Optical second harmonic generation from Wannier excitons

Excitonic effects in the linear optical response of semiconductors are well-known and the subject of countless experimental and theoretical studies. For the technologically important second order nonlinear response, however, description of excitonic effects has proved to be difficult. In this work, a simplified three-band Wannier exciton model of cubic semiconductors is applied and a closed form expression for the complex second harmonic response function including broadening is derived. Our calculated spectra are found to be in excellent agreement with the measured response near the band edge. In addition, a very substantial enhancement of the nonlinear response is predicted for the transparency region

Quantum spill out in few-nanometer metal gaps: Effect on gap plasmons and reflectance from ultrasharp groove arrays

Plasmons in ultranarrow metal gaps are highly sensitive to the electron density profile at the metal surfaces. Using a fully quantum mechanical approach, we study the effects of electron spill-out on gap plasmons and reflectance from ultrasharp metal grooves. We demonstrate that the mode index of ultranarrow gap plasmons converges to the bulk refractive index in the limit of vanishing gap and, thereby, rectify the unphysical divergence found in classical models. Surprisingly, spill-out also significantly increases the plasmonic absorption for few-nanometer gaps and lowers the reflectance from arrays of ultrasharp metal grooves. These findings are explained in terms of enhanced gap plasmon absorption taking place inside the gap 1-2 {\AA} from the walls and delocalization near the groove bottom. Reflectance calculations taking spill-out into account are shown to be in much better agreement with measurements compared with classical models

Optical properties of graphene antidot lattices

Undoped graphene is semi-metallic and thus not suitable for many electronic and optoelectronic applications requiring gapped semiconductor materials. However, a periodic array of holes (antidot lattice) renders graphene semiconducting with a controllable band gap. Using atomistic modelling, we demonstrate that this artificial nanomaterial is a dipole-allowed direct gap semiconductor with a very pronounced optical absorption edge. Hence, optical infrared spectroscopy should be an ideal probe of the electronic structure. To address realistic experimental situations, we include effects due to disorder and the presence of a substrate in the analysis.Comment: 11 pages, 9 figures, accepted for publication in Phys. Rev.

Quantum spill-out in nanometer-thin gold slabs: Effect on plasmon mode index and plasmonic absorption

A quantum mechanical approach and local response theory are applied to study plasmons propagating in nanometer-thin gold slabs sandwiched between different dielectrics. The metal slab supports two different kinds of modes, classified as long-range and short-range plasmons. Quantum spill-out is found to significantly increase the imaginary part of their mode indices, and, surprisingly, even for slabs wide enough to approach bulk the increase is 20%. This is explained in terms of enhanced plasmonic absorption, which mainly takes place at narrow peaks located near the slab surface

Artificial Intelligence: Application Today and Implications Tomorrow

This paper analyzes the applications of artificial intelligence to the legal industry, specifically in the fields of legal research and contract drafting. First, it will look at the implications of artificial intelligence (A.I.) for the current practice of law. Second, it will delve into the future implications of A.I. on law firms and the possible regulatory challenges that come with A.I. The proliferation of A.I. in the legal sphere will give laymen (clients) access to the information and services traditionally provided exclusively by attorneys. With an increase in access to these services will come a change in the role that lawyers must play. A.I. is a tool that will increase access to cheaper and more efficient services, but non-lawyers lack the training to analyze and understand information it puts out. The role of lawyers will change to fill this role, namely utilizing these tools to create a better work product with greater efficiency for their clients

Entanglement entropy of fermions in any dimension and the Widom conjecture

We show that entanglement entropy of free fermions scales faster then area law, as opposed to the scaling $L^{d-1}$ for the harmonic lattice, for example. We also suggest and provide evidence in support of an explicit formula for the entanglement entropy of free fermions in any dimension $d$, $S\sim c(\partial\Gamma,\partial\Omega)\cdot L^{d-1}\log L$ as the size of a subsystem $L\to\infty$, where $\partial\Gamma$ is the Fermi surface and $\partial\Omega$ is the boundary of the region in real space. The expression for the constant $c(\partial\Gamma,\partial\Omega)$ is based on a conjecture due to H. Widom. We prove that a similar expression holds for the particle number fluctuations and use it to prove a two sided estimates on the entropy $S$.Comment: Final versio

