Dynamically correlated regions and configurational entropy in supercooled liquids

When a liquid is cooled below its melting temperature, if crystallization is avoided, it forms a glass. This phenomenon, called glass transition, is characterized by a marked increase of viscosity, about 14 orders of magnitude, in a narrow temperature interval. The microscopic mechanism behind the glass transition is still poorly understood. However, recently, great advances have been made in the identification of cooperative rearranging regions, or dynamical heterogeneities, i.e. domains of the liquid whose relaxation is highly correlated. The growth of the size of these domains is now believed to be the driving mechanism for the increase of the viscosity. Recently a tool to quantify the size of these domains has been proposed. We apply this tool to a wide class of materials to investigate the correlation between the size of the heterogeneities and their configurational entropy, i.e. the number of states accessible to a correlated domain. We find that the relaxation time of a given system, apart from a material dependent pre-factor, is a universal function of the configurational entropy of a correlated domain. As a consequence, we find that at the glass transition temperature, the size of the domains and the configurational entropy per unit volume are anti-correlated, as originally predicted by the Adam-Gibbs theory. Finally, we use our data to extract some exponents defined in the framework of the Random First Order Theory, a recent quantitative theory of the glass transition.Comment: 8 pages, 4 figures, 3 table

Laser propulsion of nanobullets by adiabatic compression of surface plasmon polaritons

Laser propulsion and guide of nanosized objects is fundamental for a wide number of applications. These applications are often limited by the fact that the optical forces acting on nanoparticles are almost negligible even in the favorable case of metallic particles and hence large laser powers are needed to accelerate and guide nanosize devices in practical applications. Furthermore, metallic nanoparticles exhibit strong absorption bands and scattering and this makes more difficult controlling nanopropulsion. Thus, finding some mechanism enhancing the optomechanical interaction at the nanoscale controlled by laser is specifically challenging and pivotal. Here, we demonstrate a novel physical effect where the well-known adiabatic localization of the enhanced plasmonic surface field on the apex of metallic nanocones produces a significant optical pressure employable as a propulsive mechanism. The proposed method gives the possibility to develop new photonics devices to accelerate metallic nanobullets over long distances for a variety of applications

The mixing of polarizations in the acoustic excitations of disordered media with local isotropy

An approximate solution of the Dyson equation related to a stochastic Helmholtz equation, which describes the acoustic dynamics of a three-dimensional isotropic random medium with elastic tensor fluctuating in space, is obtained in the framework of the Random Media Theory. The wavevector-dependence of the self-energy is preserved, thus allowing a description of the acoustic dynamics at wavelengths comparable with the size of heterogeneity domains. This in turn permits to quantitatively describe the mixing of longitudinal and transverse dynamics induced by the medium's elastic heterogeneity and occurring at such wavelengths. A functional analysis aimed to attest the mathematical coherence and to define the region of validity in the frequency-wavevector plane of the proposed approximate solution is presented, with particular emphasis dedicated to the case of disorder characterized by an exponential decay of the covariance function.Comment: 18 pages, 8 figures, 4 supplementary notes. Revisited version for Frontiers in Physic

Shocks in nonlocal media

We investigate the formation of collisionless shocks along the spatial profile of a gaussian laser beam propagating in nonlocal nonlinear media. For defocusing nonlinearity the shock survives the smoothing effect of the nonlocal response, though its dynamics is qualitatively affected by the latter, whereas for focusing nonlinearity it dominates over filamentation. The patterns observed in a thermal defocusing medium are interpreted in the framework of our theory.Comment: 5 pages, 5 figure

Bibliometric indicators: the origin of their log-normal distribution and why they are not a reliable proxy for an individual scholar’s talent

There is now compelling evidence that the statistical distributions of extensive individual bibliometric indicators collected by a scholar, such as the number of publications or the total number of citations, are well represented by a Log-Normal function when homogeneous samples are considered. A Log-Normal distribution function is the normal distribution for the logarithm of the variable. In linear scale it is a highly skewed distribution with a long tail in the high productivity side. We are still lacking a detailed and convincing ab-initio model able to explain observed Log-Normal distributions-this is the gap this paper sets out to fill. Here, we propose a general explanation of the observed evidence by developing a straightforward model based on the following simple assumptions: (1) the materialist principle of the natural equality of human intelligence, (2) the success breeds success effect, also known as Merton effect, which can be traced back to the Gospel parables about the Talents (Matthew) and Minas (Luke), and, (3) the recognition and reputation mechanism. Building on these assumptions we propose a distribution function that, although mathematically not identical to a Log-Normal distribution, shares with it all its main features. Our model well reproduces the empirical distributions, so the hypotheses at the basis of the model are not falsified. Therefore the distributions of the bibliometric parameters observed might be the result of chance and noise (chaos) related to multiplicative phenomena connected to a publish or perish inflationary mechanism, led by scholars' recognition and reputations. In short, being a scholar in the right tail or in the left tail of the distribution could have very little connection to her/his merit and achievements. This interpretation might cast some doubts on the use of the number of papers and/or citations as a measure of scientific achievements. A tricky issue seems to emerge, that is: what then do bibliometric indicators really measure? This issue calls for deeper investigations into the meaning of bibliometric indicators. This is an interesting and intriguing topic for further research to be carried out within a wider interdisciplinary investigation of the science of science, which may include elements and investigation tools from philosophy, psychology and sociology

Probing the Debye spectrum in glasses using small system sizes

The work aims to show that small system sizes in numerical simulations turns out to be useful for investigating the Debye spectrum in glasses

Relaxation is a Two-Step Process for Metallic Glasses

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Background-deflection Brillouin microscopy reveals altered biomechanics of intracellular stress granules by ALS protein FUS

Altered cellular biomechanics have been implicated as key photogenic triggers in age-related diseases. An aberrant liquid-to-solid phase transition, observed in in vitro reconstituted droplets of FUS protein, has been recently proposed as a possible pathogenic mechanism for amyotrophic lateral sclerosis (ALS). Whether such transition occurs in cell environments is currently unknown as a consequence of the limited measuring capability of the existing techniques, which are invasive or lack of subcellular resolution. Here we developed a non-contact and label-free imaging method, named background-deflection Brillouin microscopy, to investigate the three-dimensional intracellular biomechanics at a sub-micron resolution. Our method exploits diffraction to achieve an unprecedented 10,000-fold enhancement in the spectral contrast of single-stage spectrometers, enabling, to the best of our knowledge, the first direct biomechanical analysis on intracellular stress granules containing ALS mutant FUS protein in fixed cells. Our findings provide fundamental insights on the critical aggregation step underlying the neurodegenerative ALS disease