Polymers and its applications in agriculture

<div><p> Graphical Abstract Abstract Polymers are a class of soft materials with numerous and versatile mechanical and chemical properties that can be tuned specific to their application. Agriculture is an expanding area due to the requirement for indispensable food to meet the demands of a growing global population. Consequently, development of technology to improve the quality of the soil and agriculture manages is still under development. Intelligent agricultural supplies (controlled or slow release agrochemicals and superabsorbents) and biosorbents contribute to an expanding niche using technology from polymers. This review elucidates the state-of-the-art and will discuss some important aspects of using polymers in intelligent fertilizers, as well as superabsorbent, biosorbent and biodegradation processes in agriculture that are environmentally, technically, socially, and economically sustainable.</p></div

Magnetically oriented bicelles with monoalkylphosphocholines: versatile membrane mimetics for nuclear magnetic resonance applications

Bicelles (bilayered micelles) are model membranes used in the study of peptide structure and membrane interactions. They are traditionally made of long- and short-chain phospholipids, usually dimyristoylphosphatidylcholine (D14PC) and dihexanoyl-PC (D6PC). They are attractive membrane mimetics because their composition and planar surface are similar to the native membrane environment. In this work, to improve the solubilization of membrane proteins and allow their study in bicellar systems, D6PC was replaced by detergents from the monoalkylphosphocholine (MAPCHO) family, of which dodecylphosphocholine (12PC) is known for its ability to solubilize membrane proteins. More specifically 12PC, tetradecyl- (14PC), and hexadecyl-PC (16PC) have been employed. To verify the possibility of making bicelles with different hydrophobic thicknesses to better accommodate membrane proteins, D14PC was also replaced by phospholipids with different alkyl chain lengths: dilauroyl-PC (D12PC), dipalmitoyl-PC (D16PC), distearoyl-PC (D18PC), and diarachidoyl-PC (D20PC). Results obtained by 31P solid-state nuclear magnetic resonance (NMR) and isothermal titration calorimetry (ITC) at several lipid-to-detergent molar ratios (q) and temperatures indicate that these new MAPCHO bicelles can be formed under a variety of conditions. The quality of their alignment is similar to that of classical bicelles, and the low critical micelle concentration (CMC) of the surfactants and their miscibility with phospholipids are likely to be advantageous for the reconstitution of membrane proteins