Plumbophyllite, a new species from the Blue Bell claims near Baker, San Bernardino County, California

The new mineral plumbophyllite, Pb2Si4O10·H2O, orthorhombic with space group Pbcn and cell parameters a = 13.2083(4), b = 9.7832(3), c = 8.6545(2) Å, V = 1118.33(5) Å^3, and Z = 4. It occurs as colorless to pale blue prismatic crystals to 3 mm, with wedge-shaped terminations at the Blue Bell claims, about 11 km west of Baker, San Bernardino County, California. It is found in narrow veins in a highly siliceous hornfels in association with cerussite, chrysocolla, fluorite, goethite, gypsum, mimetite, opal, plumbotsumite, quartz, sepiolite, and wulfenite. The streak is white, the luster is vitreous, the Mohs hardness is about 5, and there is one perfect cleavage, {100}. The measured density is 3.96(5) g/cm^3 and the calculated density is 3.940 g/cm^3. Optical properties (589 nm): biaxial (+), {alpha} = 1.674(2), β = 1.684(2), {gamma} = 1.708(2), 2V = 66(2)°, dispersion r > v (strong); X = b, Y = c, Z = a. Electron microprobe analysis provided PbO 60.25, CuO 0.23, SiO_2 36.22 wt%, and CHN analysis provided H_2O 3.29 wt% for a total of 99.99 wt%. Powder IR spectroscopy confirmed the presence of H_2O and single-crystal IR spectroscopy indicated the H_2O to be oriented perpendicular to the b axis. Raman spectra were also obtained. The strongest powder X-ray diffraction lines are [d (hkl) I]: 7.88(110)97, 6.63(200)35, 4.90(020)38, 3.623(202)100, 3.166(130)45, 2.938(312/411/222)57, 2.555(132/213)51, and 2.243(521/332)50. The atomic structure (R1 = 2.04%) consists of undulating sheets of silicate tetrahedra between which are located Pb atoms and channels containing H_2O (and Pb^(2+) lone-pair electrons). The silicate sheets can be described as consisting of zigzag pyroxene-like (SiO_3)_n chains joined laterally into sheets with the unshared tetrahedral apices in successive chains pointed alternately up and down, a configuration also found in pentagonite

Neuro-fuzzy knowledge processing in intelligent learning environments for improved student diagnosis

In this paper, a neural network implementation for a fuzzy logic-based model of the diagnostic process is proposed as a means to achieve accurate student diagnosis and updates of the student model in Intelligent Learning Environments. The neuro-fuzzy synergy allows the diagnostic model to some extent "imitate" teachers in diagnosing students' characteristics, and equips the intelligent learning environment with reasoning capabilities that can be further used to drive pedagogical decisions depending on the student learning style. The neuro-fuzzy implementation helps to encode both structured and non-structured teachers' knowledge: when teachers' reasoning is available and well defined, it can be encoded in the form of fuzzy rules; when teachers' reasoning is not well defined but is available through practical examples illustrating their experience, then the networks can be trained to represent this experience. The proposed approach has been tested in diagnosing aspects of student's learning style in a discovery-learning environment that aims to help students to construct the concepts of vectors in physics and mathematics. The diagnosis outcomes of the model have been compared against the recommendations of a group of five experienced teachers, and the results produced by two alternative soft computing methods. The results of our pilot study show that the neuro-fuzzy model successfully manages the inherent uncertainty of the diagnostic process; especially for marginal cases, i.e. where it is very difficult, even for human tutors, to diagnose and accurately evaluate students by directly synthesizing subjective and, some times, conflicting judgments

Understanding the gender and ethnicity attainment gap in UK higher education

In recent years the success rates of different groups of students in higher education (HE), have come under considerable scrutiny, with gender and ethnicity identified as key attributes predicting differential achievement of ‘good degrees’. A review of previous studies highlights the need for research which looks beyond ‘the deficit model’ to explain the attainment gap. This research used a mixed-methods approach to explore the academic and social experiences of students, as well as lecturers’ views on student achievement, in one UK University. Findings suggest that there are significant differences in motivation and confidence speaking English for different ethnic groups in this study, and a divergence in attendance and study time by gender – both of which may go some way to helping understand the gaps in attainment. In addition, male and BME students tended to over-estimate their likelihood of achieving a good degree outcome, compared to other groups

