Lead isotopic evidence for synextensional lithospheric ductile flow in the Colorado River extensional corridor, western United States

This is the published version. Copyright 1998 American Geophysical Union. All Rights Reserved.Temporal changes in the Pb isotopic compositions of Miocene lavas erupted in the northern Colorado River extensional corridor suggest that lithospheric mantle and middle to deep crust migrated from beneath the Colorado Plateau into the corridor during extension. Basaltic to rhyolitic lavas erupted in the extensional corridor prior to 12.2 Ma have Pb isotopic values that are similar to those of Tertiary to Quaternary lavas erupted through Proterozoic Mojave crust, which comprises surface exposures of basement in the corridor and much of the extended territory to the west. In contrast, most post-12.2 Ma lavas from the same region have Pb isotopic compositions similar to those of lavas erupted through Arizona crust, which forms the basement of the Colorado Plateau. The changes in isotopic compositions of the basaltic lavas, and perhaps a portion of the changes in isotopic compositions of silicic lavas, are attributed to a change in the composition of the mantle source. However, the 206Pb/204Pb ratios for lavas erupted before and after 12.2 Ma in the corridor decrease with decreasing MgO concentrations, suggesting that the Pb isotopic compositions of crustal assimilants changed at about the same time as the composition of the mantle. In the area of the Black Mountains accommodation zone, the surface boundary between the Arizona and Mojave crustal provinces lies a minimum of 60–80 km to the east of the westernmost lava with an Arizona Pb isotopic signature. This distance cannot be accounted for by displacements along nearby major faults, suggesting that middle to deep Arizona crust flowed a significant distance to the west during extension

Tracing the effects of high-pressure metasomatic fluids and seawater alteration in blueschist-facies overprinted eclogites: Implications for subduction channel processes

Eclogites from the Tian Shan high-pressure/low-temperature (HP/LT) metamorphic belt show evidence for successively increasing metasomatic alteration with increasing retrograde, blueschist-facies overprint. To constrain the source(s) of the metasomatizing fluid and to evaluate elemental and isotopic changes during this overprint, two sequences of eclogite-blueschist transitions were investigated: A layered transition from eclogite to blueschist (FTS 9–1 sequence) and blueschist-facies overprinted pillow metabasalts (FTS 4 samples). Geochemical trends based on the relationships of K, Ba, Rb and Th are consistent with HP metasomatism, but distinct from typical seafloor alteration trends. In contrast, oxygen isotope ratios in garnet (δ18OV-SMOW = 7.3–8.7‰) and omphacite (δ18OV-SMOW = 8.2–9.7‰) are similar to δ18OV-SMOW in bulk low-temperature altered oceanic crust (AOC), suggesting O isotopic preservation of a seafloor alteration signature. Carbonate crystallization related to the metasomatic overprint demonstrate CO2 mobility during subduction and potential C storage in HP metamorphic rocks. Carbon isotope ratios in the two sequences differ markedly: Disseminated calcite in the layered FTS 9–1 sequence has δ13CV-PDB = − 9.14 ± 0.19‰, whereas vein-forming ankerite in the pillow metabasalts has δ13CV-PDB = − 2.08 ± 0.12‰. The ankerite reflects an inorganic marine/hydrothermal signature, as observed in ophiolites, whereas the low δ13CV-PDB values from the calcite point to a contribution of organic carbon. The time when the metasomatic overprint occurred is estimated to be ~ 320 ± 11 Ma based on a Rb-Sr isochron age of six blueschist samples from the pillow metabasalts, which is in agreement with active subduction in this region. Initial (T = 320 Ma) 87Sr/86Sr ratios for all HP/LT rocks range from 0.7059 – 0.7085, and εNd320Ma varies from − 0.4 to + 10.9. Both eclogite-blueschist sequences have initial Sr isotope compositions (87Sr/86Sr ~ 0.707) that are significantly higher than those of typical oceanic mantle-derived basalts. They are thought to derive from a fluid that preserved the Sr isotopic signature of seawater by fluid-rock interaction with seawater-altered oceanic lithosphere in a subduction channel. Mixing models between eclogite and various fluids suggest that the contribution of a sediment-derived fluid was likely less than 20%. A fluid predominantly derived from seawater-altered oceanic lithosphere is also supported by the calculated O isotope composition of the fluids (10.2 – 11.2‰). It is thus evident that subduction channel fluids carry complex, mixed elemental and isotopic signatures, which reflect the composition of their source rocks modified by interaction with various other lithologies. Highlights ► Eclogites from the Tian Shan show blueschist-facies metasomatic overprint ► Fluid-induced metasomatism occurred at 320 ± 11 Ma ► Fluid predominantly derived from seawater-altered oceanic lithosphere ► Carbonates reflect C sequestration of mixture of organic and inorganic component

Distribution of recycled crust within the upper mantle : insights from the oxygen isotope composition of MORB from the Australian-Antarctic Discordance

