Working with "Wogs": Aliens, Denizens and the Machinations of Denialism

This article uses a discussion of the currency of the word “wog” in Britain to identify a pivotal, racialized position used to contain alien incomers so as to exclude them from belonging to the national community. The argument invites readers to focus on the affective energy specifically endowed in contemporary European “populist” politics by race-talk and the anti-Muslim rhetoric which share common roots in absolutist conceptions of culture and “ethnicity.” It is suggested that those developments have conditioned the digital and virtual politics of contemporary racism. They connect with the deployment of machine learning and the growing application of Artificial Intelligence to build trans-national networks among White supremacists and ultranationalists in order to promote their allyship and coordinate their activities

The other side of the wall

The closure of CrossReach's last remaining residential school, Ballikinrain, marks an important stage in the evolution of the charity's care for young people. CrossReach (the operating name for The Church of Scotland's Social Care Council) began opening large residential schools following World War II. It has now moved to family-style living in local communities for its children and young people, a process in which Scotland's changing legislation and CrossReach's own knowledge and experience have interacted to underpin a nuanced understanding of child centred care. Changes in practice at Ballikinrain, informed by academic and psychological consultation, legislative changes and recommendations from Scottish Government reports are described, together with a growing understanding of the local community's role in supporting cared for young people and necessary collaboration in the elimination of stigmatisation. This evolution is illustrated by statements from former pupils, and the particular example of one boy and his key worker, whose metaphor of driver and navigator suggests a fruitful way of viewing relationships at every level of the residential care system. We argue that the trajectory towards child-centred practice and legislation, exemplified by The Promise, supports the residential childcare system to enable our children and young people to influence national policy

Group 6 Metal Pentacarbonyl Complexes of Air-Stable Primary, Secondary, and Tertiary Ferrocenylethylphosphines

The synthesis and characterization of a series of Group 6 metal pentacarbonyl complexes of air stable primary, secondary, and tertiary phosphines containing ferrocenylethyl substituents are reported [M(CO)5L: M = Cr, Mo, W; L = PH2(CH2CH2Fc), PH(CH2CH2Fc)2, P(CH2CH2Fc)3]. The structure and composition of the complexes were confirmed by multinuclear NMR spectroscopy, IR and UV-Vis absorption spectroscopy, mass spectrometry, X-ray crystallography, and elemental analysis. The solid-state structural data reported revealed trends in M-C and M-P bond lengths that mirrored those of the atomic radii of the Group 6 metals involved. UV-Vis absorption spectroscopy and cyclic voltammetry highlighted characteristics consistent with electronically isolated ferrocene units including wavelengths of maximum absorption between 435 and 441 nm and reversible one-electron (per ferrocene unit) oxidation waves between 10 and -5 mV relative to the ferrocene/ferrocenium redox couple. IR spectroscopy confirmed that the σ donating ability of the phosphines increased as ferrocenylethyl substituents were introduced and that the tertiary phosphine ligand described is a stronger σ donor than PPh3 and a weaker σ donor than PEt3, respectively

Sacred communities: contestations and connections

This article discusses a project whose purpose was to review existing qualitative and quantitative data from two separate studies to provide new insights about everyday religion and belonging. Researchers engaged in knowledge exchange and dialogue with new and former research participants, with other researchers involved in similar research, and with wider academic networks beyond the core disciplines represented here, principally anthropology and geography. Key concluding themes related to the ambivalent nature of ‘faith’, connections over place and time, and the contested nature of community. Implicit in terms like ‘faith’, ‘community’, and ‘life course’ are larger interwoven narratives of space, time, place, corporeality, and emotion. The authors found that understanding how places, communities, and faiths differ and intersect requires an understanding of social relatedness and boundaries

Synthesis and Characterization of a Family of Air-Stable Ferrocene- and Ruthenocene-Containing Primary, Secondary, and Tertiary Phosphines

The synthesis and characterization of a family of air-stable primary, secondary, and tertiary phosphines containing all possible combinations of ethylferrocene and ethylruthenocene substituents are reported. Each phosphine was characterized by 1H, 13C, and 31P NMR spectroscopy, IR and UV-vis absorption spectroscopy, mass spectrometry, and elemental analysis. With the exception of primary ethylruthenocene phosphine 8a, all of the title compounds have been studied by single crystal X-ray crystallography. Ferrocene-containing phosphines showed maximum absorption at wavelengths of ca. 440 nm and qualitatively reversible oxidation waves in their cyclic voltammograms with intensities scaling to the number of ferrocene units present. The average metal-cyclopentadienyl centroid distances observed for ferrocene-containing phosphines were shorter than those of ruthenocene-containing phosphines, which also had maximum absorption wavelengths of ca. 320 nm and underwent irreversible electrochemical oxidation. Phosphines containing both ethylferrocene and ethylruthenocene substituents displayed properties consistent with the presence of both metallocene types

A strongly Lewis-acidic and fluorescent borenium cation supported by a tridentate formazanate ligand

Lewis acids are highly sought after for their applications in sensing, small-molecule activation, and catalysis. When combined with π-conjugated molecular frameworks, Lewis acids with unique optoelectronic properties can be realized. Here, we use a tridentate formazanate ligand to create a planar, redox-active, fluorescent, and strongly Lewis-acidic borenium cation. We also demonstrate that this compound can act as a colourimetric probe for reactivity