10 research outputs found

    Non-Gaussian statistics for the motion of self-propelled Janus particles: Experiment versus theory

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    Spherical Janus particles are one of the most prominent examples for active Brownian objects. Here, we study the diffusiophoretic motion of such microswimmers in experiment and in theory. Three stages are found: simple Brownian motion at short times, superdiffusion at intermediate times, and finally diffusive behavior again at long times. These three regimes observed in the experiments are compared with a theoretical model for the Langevin dynamics of self-propelled particles with coupled translational and rotational motion. Besides the mean square displacement also higher displacement moments are addressed. In particular, theoretical predictions regarding the non-Gaussian behavior of self-propelled particles are verified in the experiments. Furthermore, the full displacement probability distribution is analyzed, where in agreement with Brownian dynamics simulations either an extremely broadened peak or a pronounced double-peak structure is found, depending on the experimental conditions

    Focused Electron Beam Induced Deposition of 1,1-dichloro-1-silacyclohexane, silacyclohexane and 1,3,5-trisilacyclohexane: Preliminary study on the role of low energy secondary electrons in the deposition process

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    To study the potential role of low energy secondary electrons in focused electron beam induced deposition (FEBID) we have studied FEBID using 1,1-dichloro-1-silacyclohexane, silacyclohexane and 1,3,5-trisilacyclohexane. While the first of these compounds shows appreciable cross sections for dissociative electron attachment (DEA) in the gas phase, DEA is not observed for the latter two. Dissociative ionization, on the other hand is a fairly efficient decomposition path for all three compounds. The performance of these compounds in FEBID is compared with their decomposition through low energy electrons in the gas phase and discussed in context to the role of DEA and DI in FEBID.ImPhys/Imaging PhysicsApplied Science

    Life-Cycle Assessment of a Multi-Megawatt Airborne Wind Energy System

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    A key motivation for airborne wind energy is its potential to reduce the amount of material required for the generation of renewable energy. On the other hand, the materials used for airborne systems’ components are generally linked to higher environmental impacts. This study presents comparative life-cycle analyses for future multi-megawatt airborne wind energy systems and conventional wind turbines, with both technologies operating in the same farm configuration and under matching environmental conditions. The analyses quantify the global warming potential and cumulative energy demand of the emerging and established wind energy technologies. The cumulative energy demand is subsequently also used to determine the energy payback time and the energy return on investment. The selected airborne wind energy system is based on the design of Ampyx Power, using a fixed-wing aircraft that is tethered to a generator on the ground. The conventional wind turbine is primarily based on the NREL 5 MW reference turbine. The results confirm that an airborne wind energy system uses significantly less material and generates electricity at notably lower impacts than the conventional wind turbine. Furthermore, the impacts of the wind turbine depend strongly on the local environmental conditions, while the impacts of the airborne wind energy system show only a minimal dependency. Airborne wind energy is most advantageous for operation at unfavourable environmental conditions for conventional systems, where the turbines require a large hub height.Wind Energ

    Fast and accurate enzyme activity measurements using a chip-based microfluidic calorimeter

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    Recent developments in microfluidic and nanofluidic technologies have resulted in development of new chip-based microfluidic calorimeters with potential use in different fields. One application would be the accurate high-throughput measurement of enzyme activity. Calorimetry is a generic way to measure activity of enzymes, but unlike conventional calorimeters, chip-based calorimeters can be easily automated and implemented in high-throughput screening platforms. However, application of chip-based microfluidic calorimeters to measure enzyme activity has been limited due to problems associated with miniaturization such as incomplete mixing and a decrease in volumetric heat generated. To address these problems we introduced a calibration method and devised a convenient protocol for using a chip-based microfluidic calorimeter. Using the new calibration method, the progress curve of alkaline phosphatase, which has product inhibition for phosphate, measured by the calorimeter was the same as that recorded by UV-visible spectroscopy. Our results may enable use of current chip-based microfluidic calorimeters in a simple manner as a tool for high-throughput screening of enzyme activity with potential applications in drug discovery and enzyme engineering.BT/Biocatalysi

    Turbulence attenuation in simultaneously heated and cooled annular flows at supercritical pressure

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    Heated or cooled fluids at supercritical pressure show large variations in thermophysical properties, such as the density, dynamic viscosity and molecular Prandtl number, which strongly influence turbulence characteristics. To investigate this, direct numerical simulations were performed of a turbulent flow at supercritical pressure (CO2 at 8 MPa) in an annulus with a hot inner wall and a cold outer wall. The pseudo-critical temperature lies close to the inner wall, which results in strong thermophysical property variations in that region. The turbulent shear stress and the turbulent intensities significantly decrease near the hot inner wall, but increase near the cold outer wall, which can be partially attributed to the mean dynamic viscosity and density stratification. This leads to decreased production of turbulent kinetic energy near the inner wall and vice versa near the outer wall. However, by analysing a transport equation for the coherent streak flank strength, it was found that thermophysical property fluctuations significantly affect streak evolution. Near the hot wall, thermal expansion and buoyancy tend to decrease streak coherence, while the viscosity gradient that exists across the streaks interacts with mean shear to act as either a source or a sink in the evolution equation for the coherent streak flank strength. The formation of streamwise vortices on the other hand is hindered by the torque that is the result of the kinetic energy and density gradients. Near the cold wall, the results are reversed, i.e. the coherent streak flank strength and the streamwise vortices are enhanced due to the variable density and dynamic viscosity. The results show that not only the mean stratification but also the large instantaneous thermophysical property variations that occur in heated or cooled fluids at supercritical pressure have a significant effect on turbulent structures that are responsible for the self-regeneration process in near-wall turbulence. Thus, instantaneous density and dynamic viscosity fluctuations are responsible for decreased (or increased) turbulent motions in heated (or cooled) fluids at supercritical pressure.Green Open Access added to TU Delft Institutional Repository ‘You share, we take care!’ – Taverne project https://www.openaccess.nl/en/you-share-we-take-care Otherwise as indicated in the copyright section: the publisher is the copyright holder of this work and the author uses the Dutch legislation to make this work public.Energy TechnologyRST/Reactor Physics and Nuclear MaterialsExecutive boardProcess and Energ

