Rotation-Induced Breakdown of Torsional Quantum Control

Control of the torsional angles of nonrigid molecules is key for the development of emerging areas like molecular electronics and nanotechnology. Based on a rigorous calculation of the rotation-torsion-Stark energy levels of nonrigid biphenyl-like molecules, we show that, unlike previously believed, instantaneous rotation-torsion-Stark eigenstates of such molecules, interacting with a strong laser field, present a large degree of delocalization in the torsional coordinate even for the lowest energy states. This is due to a strong coupling between overall rotation and torsion leading to a breakdown of the torsional alignment. Thus, adiabatic control of changes on the planarity of this kind of molecule is essentially impossible unless the temperature is on the order of a few Kelvin

Differential elastic electron scattering cross sections for CCl₄ by 1.5–100 eV energy electron impact

We report absolute elastic differential, integral and momentum transfer cross sections for electron interactions with CCl₄. The incident electron energy range is 1.5-100 eV, and the scattered electron angular range for the differential measurements varies from 15°-130°. The absolute scale of the differential cross section was set using the relative flow technique with helium as the reference species. Comparison with previous total cross sections shows good agreement. Atomic-like behaviour in this scattering system is shown here for the first time, and is further investigated by comparing the CCl₄ elastic cross sections to recent results on the halomethanes and atomic chlorine at higher impact energies [H. Kato, T. Asahina, H. Masui, M. Hoshino, H. Tanaka, H. Cho, O. Ingólfsson, F. Blanco, G. Garcia, S. J. Buckman, and M. J. Brunger, J. Chem. Phys. 132, 074309 (2010)].This work was conducted under the support of the Japanese Ministry of Education, Sport, Culture and Technology. H.K. acknowledges the Japan Society for the Promotion of Science (JSPS) for his fellowships as grants-in-aid for scientific research. S.J.B also acknowledges the JSPS Invitation Fellowship for Research in Japan

Rare earth element geochemistry in zircons from basaltic eucrites.

第2回極域科学シンポジウム/第34回南極隕石シンポジウム 11月18日（金） 国立国語研究所 2階講

First-principles study on scanning tunneling microscopy images of hydrogen-terminated Si(110) surfaces

Scanning tunneling microscopy images of hydrogen-terminated Si(110) surfaces are studied using first-principles calculations. Our results show that the calculated filled-state images and local density of states are consistent with recent experimental results, and the empty-state images appear significantly different from the filled-state ones. To elucidate the origin of this difference, we examined in detail the local density of states, which affects the images, and found that the bonding and antibonding states of surface silicon atoms largely affect the difference between the filled- and empty-state images.Comment: 4 pages, and 4 figure

The developmental process of flood shoals based on observations in Toufutsu lake, Japan

Recently, the flood tidal sand bars have been developed at the entrance channel of Toufutsu Lake located along Okhotsk Sea in Hokkaido, and they affect flood control, inland water fisheries in lake, and so forth. In this study, we aimed to reveal the developmental process of sand bars by observations, which are velocity observation, water level observation, bed material investigation and video monitoring. Followings were major accomplishments of this study. (1) The maximum magnitude of reverse velocity at St.400 in the entrance channel during the periods of flood-tide was faster than that of normal velocity during the periods of ebb-tide. (2) The relationship between velocity at SP400 and friction velocity at SP400 during the periods of flood-tide is different from that during the periods of ebb-tide. (3) The\ud flood tidal sand bars at the entrance channel of Toufutsu Lake were developed by not only sea waves, but also adverse tidal current in the spring-tide

Spectrum of Disorders Associated with Elevated Serum IgG4 Levels Encountered in Clinical Practice

IgG4-related disease (IgG4-RD) is a recently described systemic fibroinflammatory disease associated with elevated circulating levels of IgG4 and manifests a wide spectrum of clinical presentations. Although serum IgG4 level has been described to be the most sensitive and specific laboratory test for the diagnosis of IgG4-RD, it is recognized that an elevated serum IgG4 level can be encountered in other diseases. In this study, we sought to identify the frequency of IgG4-RD and other disease associations in patients with elevated serum IgG4 levels seen in clinical practice. Among 3,300 patients who underwent IgG subclass testing over a 2-year period from January 2009 to December 2010, 158 (4.8%) had an elevated serum IgG4 level (>140 mg/dL). IgG4 subclass testing was performed for evaluation of suspected IgG4-RD or immunodeficiency. Twenty-nine patients (18.4%) had definite or possible IgG4-RD. Among those patients without IgG4-RD, a broad spectrum of biliary tract, pancreatic, liver, and lung diseases, as well as systemic vasculitis, was diagnosed. We conclude that patients with elevated serum IgG4 levels encountered in clinical practice manifest a wide array of disorders, and only a small minority of them has IgG4-RD