Author Posting. © American Geophysical Union, 2009. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 10 (2009): Q12004, doi:10.1029/2009GC002728Geochemical heterogeneity within the mantle has long been recognized through the diversity of trace element and radiogenic isotopic compositions of mantle-derived rocks, yet the specific origin, abundance, and distribution of enriched material within the mantle have been difficult to quantify. In particular, the origin of the distinctive geochemical characteristics of Indian mantle has been debated for decades. We present new laser fluorination oxygen isotope measurements of mid-ocean ridge basalt from the Australian-Antarctic Discordance (AAD), an area where a particularly abrupt transition occurs between Pacific-type mid-ocean ridge basalts (MORB) and Atlantic-type MORB. These data show no distinction in average δ18O between Pacific- and Atlantic-type MORB, indicating that the origin of Indian-type mantle cannot be attributed to the presence of pelagic sediment. The combined radiogenic isotope, δ18O, and trace element characteristics of Indian-type MORB at the AAD are consistent with contamination of the Indian upper mantle by lower crustal material. We also present a compilation of available laser fluorination δ18O data for MORB and use these data to evaluate the nature and percentage of enriched material within the upper mantle globally. Data for each ocean basin fit a normal distribution, with indistinguishable means and standard deviations, implying that the variation in δ18O of MORB reflects a stochastic process that operates similarly across all ocean basins. Monte Carlo simulations show that the mean and standard deviation of the MORB data are robust indicators of the mean and standard deviation of the parent distribution of data. Further, although some skewness in the data cannot be ruled out, Monte Carlo results are most consistent with a normal parent distribution. This similarity in characteristics of the δ18O data between ocean basins, together with correlations of δ18O with radiogenic isotope and trace element characteristics of subsets of the data, suggest that the upper mantle globally contains an average of ∼5–10% recycled crustal material and that the depleted mantle in the absence of this component would have δ18O of ∼5.25‰. The Monte Carlo simulations also suggest that additional oxygen isotope data may be used in the future to test the ability of geodynamical models to predict the physical distribution of enriched domains within the upper mantle

The History, Relevance, and Applications of the Periodic System in Geochemistry

Geochemistry is a discipline in the earth sciences concerned with understanding the chemistry of the Earth and what that chemistry tells us about the processes that control the formation and evolution of Earth materials and the planet itself. The periodic table and the periodic system, as developed by Mendeleev and others in the nineteenth century, are as important in geochemistry as in other areas of chemistry. In fact, systemisation of the myriad of observations that geochemists make is perhaps even more important in this branch of chemistry, given the huge variability in the nature of Earth materials – from the Fe-rich core, through the silicate-dominated mantle and crust, to the volatile-rich ocean and atmosphere. This systemisation started in the eighteenth century, when geochemistry did not yet exist as a separate pursuit in itself. Mineralogy, one of the disciplines that eventually became geochemistry, was central to the discovery of the elements, and nineteenth-century mineralogists played a key role in this endeavour. Early “geochemists” continued this systemisation effort into the twentieth century, particularly highlighted in the career of V.M. Goldschmidt. The focus of the modern discipline of geochemistry has moved well beyond classification, in order to invert the information held in the properties of elements across the periodic table and their distribution across Earth and planetary materials, to learn about the physicochemical processes that shaped the Earth and other planets, on all scales. We illustrate this approach with key examples, those rooted in the patterns inherent in the periodic law as well as those that exploit concepts that only became familiar after Mendeleev, such as stable and radiogenic isotopes

Post break-up tectonic inversion across the southwestern cape of South Africa: new insights from apatite and zircon fission track thermochronometry

The south-west African margin is regarded as an example of a passive continental margin formed by continental rifting following a phase of lithospheric extension and thinning. Recent attention focused on this margin has included theoretical modelling studies of rift processes, plate kinematic studies of the opening geometry and timing, and empirical studies focused on documenting the crustal structure and offshore sedimentary record. Here, we examine the onshore geomorphic and tectonic response to rifting and breakup, with a specific focus on the SW Cape of South Africa. We present 75 new apatite and 8 new zircon fission track analyses from outcrop samples and onshore borehole profiles along the western margin of South Africa. The data are used to derive robust thermal histories that record two discrete phases of accelerated erosional cooling during the Early Cretaceous (150-130 Ma) and Late Cretaceous (100-80 Ma), respectively. Both periods of enhanced erosion are regional in extent, involved km-scale erosion, and extend well inland of the current escarpment zone, albeit with spatially variable intensity and style. The Late Cretaceous episode is also expressed more locally by tectonic reactivation and inversion of major faults causing km-scale differential displacement and erosion. The new AFT data do not exclude the possibility of modest surface uplift occurring during the Cenozoic, but they restrict the depth of regional Cenozoic erosion on the western margin to less than c. 1 km. The inferred pattern and chronology of erosion onshore is consistent with the key features and sediment accumulation patterns within the offshore Orange and Bredasdorp basins. It is suggested that the Late Cretaceous event was triggered by a combination of regional dynamic uplift augmented along the western margin and in the SW Cape by local tectonic forces arising from dextral displacement of the Falkland Plateau along the Falkland-Agulhas Fracture Zone

Letter to Lord Sandwich, Bromley, 19 November 1771.

Acknowledgesreceipt of first volume of journal of Joseph Banks; hopes to have manuscript ready in time for sanction of Banks and Capt. Cook; editing the voyages will be his principal business. (2pp)

An Account of the Voyages undertaken in the Southern Hemisphere, Volume 3

An account of the voyages undertaken by the order of His Present Majesty, for making discoveries in the Southern Hemisphere, and successively performed by Commodore Byron, Captain Wallis, Captain Carteret, and Captain Cook, in the Dolphin, the Swallow, and the Endeavour; drawn up from the journals which were kept by the several commanders, and from the papers of Joseph Banks, Esq; By John Hawkesworth, LL. D. In three volumes.An account of the voyages undertaken by the order of His Present Majesty, for making discoveries in the Southern Hemisphere, and successively performed by Commodore Byron, Captain Wallis, Captain Carteret, and Captain Cook, in the Dolphin, the Swallow, and the Endeavour; drawn up from the journals which were kept by the several commanders, and from the papers of Joseph Banks, Esq; By John Hawkesworth, LL. D. In three volumes