924 research outputs found
Hydrogen-based Energy Storage (IEA-HIA Task 32)
The International Energy Agency (IEA) in its Hydrogen Implementation Agreement (HIA) conducts the core R&D work in Tasks byMember Experts.Task 32 'Hydrogen-based Energy Storage' addresses solutions for energy storage based on hydrogen. Task 32 is the largest international collaboration in this field involving over 50 experts from 18 countries. Currently, the task consists of six working groups, porous materials, magnesium-based hydrogen and energy storage materials, complex and liquid hydrides, electrochemical storage of energy, heat storage and hydrogen storage systems for mobile applications
First Calorimetric Measurement of OI-line in the Electron Capture Spectrum of Ho
The isotope Ho undergoes an electron capture process with a
recommended value for the energy available to the decay, , of about
2.5 keV. According to the present knowledge, this is the lowest
value for electron capture processes. Because of that, Ho is the best
candidate to perform experiments to investigate the value of the electron
neutrino mass based on the analysis of the calorimetrically measured spectrum.
We present for the first time the calorimetric measurement of the atomic
de-excitation of the Dy daughter atom upon the capture of an electron
from the 5s shell in Ho, OI-line. The measured peak energy is 48 eV.
This measurement was performed using low temperature metallic magnetic
calorimeters with the Ho ion implanted in the absorber.
We demonstrate that the calorimetric spectrum of Ho can be measured
with high precision and that the parameters describing the spectrum can be
learned from the analysis of the data. Finally, we discuss the implications of
this result for the Electron Capture Ho experiment, ECHo, aiming to
reach sub-eV sensitivity on the electron neutrino mass by a high precision and
high statistics calorimetric measurement of the Ho spectrum.Comment: 5 pages, 3 figure
Detection of a dense clump in a filament interacting with W51e2
In the framework of the Herschel/PRISMAS Guaranteed Time Key Program, the
line of sight to the distant ultracompact HII region W51e2 has been observed
using several selected molecular species. Most of the detected absorption
features are not associated with the background high-mass star-forming region
and probe the diffuse matter along the line of sight. We present here the
detection of an additional narrow absorption feature at ~70 km/s in the
observed spectra of HDO, NH3 and C3. The 70 km/s feature is not uniquely
identifiable with the dynamic components (the main cloud and the large-scale
foreground filament) so-far identified toward this region. The narrow
absorption feature is similar to the one found toward low-mass protostars,
which is characteristic of the presence of a cold external envelope. The
far-infrared spectroscopic data were combined with existing ground-based
observations of 12CO, 13CO, CCH, CN, and C3H2 to characterize the 70 km/s
component. Using a non-LTE analysis of multiple transitions of NH3 and CN, we
estimated the density (n(H2) (1-5)x10^5 cm^-3) and temperature (10-30 K) for
this narrow feature. We used a gas-grain warm-up based chemical model with
physical parameters derived from the NH3 data to explain the observed
abundances of the different chemical species. We propose that the 70 km/s
narrow feature arises in a dense and cold clump that probably is undergoing
collapse to form a low-mass protostar, formed on the trailing side of the
high-velocity filament, which is thought to be interacting with the W51 main
cloud. While the fortuitous coincidence of the dense clump along the line of
sight with the continuum-bright W51e2 compact HII region has contributed to its
non-detection in the continuum images, this same attribute makes it an
appropriate source for absorption studies and in particular for ice studies of
star-forming regions.Comment: Accepted for publication in A&
The chemistry of C3 & Carbon Chain Molecules in DR21(OH)
(Abridged) We have observed velocity resolved spectra of four ro-vibrational
far-infrared transitions of C3 between the vibrational ground state and the
low-energy nu2 bending mode at frequencies between 1654--1897 GHz using HIFI on
board Herschel, in DR21(OH), a high mass star forming region. Several
transitions of CCH and c-C3H2 have also been observed with HIFI and the IRAM
30m telescope. A gas and grain warm-up model was used to identify the primary
C3 forming reactions in DR21(OH). We have detected C3 in absorption in four
far-infrared transitions, P(4), P(10), Q(2) and Q(4). The continuum sources MM1
and MM2 in DR21(OH) though spatially unresolved, are sufficiently separated in
velocity to be identified in the C3 spectra. All C3 transitions are detected
from the embedded source MM2 and the surrounding envelope, whereas only Q(4) &
P(4) are detected toward the hot core MM1. The abundance of C3 in the envelope
and MM2 is \sim6x10^{-10} and \sim3x10^{-9} respectively. For CCH and c-C3H2 we
only detect emission from the envelope and MM1. The observed CCH, C3, and
c-C3H2 abundances are most consistent with a chemical model with
n(H2)\sim5x10^{6} cm^-3 post-warm-up dust temperature, T_max =30 K and a time
of \sim0.7-3 Myr. Post warm-up gas phase chemistry of CH4 released from the
grain at t\sim 0.2 Myr and lasting for 1 Myr can explain the observed C3
abundance in the envelope of DR21(OH) and no mechanism involving
photodestruction of PAH molecules is required. The chemistry in the envelope is
similar to the warm carbon chain chemistry (WCCC) found in lukewarm corinos.