Effect of applied DC voltages and temperatures on space charge behaviour of multi-layer oil-paper insulation

In this paper, space charge in a multi-layer oil-paper insulation system was investigated using the pulsed electroacoustic (PEA) technique. A series of measurements had been carried following subjection of the insulation system to different applied voltages and different temperatures. Charge behaviours in the insulation system were analyzed and the influence of temperature on charge dynamics was discussed. The test results shows that homocharge injection takes place under all the test conditions, the applied DC voltage mainly affects the amount of space charge, while the temperature has greater influence on the distribution and mobility of space charge inside oil-paper samples

Quantum Coherence of Relic Neutrinos

We argue that in at least a portion of the history of the universe the relic background neutrinos are spatially-extended, coherent superpositions of mass states. We show that an appropriate quantum mechanical treatment affects the neutrino mass values derived from cosmological data. The coherence scale of these neutrino flavor wavepackets can be an appreciable fraction of the causal horizon size, raising the possibility of spacetime curvature-induced decoherence.Comment: 4 pages, 4 figures; matches publication in PR

The Incidence of the Local Property Tax: A Re-evaluation

The article identifies the key assumptions that underlie competing theories of the incidence of the local property tax. We conclude that the"benefit view" which maintains that the property tax system is equivalent to a set of non-distortionary user changes is correct only under very restrictive assumptions. Only when communities adopt a set of exact, binding zoning requirements will a distortionary tax be transformed into a lump-sum tax. We argue that within jurisdiction heterogeneity of house and firm typeis very unlikely and that the burden of a property tax that is distortionary at the margin falls on the owners of capital.

The New View of the Property Tax: A Reformulation

The"new view" of the property tax is reformulated within the context of a model with interjurisdictional competition, endogenous local public services, individuals who are segregated into homogeneous communities according to tastes for local public services, a simple form of land use zoning, and a political or constitutional constraint on the use of head taxes by local governments. Expressions for the "profits tax" and"excise tax" effects of the property tax are derived. The effects of a "consumption distortion" away from government services due to local reluctance to tax mobile capital are also examined.

Observation of surface charge screening and Fermi level pinning on a synthetic, boron-doped diamond

Spectroscopic current-voltage (I-V) curves taken with a scanning tunneling microscope on a synthetic, boron-doped diamond single crystal indicate that the diamond, boiled in acid and baked to 500 °C in vacuum, does not exhibit ideal Schottky characteristics. These I-V curves taken in ultrahigh vacuum do not fit the traditional theory of thermionic emission; however, the deviation from ideal can be accounted for by charge screening at the diamond surface. At ambient pressure, the I-V curves have a sharp threshold voltage at 1.7 eV above the valence band edge indicating pinning of the Fermi energy. This measurement is in excellent agreement with the 1/3 band gap rule of Mead and Spitzer [Phys. Rev. 134, A713 (1964)]

X-ray spectrum of the high polarization quasar PKS 1510-089

We present results on the X-ray spectra of the radio-loud, high-polarization quasar, PKS 1510-089, based on new data obtained using ASCA, and from archival ROSAT data. The X-ray spectrum obtained by ASCA is unusually hard, with the photon index=1.30+-0.06, while the (non-simultaneous) ROSAT data indicate a steeper spectrum (1.9+-0.3). The X-ray flux at 1 keV is within 10% during both observations. A break in the underlying continuum at about 0.7 keV is suggested. Flat X-ray spectra seem to be the characteristic of high polarization quasars, and their spectra also appear to be harder than that of the other radio-loud but low-polarization quasars. The multiwavelength spectrum of PKS 1510-089 is similar to many other gamma-ray blazars, suggesting the emission is dominated by that from a relativistic jet. A big blue-bump is also seen in its multiwavelength spectrum, suggesting the presence of a strong thermal component as well.Comment: 19 pages (Latex + 5 ps figures), Accpeted for publication in the Astrophysical Journal, December 20, 199