1,023 research outputs found
A Second-Generation Janus Scorpionate Ligand: Controlling Coordination Modes in Iron(II) Complexes by Steric Modulation
The second-generation Janus scorpionate ligand [HB(mtdaMe)3−] containing methyl-mercaptothiadiazolyl (mtdaMe) heterocyclic rings and (N,N,N-) and (S,S,S-) binding pockets has been prepared. The effect of methyl substitution versus the unsubstituted first-generation Janus scorpionate [HB(mtda)3]− on the coordination chemistry with alkali metals and on the binding preferences and on the ground spin state of iron(II) complexes has been studied structurally and by 57Fe Mossbauer Spectroscopy
Cavity-enhanced optical Hall effect in two-dimensional free charge carrier gases detected at terahertz frequencies
The effect of a tunable, externally coupled Fabry-P\'{e}rot cavity to
resonantly enhance the optical Hall effect signatures at terahertz frequencies
produced by a traditional Drude-like two-dimensional electron gas is shown and
discussed in this communication. As a result, the detection of optical Hall
effect signatures at conveniently obtainable magnetic fields, for example by
neodymium permanent magnets, is demonstrated. An AlInN/GaN-based high electron
mobility transistor structure grown on a sapphire substrate is used for the
experiment. The optical Hall effect signatures and their dispersions, which are
governed by the frequency and the reflectance minima and maxima of the
externally coupled Fabry-P\'{e}rot cavity, are presented and discussed. Tuning
the externally coupled Fabry-P\'{e}rot cavity strongly modifies the optical
Hall effect signatures, which provides a new degree of freedom for optical Hall
effect experiments in addition to frequency, angle of incidence and magnetic
field direction and strength
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Spontaneous Polarisation Build up in a Room Temperature Polariton Laser
We observe the build up of strong (~50%) spontaneous vector polarisation in
emission from a GaN-based polariton laser excited by short optical pulses at
room temperature. The Stokes vector of emitted light changes its orientation
randomly from one excitation pulse to another, so that the time-integrated
polarisation remains zero. This behaviour is completely different to any
previous laser. We interpret this observation in terms of the spontaneous
symmetry breaking in a Bose-Einstein condensate of exciton-polaritons
Colossal Positive Magnetoresistance in a Doped Nearly Magnetic Semiconductor
We report on a positive colossal magnetoresistance (MR) induced by
metallization of FeSb, a nearly magnetic or "Kondo" semiconductor with 3d
ions. We discuss contribution of orbital MR and quantum interference to
enhanced magnetic field response of electrical resistivity.Comment: 5 pages, 5 figure
Genetic diversity of Mycobacterium tuberculosis in Peru and exploration of phylogenetic associations with drug resistance.
BACKGROUND: There is limited available data on the strain diversity of M tuberculosis in Peru, though there may be interesting lessons to learn from a setting where multidrug resistant TB has emerged as a major problem despite an apparently well-functioning DOTS control programme. METHODS: Spoligotyping was undertaken on 794 strains of M tuberculosis collected between 1999 and 2005 from 553 community-based patients and 241 hospital-based HIV co-infected patients with pulmonary tuberculosis in Lima, Peru. Phylogenetic and epidemiologic analyses permitted identification of clusters and exploration of spoligotype associations with drug resistance. RESULTS: Mean patient age was 31.9 years, 63% were male and 30.4% were known to be HIV+. Rifampicin mono-resistance, isoniazid mono-resistance and multidrug resistance (MDR) were identified in 4.7%, 8.7% and 17.3% of strains respectively. Of 794 strains from 794 patients there were 149 different spoligotypes. Of these there were 27 strains (3.4%) with novel, unique orphan spoligotypes. 