    Characteristics of turbulent heat transfer in an annulus at supercritical pressure

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    Heat transfer to fluids at supercritical pressure is different from heat transfer at lower pressures due to strong variations of the thermophysical properties with the temperature. We present and analyze results of direct numerical simulations of heat transfer to turbulent CO2 at 8 MPa in an annulus. Periodic streamwise conditions are imposed so that mean streamwise acceleration due to variations in the density does not occur. The inner wall of the annulus is kept at a temperature of 323 K, while the outer wall is kept at a temperature of 303 K. The pseudocritical temperature Tpc=307.7 K, which is the temperature where the thermophysical properties vary the most, can be found close to the inner wall. This work is a continuation of an earlier study, in which turbulence attenuation due to the variable thermophysical properties of a fluid at supercritical pressure was studied. In the current work, the direct effects of variations in the specific heat capacity, thermal diffusivity, density, and the molecular Prandtl number on heat transfer are investigated using different techniques. Variations in the specific heat capacity cause significant differences between the mean nondimensionalized temperature and enthalpy profiles. Compared to the enthalpy fluctuations, temperature fluctuations are enhanced in regions with low specific heat capacity and diminished in regions with a large specific heat capacity. The thermal diffusivity causes local changes to the mean enthalpy gradient, which in turn affects molecular conduction of thermal energy. The turbulent heat flux is directly affected by the density, but it is also affected by the mean molecular Prandtl number and attenuated or enhanced turbulent motions. In general, enthalpy fluctuations are enhanced in regions with a large mean molecular Prandtl number, which enhances the turbulent heat flux. While analyzing the Nusselt numbers under different conditions it is found that heat transfer deterioration or enhancement can occur without streamwise acceleration or mixed convection conditions. Finally, through a combination of a relation between the Nusselt number and the radial heat fluxes, a quadrant analysis of the turbulent heat flux, and conditional averaging of the heat flux quadrants, it is shown that heat transfer from a heated surface depends on the density and the molecular Prandtl number of both hot fluid moving away from a heated surface as well as the thermophysical properties of relatively cold fluid moving towards it.Energy TechnologyRST/Reactor Physics and Nuclear MaterialsExecutive boardProcess and Energ

    Telecom-Band Quantum Interference of Frequency-Converted Photons from Remote Detuned NV Centers

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    Entanglement distribution over quantum networks has the promise of realizing fundamentally new technologies. Entanglement between separated quantum processing nodes has been achieved on several experimental platforms in the past decade. To move toward metropolitan-scale quantum network test beds, the creation and transmission of indistinguishable single photons over existing telecom infrastructure is key. Here, we report the interference of photons emitted by remote spectrally detuned NV-center-based network nodes, using quantum frequency conversion to the telecom L band. We find a visibility of 0.79±0.03 and an indistinguishability between converted NV photons around 0.9 over the full range of the emission duration, confirming the removal of the spectral information present. Our approach implements fully separated and independent control over the nodes, time multiplexing of control and quantum signals, and active feedback to stabilize the output frequency. Our results demonstrate a working principle that can be readily employed on other platforms and shows a clear path toward generating metropolitan-scale solid-state entanglement over deployed telecom fibers.QuTechQID/Hanson LabQN/vanderSarlabQID/Taminiau LabQID/Software GroupBUS/TNO STAFFQN/Hanson La

    SPORT : a system for processing reactor transient data on the IBM-7040 computer /

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    To facilitate the processing and analysis of data recorded during transient tests in the Spert reactors, a system of programs for the IBM-7040 computer has been developed to (a) smooth and store data so they are readily accessible, (b) calculate from the power history the reactivity and energy release as functions of time, and (c) provide a means by which frequency response analyses of data can be made. This report describes the mathematics employed in the various programs in the system and the procedures necessary to process data with the system. Test and sample problems are presented, and a complete listing of the source program is included."National Reactor Testing Station"--Cover."Phillips Petroleum Company, Atomic Energy Division, Contract AT(10-1)-205.""Reactor Technology ; TID-4500, (41st Ed.).""Issued: July 1965."Includes bibliographical references (p. 116).To facilitate the processing and analysis of data recorded during transient tests in the Spert reactors, a system of programs for the IBM-7040 computer has been developed to (a) smooth and store data so they are readily accessible, (b) calculate from the power history the reactivity and energy release as functions of time, and (c) provide a means by which frequency response analyses of data can be made. This report describes the mathematics employed in the various programs in the system and the procedures necessary to process data with the system. Test and sample problems are presented, and a complete listing of the source program is included.Mode of access: Internet

    Die Auswirkungen des Klimawandels auf die BiodiversitÀt

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