Creation of a homogeneous plasma column by means of hohlraum radiation for ion-stopping measurements

In this work, we present the results of two-dimensional radiation-hydrodynamics simulations of a hohlraum target whose outgoing radiation is used to produce a homogeneously ionized carbon plasma for ion-beam stopping measurements. The cylindrical hohlraum with gold walls is heated by a frequency-doubled ($\lambda_l = 526.5$ $\mu m$) $1.4$ $ns$ long laser pulse with the total energy of $E_l = 180$ $J$. At the laser spot, the peak matter and radiation temperatures of, respectively, $T \approx 380$ $eV$ and $T_r \approx 120$ $eV$ are observed. X-rays from the hohlraum heat the attached carbon foam with a mean density of $\rho_C = 2$ $mg/cm^3$ to a temperature of $T \approx 25$ $eV$. The simulation shows that the carbon ionization degree ($Z \approx 3.75$) and its column density stay relatively stable (within variations of about $\pm7\%$) long enough to conduct the ion-stopping measurements. Also, it is found that a special attention should be paid to the shock wave, emerging from the X-ray heated copper support plate, which at later times may significantly distort the carbon column density traversed by the fast ions.Comment: 12 pages, 12 figure

Suzuki-Miyaura Cross-Coupling of Unprotected, Nitrogen-Rich Heterocycles: Substrate Scope and Mechanistic Investigation

The Suzuki-Miyaura cross-coupling of unprotected, nitrogen-rich heterocycles using precatalysts P1 or P2 is reported. The procedure allows for the reaction of variously substituted indazole, benzimidazole, pyrazole, indole, oxindole, and azaindole halides under mild conditions in good to excellent yields. Additionally, the mechanism behind the inhibitory effect of unprotected azoles on Pd-catalyzed cross-coupling reactions is described based on evidence gained through experimental, crystallographic, and theoretical investigations.National Institutes of Health (U.S.) (Award GM46059)German Science Foundation (Postdoctoral Fellowship