Superselection in the presence of constraints

For systems which contain both superselection structure and constraints, we study compatibility between constraining and superselection. Specifically, we start with a generalisation of Doplicher-Roberts superselection theory to the case of nontrivial centre, and a set of Dirac quantum constraints and find conditions under which the superselection structures will survive constraining in some form. This involves an analysis of the restriction and factorisation of superselection structures. We develop an example for this theory, modelled on interacting QED.Comment: Latex, 38 page

Conditional expectations associated with quantum states

An extension of the conditional expectations (those under a given subalgebra of events and not the simple ones under a single event) from the classical to the quantum case is presented. In the classical case, the conditional expectations always exist; in the quantum case, however, they exist only if a certain weak compatibility criterion is satisfied. This compatibility criterion was introduced among others in a recent paper by the author. Then, state-independent conditional expectations and quantum Markov processes are studied. A classical Markov process is a probability measure, together with a system of random variables, satisfying the Markov property and can equivalently be described by a system of Markovian kernels (often forming a semigroup). This equivalence is partly extended to quantum probabilities. It is shown that a dynamical (semi)group can be derived from a given system of quantum observables satisfying the Markov property, and the group generators are studied. The results are presented in the framework of Jordan operator algebras, and a very general type of observables (including the usual real-valued observables or self-adjoint operators) is considered.Comment: 10 pages, the original publication is available at http://www.aip.or

Calibration of the Mass-Temperature Relation for Clusters of Galaxies Using Weak Gravitational Lensing

The main uncertainty in current determinations of the power spectrum normalization, sigma_8, from abundances of X-ray luminous galaxy clusters arises from the calibration of the mass-temperature relation. We use our weak lensing mass determinations of 30 clusters from the hitherto largest sample of clusters with lensing masses, combined with X-ray temperature data from the literature, to calibrate the normalization of this relation at a temperature of 8 keV, M_{500c,8 keV}=(8.7 +/- 1.6) h^{-1} 10^{14} M_sun. This normalization is consistent with previous lensing-based results based on smaller cluster samples, and with some predictions from numerical simulations, but higher than most normalizations based on X-ray derived cluster masses. Assuming the theoretically expected slope alpha=3/2 of the mass-temperature relation, we derive sigma_8 = 0.88 +/-0.09 for a spatially-flat LambdaCDM universe with Omega_m = 0.3. The main systematic errors on the lensing masses result from extrapolating the cluster masses beyond the field-of-view used for the gravitational lensing measurements, and from the separation of cluster/background galaxies, contributing each with a scatter of 20%. Taking this into account, there is still significant intrinsic scatter in the mass-temperature relation indicating that this relation may not be very tight, at least at the high mass end. Furthermore, we find that dynamically relaxed clusters are 75 +/-40% hotter than non-relaxed clusters.Comment: 8 pages, 4 figures, revised version submitted to Ap

A mapping approach to synchronization in the "Zajfman trap": stability conditions and the synchronization mechanism

We present a two particle model to explain the mechanism that stabilizes a bunch of positively charged ions in an "ion trap resonator" [Pedersen etal, Phys. Rev. Lett. 87 (2001) 055001]. The model decomposes the motion of the two ions into two mappings for the free motion in different parts of the trap and one for a compressing momentum kick. The ions' interaction is modelled by a time delay, which then changes the balance between adjacent momentum kicks. Through these mappings we identify the microscopic process that is responsible for synchronization and give the conditions for that regime.Comment: 12 pages, 9 figures; submitted to Phys Rev