288 research outputs found
Resonance structure in low-energy electron scattering from OCS
Energy-dependent absolute angle-differential cross sections (θ = 135°) for elastic and vibrationally inelastic electron scattering from OCS molecules have been investigated at high resolution (13 meV). The elastic cross section, reported over the range E= 0.06–20 eV, exhibits a deep Ramsauer–Townsend minimum near 0.55 eV and the π*(1.2 eV) and σ*(3.8 eV) resonances known from earlier experimental and theoretical work. The excitation functions for vibrational excitation (VE) of the fundamental CS stretch (1 0 0), the CO stretch (0 0 1) as well as for the fundamental and harmonics of the bending (0 n 0) mode are reported from threshold up to E = 8 eV. VE is mediated—in part in a mode-selective way—by threshold peaks and the higher lying resonances. The selectivity in the threshold region can be rationalized in terms of symmetry arguments where the ²Σ virtual state excites preferentially the σ vibrational states with even quanta of bending vibration over the π vibrational states with odd quanta of bending vibration. The σ*CS resonance is essentially inactive in VE of the CO stretch and the bending mode
Spin polarization of light atoms in jellium: Detailed electronic structures
We revisit the problem of the spontaneous magnetization of an {\em sp}
impurity atom in a simple metal host. The main features of interest are: (i)
Formation of the spherical spin density/charge density wave around the
impurity; (ii) Considerable decrease in the size of the pseudoatom in the
spin-polarized state as compared with the paramagnetic one, and (iii) Relevance
of the electron affinity of the isolated atom to this spin polarization, which
is clarified by tracing the transformation of the pseudoatom into an isolated
negative ion in the low-density limit of the enveloping electron gas.Comment: 4 pages, 4 figures, accepted to Phys. Rev.
Electron attachment to SF6 and lifetimes of SF6- negative ions
We study the process of low-energy electron capture by the SF6 molecule. Our
approach is based on the model of Gauyacq and Herzenberg [J. Phys. B 17, 1155
(1984)] in which the electron motion is coupled to the fully symmetric
vibrational mode through a weakly bound or virtual s state. By tuning the two
free parameters of the model, we achieve an accurate description of the
measured electron attachment cross section and good agreement with vibrational
excitation cross sections of the fully symmetric mode. An extension of the
model provides a limit on the characteristic time of intramolecular vibrational
relaxation in highly-excited SF6-. By evaluating the total vibrational spectrum
density of SF6-, we estimate the widths of the vibrational Feshbach resonances
of the long-lived negative ion. We also analyse the possible distribution of
the widths and its effect on the lifetime measurements, and investigate
nonexponential decay features in metastable SF6-.Comment: 22 pages, 10 figures, submitted to Phys. Rev.
High resolution studies of low-energy electron attachment to SF5Cl: Product anions and absolute cross sections
Low energy electron attachment to SFCl was studied at high energy resolution by mass spectrometric detection of the product anions. Two variants of the laser photoelectron attachment (LPA) technique (Kaiserslautern) were used for determining the threshold behaviour of the yield for SF formation at about 1 meV resolution, and to investigate the relative cross sections for Cl, FCl, and SF formation towards higher energies (up to 1 eV) at about 20 meV resolution. Thermal swarm measurements (Birmingham) were used to place the relative LPA cross sections on an absolute scale. A trochoidal electron monochromator (Innsbruck) was used for survey measurements of the relative cross sections for the different product anions over the energy range of 0-14 eV with a resolution of 0.30 eV. Combined with earlier beam data (taken at Berlin, J. Chem. Phys. 88 (1988) 149), the present experimental results provide a detailed set of partial cross sections for anion formation in low-energy electron collisions with SFCl
Rotational hybridization, and control of alignment and orientation in triatomic ultralong-range Rydberg molecules
We explore the electronic structure and rovibrational properties of an ultralong-range triatomic Rydberg molecule formed by a Rydberg atom and a ground state heteronuclear diatomic molecule. We focus here on the interaction of a Rb() Rydberg atom with a KRb(N = 0) diatomic polar molecule. There is significant electronic hybridization with the Rb(n = 24, ) degenerate manifold. The polar diatomic molecule is allowed to rotate in the electric fields generated by the Rydberg electron and core as well as an external field. We investigate the metamorphosis of the Born–Oppenheimer potential curves, essential for the binding of the molecule, with varying electric field and analyze the resulting properties such as the vibrational structure and the alignment and orientation of the polar diatomic molecule.RGF gratefully acknowledges a Mildred Dresselhaus award from the excellence cluster 'The Hamburg Center for Ultrafast Imaging Structure, Dynamics and Control of Matter at the Atomic Scale' of the Deutsche Forschungsgemeinschaft and financial support by the Spanish Ministry of Science FIS2011-24540 (MICINN), grants P11-FQM-7276 and FQM-4643 (Junta de AndalucÃa), and by the Andalusian research group FQM-207. We also acknowledge financial support by the Initial Training Network COHERENCE of the European Union FP7 framework. HRS and PS acknowledge ITAMP at the Harvard-Smithsonian Center for Astrophysics for support
Three-photon detachment of electrons from the fluorine negative ion
Absolute three-photon detachment cross sections are calculated for the
fluorine negative ion within the lowest-order perturbation theory. The Dyson
equation of the atomic many-body theory is used to obtain the ground-state 2p
wavefunction with correct asymptotic behaviour, corresponding to the true
(experimental) binding energy. We show that in accordance with the adiabatic
theory (Gribakin and Kuchiev 1997 {Phys. Rev. A} {\bf 55} 3760) this is crucial
for obtaining absolute values of the multiphoton cross sections. Comparisons
with other calculations and experimental data are presented.Comment: 10 pages, two figures, Latex, IOP styl
Electron attachment to valence-excited CO
The possibility of electron attachment to the valence state of CO
is examined using an {\it ab initio} bound-state multireference configuration
interaction approach. The resulting resonance has symmetry;
the higher vibrational levels of this resonance state coincide with, or are
nearly coincident with, levels of the parent state. Collisional
relaxation to the lowest vibrational levels in hot plasma situations might
yield the possibility of a long-lived CO state.Comment: Revtex file + postscript file for one figur
Evaporative attachment of slow electrons to alkali nanoclusters
The abundance spectrum of Na^-_{n~7-140} anions formed by low energy electron
attachment to free nanoclusters is measured to be strongly and nontrivially
restructured with respect to the neutral precursor beam. This restructuring is
explained in quantitative detail by a general framework of evaporative
attachment: an electron is captured by the long-range polarization potential,
its energy is transferred into thermal vibrations, and dissipated by
evaporative cooling. The data also affirm a formulated relation between the
binding energies of cationic, neutral, and anionic clusters, and an adjustment
to the prior values of dimer evaporation energies.Comment: 9 pages, 3 figures, revise
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