13,952 research outputs found

    Non-equilibrium Bethe-Salpeter equation for transient photo-absorption spectroscopy

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    In this work we propose an accurate first-principle approach to calculate the transient photo--absorption spectrum measured in Pump\&\,Probe experiments. We formulate a condition of {\em adiabaticity} and thoroughly analyze the simplifications brought about by the fulfillment of this condition in the non--equilibrium Green's function (NEGF) framework. Starting from the Kadanoff-Baym equations we derive a non--equilibrium Bethe--Salpeter equation (BSE) for the response function that can be implemented in most of the already existing {\em ab--initio} codes. In addition, the {\em adiabatic} approximation is benchmarked against full NEGF simulations in simple model hamiltonians, even under extreme, nonadiabatic conditions where it is expected to fail. We find that the non--equilibrium BSE is very robust and captures important spectral features in a wide range of experimental configurations.Comment: 13 pages, 5 captioned figure

    First-principles approach to excitons in time-resolved and angle-resolved photoemission spectra

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    We show that any {\em quasi-particle} or GW approximation to the self-energy does not capture excitonic features in time-resolved (TR) photoemission spectroscopy. In this work we put forward a first-principles approach and propose a feasible diagrammatic approximation to solve this problem. We also derive an alternative formula for the TR photocurrent which involves a single time-integral of the lesser Green's function. The diagrammatic approximation applies to the {\em relaxed} regime characterized by the presence of quasi-stationary excitons and vanishing polarization. The main distinctive feature of the theory is that the diagrams must be evaluated using {\em excited} Green's functions. As this is not standard the analytic derivation is presented in detail. The final result is an expression for the lesser Green's function in terms of quantities that can all be calculated {\em ab initio}. The validity of the proposed theory is illustrated in a one-dimensional model system with a direct gap. We discuss possible scenarios and highlight some universal features of the exciton peaks. Our results indicate that the exciton dispersion can be observed in TR {\em and} angle-resolved photoemission.Comment: 15 pages, 8 figure

    Quasiparticle Electronic structure of Copper in the GW approximation

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    We show that the results of photoemission and inverse photoemission experiments on bulk copper can be quantitatively described within band-structure theory, with no evidence of effects beyond the single-quasiparticle approximation. The well known discrepancies between the experimental bandstructure and the Kohn-Sham eigenvalues of Density Functional Theory are almost completely corrected by self-energy effects. Exchange-correlation contributions to the self-energy arising from 3s and 3p core levels are shown to be crucial.Comment: 4 pages, 2 figures embedded in the text. 3 footnotes modified and 1 reference added. Small modifications also in the text. Accepted for publication in PR

    International scientific collaborations and the Chinese Belt and Road Initiative (BRI). A bibliometric assessment of the research component of BRI geopolitical strategy

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    Joining the European Union as an advantage in science performativity. A quasi-experimental study

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    The paper investigates the issue of increasing international co-authored publications, comparing countries that accessed the Europe-an Union (EU) in 2004 (EU04) against other Central-Eastern European Countries (othEast-ERA), adopting a scientometrical approach. This comparison is interesting to check whether to be part of the EU is dif-ferent from being part of the European Research Area (ERA) – being both entities aimed at fostering more international collaborations. The hypothesis is that EU might convey more opportunities for the sake of international publications, although ERA assures access to European funding schemes anyway. Analysing the census of internationally co-authored publications from 1995 to 2015, difference-in-differences regressions show that Countries that joined EU in 2004 performed better than other Central-Eastern ones. Implications for the public policies in science are discussed

    Italy's New Requirements for Academic Careers: The New Habilitation and its Worthiness

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    The new habilitation, established in Italy in 2010 and commenced in 2012, was designed (outcomes released commencing December 2013). Its aim is to filter who will be eligible to apply for competitions for the two permanent level professor positions in the universities. The results of the first set of data are 20 scientific sectors representing more than 10% of all sectors analyzed to understand if the outcomes reflected in a worthy way the indicators of productivity and quality of scientific production of candidates. Some legal and statistical framework are fostered before the data analysis in order to have a better understanding of the reform and the context where it operates. The hypothesis of the worthiness is here addressed on the assumption that the current position held by a candidate should not play any role in the attainment of the habilitation. Splitting candidates into two roles and having controlled for age as a variable, the data was used to reveal that the indicators of quality of scientific production (H index for hard sciences and articles in top ranked journals for social sciences and humanities) are more frequently the best predictors. Though some limits of the present analysis are faced and illustrated, some critical points of this new institution are discussed

    Critical properties of Ising model on Sierpinski fractals. A finite size scaling analysis approach

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    The present paper focuses on the order-disorder transition of an Ising model on a self-similar lattice. We present a detailed numerical study, based on the Monte Carlo method in conjunction with the finite size scaling method, of the critical properties of the Ising model on some two dimensional deterministic fractal lattices with different Hausdorff dimensions. Those with finite ramification order do not display ordered phases at any finite temperature, whereas the lattices with infinite connectivity show genuine critical behavior. In particular we considered two Sierpinski carpets constructed using different generators and characterized by Hausdorff dimensions d_H=log 8/log 3 = 1.8927.. and d_H=log 12/log 4 = 1.7924.., respectively. The data show in a clear way the existence of an order-disorder transition at finite temperature in both Sierpinski carpets. By performing several Monte Carlo simulations at different temperatures and on lattices of increasing size in conjunction with a finite size scaling analysis, we were able to determine numerically the critical exponents in each case and to provide an estimate of their errors. Finally we considered the hyperscaling relation and found indications that it holds, if one assumes that the relevant dimension in this case is the Hausdorff dimension of the lattice.Comment: 21 pages, 7 figures; a new section has been added with results for a second fractal; there are other minor change
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