Multiscale characterization of chemical-mechanical interactions between polymer fibers and cementitious matrix

Together with a series of mechanical tests, the interactions and potential bonding between polymeric fibers and cementitious materials were studied using scanning transmission X-ray microscopy (STXM) and microtomography (mu CT). Experimental results.showed that these techniques have great potential to characterize the polymer fiber-hydrated cement-paste matrix interface, as well as differentiating the chemistry of the two components of a bi-polymer (hybrid) fiber-the polypropylene core and the ethylene acrylic acid copolymer sheath. Similarly, chemical interactions between the hybrid fiber and the cement hydration products were observed, indicating the chemical bonding between the sheath and the hardened cement paste matrix. Microtomography allowed visualization of the performance of the samples, and the distribution and orientation of the two types of fiber in mortar. Beam flexure tests confirmed improved tensile strength of mixes containing hybrid fibers, and expansion bar tests showed similar reductions in expansion for the polypropylene and hybrid fiber mortar bars

Corporate Governance in Latin America

This paper analyzes recent trends of Latin America's institutional development regarding investor protection. In spite of the underdevelopment of the region's financial markets, there is slow movement towards legal reforms intended to protect investors and make regional markets more attractive to investors; current inadequacies in the region's legal institution's generate high levels of ownership concentration, poor access to external equity financing, and narrow equity markets. The evidence in this paper, based on firm-level data for six countries, shows that, like legal protection of investors, appropriate firm-level corporate governance is linked to lower costs for capital, better valuation, performance, and dividend payments across countries. Firms can compensate for their countries' legal deficiencies by distinguishing themselves through improved corporate governance practices, thus increasing transparency and limiting potential conflict between large and minority shareholders. Firms can additionally look for capital by issuing ADRs, as they have in recent years, although this practice undermines local capital markets. In the end, firms and regulators must improve their governance structures and shareholder protections if they are to meet the improved benchmarks of developed nations brought about by Asian, European, and U.S. scandals in recent years

Effect of volcanic ash pozzolan or limestone replacement on hydration of Portland cement

The replacement of Portland cement (PC) with either supplementary cementitious material (SCM) or fillers, such as natural pozzolans (NP) or limestone powder (LP) respectively, is known to affect the chemical properties of concrete, thus influencing its fresh and hardened properties. This study investigated the effects of volcanic ash NP or LP on setting time, normal consistency, hydration, and strength properties of cement paste and mortar while following the chemical changes that were a direct result of the substitution. While both materials were found to increase water demand, NP at 30% and 50% replacement levels increased setting time while LP at 15% replacement level insignificantly influenced the property. At a proportion lower than their replacement levels, both materials reduced the ultimate compressive strength of mortar. Thermal, chemical and microstructural analyses confirmed the participatory roles of NP and LP in controlling reaction kinetics and forming new hydration products

Development of pervious oyster shell habitat (POSH) concrete for reef restoration and living shorelines

This study investigated the development of a more durable and sustainable cementitious composite substrate for oyster reef restoration using recycled oyster shells and low cement content. The effects of concrete mix proportions (w/c ratio, sand content, and cement content) on the physical properties of the hardened concretes were investigated. Increasing the water, sand, cement, and high-range water reducing admixture content improved both the compressive and flexural strength mostly by improving the coating of cementitious materials around the shells. The proposed material for reef restoration is superior in terms of cost, durability, environmental benefits, and carbon footprint

Carbonation of calcium sulfoaluminate mortars

This study investigated potential physical and chemical parameters that could govern the carbonation rate of calcium sulfoaluminate (CSA) mortars and endeavored to elucidate the microstructural and chemical factors that govern CSA cement\u27s carbonation rate. Experiments included: water absorption, oxygen diffusion, mercury intrusion porosimetry, quantitative X-ray diffraction, thermogravimetric analysis, accelerated carbonation, compression and flexure tests. Additionally, the carbonation process was investigated using thermodynamic modeling. The results show that CSA mortars carbonate much faster than Portland cement mortars and at approximately the same rate as calcium aluminate cement mortars. Additionally, CSA mortars carbonate slower with decreasing w/c, and the anhydrite content of the CSA mortars strongly affects the ye\u27elimite reaction kinetics which plays an important role in imparting carbonation resistance in CSA mortars. Finally, calcium sulfate additions to CSA clinker to produce CSA cement dilutes the clinker content and reduces the amount of CO2 that the CSA cement can ultimately bind

