A thermodynamic unification of jamming

Fragile materials ranging from sand to fire-retardant to toothpaste are able to exhibit both solid and fluid-like properties across the jamming transition. Unlike ordinary fusion, systems of grains, foams and colloids jam and cease to flow under conditions that still remain unknown. Here we quantify jamming via a thermodynamic approach by accounting for the structural ageing and the shear-induced compressibility of dry sand. Specifically, the jamming threshold is defined using a non-thermal temperature that measures the 'fluffiness' of a granular mixture. The thermodynamic model, casted in terms of pressure, temperature and free-volume, also successfully predicts the entropic data of five molecular glasses. Notably, the predicted configurational entropy avoids the Kauzmann paradox entirely. Without any free parameters, the proposed equation-of-state also governs the mechanism of shear-banding and the associated features of shear-softening and thickness-invariance.Comment: 16 pgs double spaced. 4 figure

Laser shock peening and mechanical shot peening processes applicable for the surface treatment of technical grade ceramics: a review

Laser shock peening and conventional mechanical shot peening are both comparable processes generally applicable to surface treat various metals and alloys. Commercial advantages offered by the laser systems such as flexibility, deep penetration of laser-induced shocks with precise control of the thermal pulses, shorter process times, high speeds, accuracy and aesthetics are attractive in comparison with the mechanical shot peening technique. Laser shock peening in the recent years has proved to be successful with steels, aluminium and titanium surfaces and metallic alloys in general. Nevertheless, minimal research has been conducted on laser shock peening and mechanical shot peening of technical grade ceramics. This article presents an update of the theory and to-date relevant literature within the two subject areas, as well as a comparison and a contrast between the mechanical and laser shock peening techniques. In addition, various gaps in knowledge are identified to propose further research for the development of both the techniques applicable to the surface treatment of technical grade ceramics