The observed lower C3 abundance in MM1 as compared to MM2 and the envelope
could be indicative of destruction of C3 in the more evolved MM1. The timescale
for the chemistry derived for the envelope is consistent with the dynamical
timescale of 2 Myr derived for DR21(OH) in other studies.Comment: 11 Pages, 6 figures, accepted for publication in A&
Effects of oxidized lipids (4,5 (E)-epoxy-2(E)-heptenal and 4,5 (E)-epoxy-2 (E) -decenal) and lysine reaction products on zinc and calcium utilization: assays in Caco-2 cells
The influence of the presence of brown products from the reaction between two oxidized lipids (4,5 (E)-epoxy-2(E)-heptenal, EH, and 4,5 (E)-epoxy-2 (E)-decenal, ED) and lysine (EH-L and ED-L) on zinc and calcium utilization was studied, and compared with a fructosyl-lysine mixture (F-L). Assays were carried out in
Caco-2 cells grown in bicameral chambers. The Zn transported across the cell monolayer was significantly lower in the presence of the EH-L, ED-L and F-L samples, specially with EH-L. Significant decreases in Zn uptake were also observed, with no
differences between samples. However, calcium transport was not modified. Thus, the assayed lipid-aminoacid brown products seem to have negative effects on Zn availability, whereas Ca availability
appears to be unaffected.Se estudió la influencia de la presencia de productos obtenidos en la reacción de dos lípidos oxidados (4,5(E)-epoxy-2(E)- heptenal, EH, y 4,5(E)-epoxy-2(E)-decenal, ED) con el aminoácido lisina (EH-L y ED-L), sobre la absorción de zinc y calcio, comparándolos frente a una mezcla de fructosil-lisina (F-L). Los ensayos se realizaron con células Caco-2 sembradas en placas bicamerales. La adición de las muestras EH-L, ED-L y F-L al medio de cultivo supuso una reducción significativa en el Zn transportado a través de la monocapa de células, mucho más marcada ante la presencia de EH-L. También se redujo significativamente la captación celular de Zn, sin diferencias entre las distintas muestras ensayadas. Sin embargo, el transporte de Ca no se vio modificado. Por lo tanto, los productos pardos lípido-aminoacídicos ensayados parecen afectar negativamente la disponibilidad del Zn, sin tener efectos notables sobre la del Ca.Peer reviewe
Characterization of the Ho Electron Capture Spectrum: A Step Towards the Electron Neutrino Mass Determination
The isotope Ho is in many ways the best candidate to perform experiments to investigate the value of the electron neutrino mass. It undergoes an electron capture process to Dy with an energy available to the decay, Q, of about 2.8 keV. According to the present knowledge, this is the lowest Q value for such transitions. Here we discuss a newly obtained spectrum of Ho, taken by cryogenic metallic magnetic calorimeters with Ho implanted in the absorbers and operated in anticoincident mode for background reduction. For the first time, the atomic deexcitation of the Dy daughter atom following the capture of electrons from the 5s shell in Ho, the OI line, was observed with a calorimetric measurement. The peak energy is determined to be 48 eV. In addition, a precise determination of the energy available for the decay Q=(2.858±0.010±0.05) keV was obtained by analyzing the intensities of the lines in the spectrum. This value is in good agreement with the measurement of the mass difference between Ho and Dy obtained by Penning-trap mass spectrometry, demonstrating the reliability of the calorimetric technique
Spatial organization in cyclic Lotka-Volterra systems
We study the evolution of a system of interacting species which mimics
the dynamics of a cyclic food chain. On a one-dimensional lattice with N<5
species, spatial inhomogeneities develop spontaneously in initially homogeneous
systems. The arising spatial patterns form a mosaic of single-species domains
with algebraically growing size, , where
(1/2) and 1/3 for N=3 with sequential (parallel) dynamics and N=4,
respectively. The domain distribution also exhibits a self-similar spatial
structure which is characterized by an additional length scale, , with and 2/3 for N=3 and 4, respectively. For
, the system quickly reaches a frozen state with non interacting
neighboring species. We investigate the time distribution of the number of
mutations of a site using scaling arguments as well as an exact solution for
N=3. Some possible extensions of the system are analyzed.Comment: 18 pages, 10 figures, revtex, also available from
http://arnold.uchicago.edu/~ebn
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Combination of Cladding Processes with Subsequent Hot Forming as a New Approach for the Production of Hybrid Components
A new process chain for the manufacturing of load-adapted hybrid components is presented. The "Tailored
Forming” process chain consists of a deposition welding process, hot forming, machining and an optional heat
treatment. This paper focuses on the combination of laser hot-wire cladding with subsequent hot forming to
produce hybrid components. The applicability is investigated for different material combinations and component
geometries, e.g. a shaft with a bearing seat or a bevel gear. Austenitic stainless steel AISI 316L and martensitic
valve steel AISI HNV3 are used as cladding materials, mild steel AISI 1022M and case hardening steel AISI 5120
are used as base materials. The resulting component properties after laser hot-wire cladding and hot forming such
as hardness, microstructure and residual stress state are presented. In the cladding and the heat-affected zone, the
hot forming process causes a transformation from a welding microstructure to a fine-grained forming
microstructure. Hot forming significantly affects the residual stress state in the cladding the resulting residual
stress state depends on the material combination.Mechanical Engineerin
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