Microanalysis of dissolved iron and phosphate in pore waters of hypersaline sediment

Diurnal fluctuations of reduced iron concentrations, expected to occur in reduced sediments in the photic zone, were studied. Iron concentration was compared to O2-H2S, a microcanalysis of sulfate reduction was performed, as well as an examination of diurnal concentration of dissolved phosphate and changes in interstitial CO2. The iron profiles suggest a strong correlation between iron remobilization and processes occurring in the light. Phosphate profiles suggest the removal of phosphate is strongly correlated with precipitation of oxidized iron in the upper 2 mm to 5 mm of the sediments. Pore water CO2 concentrations and carbon isotope ratios are presented. These data are from the analyses of minisediment cores collected from the 42 per mil salt pond and incubated in the laboratory under light and dark conditions

Critical behavior of an Ising model with aperiodic interactions

We write exact renormalization-group recursion relations for a ferromagnetic Ising model on the diamond hierarchical lattice with an aperiodic distribution of exchange interactions according to a class of generalized two-letter Fibonacci sequences. For small geometric fluctuations, the critical behavior is unchanged with respect to the uniform case. For large fluctuations, the uniform fixed point in the parameter space becomes fully unstable. We analyze some limiting cases, and propose a heuristic criterion to check the relevance of the fluctuations.Comment: latex file, 5 figures, accepted by Braz. Jour. Phy

Some urban facts of life

This review of recent literature explores the challenges to urban food and nutrition security in the rapidly urbanizing developing world. The premise of the manuscript is that the causes of malnutrition and food insecurity in urban and rural areas are different due primarily to a number of phenomena that are unique to or exacerbated by urban living. These areas include (1) a greater dependence on cash income; (2) weaker informal safety nets; (3) greater labor force participation of women and its consequences for child care; (4) lifestyle changes, particularly diet and exercise patterns; (5) greater availability of public services, but questionable access by the poor; (6) greater exposure to environmental contamination; and (7) governance by a new, possibly nonexistent, set of property rights. The main focus is on identifying what is different about urban areas, so as to better frame the program and policy responses.Urbanization. ,employment ,Child care ,Malnutrition. ,Labor ,Food security. ,Nutrition ,Property rights ,

Development of a Virtual Laparoscopic Trainer using Accelerometer Augmented Tools to Assess Performance in Surgical training

Previous research suggests that virtual reality (VR) may supplement conventional training in laparoscopy. It may prove useful in the selection of surgical trainees in terms of their dexterity and spatial awareness skills in the near future. Current VR training solutions provide levels of realism and in some instances, haptic feedback, but they are cumbersome by being tethered and not ergonomically close to the actual surgical instruments for weight and freedom of use factors. In addition, they are expensive hence making them less accessible to departments than conventional box trainers. The box trainers in comparison, although more economical, lack tangible feedback and realism for handling delicate tissue structures. We have previously reported on the development of a modified digitally enhanced surgical instrument for laparoscopic training, named the Parkar Tool. This tool contains wireless accelerometer and gyroscopic sensors integrated into actual laparoscopic instruments. By design, it alleviates the need for both tethered and physically different shaped tools thereby enhancing the realism when performing surgical procedures. Additionally the software (Valhalla) has the ability to digitally record surgical motions, thereby enabling it to remotely capture surgical training data to analyse and objectively evaluate performance. We have adapted and further developed our initial single training tool method as used with a laparoscopic pyloromyotomy scenario, to an enhanced method using multiple Parkar wireless tools simultaneously, for use in several different case scenarios. This allows the use and measurement of right and left handed dexterity with the benefit of using several tasks of differing complexity. The development of a 3D tissue-surface deformations solution written in OpenGL gives us several different virtual surgical training scenario approximations to use with the instruments. The trainee can start with learning simple tasks e.g. incising tissue, grasping, squeezing and stretching tissue, to more complex procedures such as suturing, herniotomies, bowel anastomoses, as well as the original pyloromyotomy as used in the first model

On dispersion and characteristic motions of temperature rate dependent materials

Three dimensional theory of thermomechanical material developed using techniques of continuum mechanics and law of thermodynamic

Field behavior of an Ising model with aperiodic interactions

We derive exact renormalization-group recursion relations for an Ising model, in the presence of external fields, with ferromagnetic nearest-neighbor interactions on Migdal-Kadanoff hierarchical lattices. We consider layered distributions of aperiodic exchange interactions, according to a class of two-letter substitutional sequences. For irrelevant geometric fluctuations, the recursion relations in parameter space display a nontrivial uniform fixed point of hyperbolic character that governs the universal critical behavior. For relevant fluctuations, in agreement with previous work, this fixed point becomes fully unstable, and there appears a two-cycle attractor associated with a new critical universality class.Comment: 9 pages, 1 figure (included). Accepted for publication in Int. J. Mod. Phys.

Occupational safety considerations with hydrazine fuels

A simple pharmacokinetic model and a specially designed dermal vapor exposure chamber which provides respiratory protection were used to determine the rate of penetration of hydrazine and 1,1-dimethylhydrazine (UDMH) vapor through the skin of rats. Parameters for the pharmacokinetic model were determined from intravenous and inhalation exposure data. The model was then used to estimate the skin permeation coefficient for hydrazine or UDMH vapor from the dermal-vapor exposure data. This analysis indicates that UDMH vapor has a relatively high permeability through skin (0.7 cm/hr), a value somewhat higher than was obtained for hydrazine by the same procedure (0.09 cm/hr). Based on these skin permeability results, a skin-only vapor exposure limit giving protection equivalent to the inhalation Threshold Limit Value (TLV) could be calculated. The current TLV's for UDMH and hydrazine are 0.5 and 0.1 ppm, respectively. The corresponding skin-only TLV equivalents, for personnel wearing respiratory protection, are 32 ppm for UDMH and 48 ppm for hydrazine. Should the proposed lowering to the TLV's for these compounds to 0.01 ppm be adopted, the equivalent skin-only TLV's would become 0.64 ppm for UDMH and 4.8 for hydrazine