9%) while the 50 wt.% variant produced the highest ignition temperature (181 ± 18 °C)

Investigation of Efficient Alkali Treatment and the Effect of Flame Retardant on the Mechanical and Fire Performance of Frost-Retted Hemp Fiber Reinforced PLA

Publisher Copyright: © 2022 by the authors. Licensee MDPI, Basel, Switzerland.This research investigates an effective alkali (NaOH) treatment and fire-retardant coating to produce biocomposites from frost-retted hemp fiber and PLA. The fiber surface treatment with various NaOH concentrations was investigated throughout a range of soaking times. The results show that the extracted non-cellulosic fiber content increases with treatment duration and NaOH concentration, while the fraction of targeted components removed remains nearly unchanged after soaking for 1, 2, and 4 h with a 5 wt.% NaOH solution. At the composite level, the treatment with 5 wt.% NaOH solution for 1 h emerged as the most efficient, with tensile strength, Young’s modulus, flexural strength, and flexural modulus of 89.6 MPa, 9.1 GPa, 121.6 MPa, and 9.6 GPa, respectively, using 30 wt.% fibrous reinforcement. The fire performance of the examined batches of biocomposites improved significantly with the novel fire-retardant (Palonot F1) coating. However, the tensile strength notably decreased, while the flexural properties showed only a slight reduction. In most cases, the biocomposites with the alkali-treated hemp fiber had delayed ignition during the 5 min exposure to the cone heater. The findings in this work contribute to studies that will be required to give design guidelines for sustainable building options.Peer reviewe

Tensile and Surface Wettability Properties of the Solvent Cast Cellulose Fatty Acid Ester Films

Thermoplastic cellulose esters are promising materials for bioplastic packaging. For that usage, it is important to understand their mechanical and surface wettability properties. In this study, a series of cellulose esters are prepared, such as laurate, myristate, palmitate, and stearate. The aim of the study is to investigate the tensile and surface wettability properties of the synthesized cellulose fatty acid esters to understand their suitability as a bioplastic packaging material. Cellulose fatty acid esters are first synthesized from microcrystalline cellulose (MCC), then dissolved in pyridine solution, and after the solvent cast into thin films. The cellulose fatty acid ester acylation process is characterized by the FTIR method. Cellulose esters hydrophobicity is evaluated with contact angle measurements. The mechanical properties of the films are tested with the tensile test. For all the synthesized films, FTIR provides clear evidence of acylation by showing the presence of characteristic peaks. Films’ mechanical properties are comparable to those of generally used plastics such as LDPE and HDPE. Furthermore, it appears that with an increase in the side-chain length, the water barrier properties showed improvement. These results show that they could potentially be suitable materials for films and packaging materials