The effect of water and gypsum content on strätlingite formation in calcium sulfoaluminate-belite cement pastes

The main objective of this study was to investigate the phase and strength development of calcium sulfoaluminate-belite (CSAB) cement pastes with different amounts of gypsum and water. Thermodynamic modeling and a series of experiments including X-ray diffraction (XRD), thermogravimetric analysis, isothermal calorimetry, and compressive strength tests were performed. Decreasing the mixing water increased the strength of CSAB pastes, but decreased the degree of hydration. Interpretation of the early age XRD results and thermodynamic modeling suggested the formation of a meta-stable phase from the hydration of belite, possibly C-(A)-S-H, which transformed into strätlingite at later ages only in the samples with high water content, likely due to easier diffusion of ions at higher w/c. Furthermore, the XRD results and thermodynamic modeling confirmed that the amount of gypsum controls the hydration of ye\u27elimite as well as belite in the CSAB cements

The effect of water and gypsum content on strätlingite formation in calcium sulfoaluminate-belite cement pastes

The main objective of this study was to investigate the phase and strength development of calciumsulfoaluminate-belite (CSAB) cement pastes with different amounts of gypsum and water.Thermodynamic modeling and a series of experiments including X-ray diffraction (XRD), thermogravimetric analysis, isothermal calorimetry, and compressive strength tests were performed. Decreasing the mixing water increased the strength of CSAB pastes, but decreased the degree of hydration. Interpretation of the early age XRD results and thermodynamic modeling suggested the formation of a meta-stable phase from the hydration of belite, possibly C-(A)-S-H, which transformed into strätlingite at later ages only in the samples with high water content, likely due to easier diffusion of ions at higher w/c. Furthermore, the XRD results and thermodynamic modeling confirmed that the amount of gypsum controls the hydration of ye’elimite as well as belite in the CSAB cements

First-Year Performance of the Pervious Oyster Shell Habitat (POSH) along Two Energetic Shorelines in Northeast Florida

Novel living shoreline methods are being developed to minimize negative environmental impact while maintaining strength and effectiveness in high-energy systems. The “Pervious Oyster Shell Habitat” (POSH) is a novel structure composed of oyster shells bound by a thin layer of Portland cement into the shape of a dome. The structure’s makeup greatly reduces its environmental impact while providing optimal substrate for the provision of oyster reef habitat. Previous laboratory testing has demonstrated that the structure is robust, and this follow-up study assesses the structure’s performance in the estuarine environment. Oyster and barnacle densities were compared between POSH modules and the industry standard “Oyster Ball” model Reef BallTM along two energetic shorelines in northeast Florida. Oyster densities on the POSH were high and significantly greater than on the Oyster Ball at both sites. Barnacle densities did not differ between structures and did not appear to affect oyster recruitment. The size distribution of oysters on POSH and Oyster Ball modules was measured to assess the demographics and growth of oysters over time. Overall, demographics were similar among the two structures. Differences in oyster densities and demographics were greater at our more energetic site. Results show that the POSH can be an optimal structure for early oyster recruitment and reef development in energetic systems and should be considered by restoration stakeholders

The effect of elevated curing temperatures on high ye\u27elimite calcium sulfoaluminate cement mortars

This study investigated the material properties and hydration characteristics of calcium sulfoaluminate cement (CSA) based mortars cured under 3 different initial curing temperatures. Two CSA cements with different M-values were selected. Obtained experimental results of mechanical properties, dimensional stability, and heat release were explained by hydration characteristics from X-ray diffraction, thermal gravimetric analysis, porosimetry, and thermodynamic modeling. Decomposition of ettringite decreased compressive strength but reformation of ettringite after additional curing at 30 °C helped to recover the strength in CSA cement with a high amount of calcium sulfate. CSA cement with a low amount of calcium sulfate which was designed to predominantly have monosulfate as the main hydration product, showed increased 1-day strength after higher temperature curing but this occurred was at the expense of decreased 28-day strength