498 strains (62.7%) were clustered in the nine most common spoligotypes: 16.4% SIT 50 (clade H3), 12.3% SIT 53 (clade T1), 8.3% SIT 33 (LAM3), 7.4% SIT 42 (LAM9), 5.5% SIT 1 (Beijing), 3.9% SIT 47 (H1), 3.0% SIT 222 (clade unknown), 3.0% SIT1355 (LAM), and 2.8% SIT 92 (X3). Amongst HIV-negative community-based TB patients no associations were seen between drug resistance and specific spoligotypes; in contrast HIV-associated MDRTB, but not isoniazid or rifampicin mono-resistance, was associated with SIT42 and SIT53 strains. CONCLUSION: Two spoligotypes were associated with MDR particularly amongst patients with HIV. The MDR-HIV association was significantly reduced after controlling for SIT42 and SIT53 status; residual confounding may explain the remaining apparent association. These data are suggestive of a prolonged, clonal, hospital-based outbreak of MDR disease amongst HIV patients but do not support a hypothesis of strain-specific propensity for the acquisition of resistance-conferring mutations
Theory of Adsorption and Surfactant Effect of Sb on Ag (111)
We present first-principles studies of the adsorption of Sb and Ag on clean
and Sb-covered Ag (111). For Sb, the {\it substitutional} adsorption site is
found to be greatly favored with respect to on-surface fcc sites and to
subsurface sites, so that a segregating surface alloy layer is formed. Adsorbed
silver adatoms are more strongly bound on clean Ag(111) than on Sb-covered Ag.
We propose that the experimentally reported surfactant effect of Sb is due to
Sb adsorbates reducing the Ag adatom mobility. This gives rise to a high
density of Ag islands which coalesce into regular layers.Comment: RevTeX 3.0, 11 pages, 0 figures] 13 July 199
The influence of protocol design on the identification of ventilatory thresholds and the attainment of peak physiological responses during synchronous arm crank ergometry in able-bodied participants
Purpose To examine the effects of stage duration on power output (PO), oxygen uptake (VO2), and heart rate (HR) at peak level and ventilatory thresholds during synchronous arm crank ergometry. Methods Nineteen healthy participants completed a ramp, 1-min stepwise, and 3-min stepwise graded arm crank exercise test. PO, VO2, and HR at the first and second ventilatory threshold (VT1, VT2) and peak level were compared among the protocols: a repeated measures analysis of variance was performed to test for systematic differences, while intraclass correlation coefficients (ICC) and Bland-Altman plots were calculated to determine relative and absolute agreement. Results Systematic differences among the protocols were found for PO at VT1, VT2, and peak level. At peak level, PO differed significantly among all protocols (ramp: 115 +/- 37 W; 1-min stepwise: 108 +/- 34 W; 3-min stepwise: 94 +/- 31 W, p Conclusions PO at VTs and peak level was significantly higher in short-stage protocols compared with the 3-min stepwise protocol, whereas HR and VO2 showed no differences. Therefore, training zones based on PO determined in short-stage protocols might give an overestimation. Moreover, due to large random error in HR at VTs between the protocols, it is recommended that different protocols should not be used interchangeably within individuals
Weak Ferromagnetism in Fe1-xCoxSb2
Weak ferromagnetism in Fe1-xCoxSb2 is studied by magnetization and Mossbauer
measurements. A small spontaneous magnetic moment of the order of 10^-3 uB
appears along the b-axis for 0.2<= x <= 0.4. Based on the structural analysis,
we argue against extrinsic sources of weak ferromagnetism. We discuss our
results in the framework of the nearly magnetic electronic structure of the
parent compound FeSb2.Comment: 6 pages, 7 figure
Optical Properties of MFe_4P_12 filled skutterudites
Infrared reflectance spectroscopy measurements were made on four members of
the MFe_4P_12 family of filled skutterudites, with M=La, Th, Ce and U. In
progressing from M=La to U the system undergoes a metal-insulator transition.
It is shown that, although the filling atom induces such dramatic changes in
the transport properties of the system, it has only a small effect on lattice
dynamics. We discuss this property of the compounds in the context of their
possible thermoelectric applications.Comment: Manuscript in ReVTeX format, 7 figures in PostScirpt forma
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