Gauge theory approach to glass transitions

This theory combines a thermodynamic approach with a dynamic one in order to describe glass transition. Glass transition is regarded as an inaccessible second order phase transition, which is interrupted because of premature critical slowing down, caused by the system's frustration. The frustration-induced vortices are present in the structure besides thermoactivated vortices, and prevent the development of the order parameter fluctuations, that leads to the critical slowing down the system kinetics at some temperature above the phase transition point

The perimeter of large planar Voronoi cells: a double-stranded random walk

Let $p\_n$ be the probability for a planar Poisson-Voronoi cell to have exactly $n$ sides. We construct the asymptotic expansion of $\log p\_n$ up to terms that vanish as $n\to\infty$. We show that {\it two independent biased random walks} executed by the polar angle determine the trajectory of the cell perimeter. We find the limit distribution of (i) the angle between two successive vertex vectors, and (ii) the one between two successive perimeter segments. We obtain the probability law for the perimeter's long wavelength deviations from circularity. We prove Lewis' law and show that it has coefficient 1/4.Comment: Slightly extended version; journal reference adde

Asymptotic statistics of the n-sided planar Poisson-Voronoi cell. I. Exact results

We achieve a detailed understanding of the $n$-sided planar Poisson-Voronoi cell in the limit of large $n$. Let ${p}\_n$ be the probability for a cell to have $n$ sides. We construct the asymptotic expansion of $\log {p}\_n$ up to terms that vanish as $n\to\infty$. We obtain the statistics of the lengths of the perimeter segments and of the angles between adjoining segments: to leading order as $n\to\infty$, and after appropriate scaling, these become independent random variables whose laws we determine; and to next order in $1/n$ they have nontrivial long range correlations whose expressions we provide. The $n$-sided cell tends towards a circle of radius (n/4\pi\lambda)^{\half}, where $\lambda$ is the cell density; hence Lewis' law for the average area $A\_n$ of the $n$-sided cell behaves as $A\_n \simeq cn/\lambda$ with $c=1/4$. For $n\to\infty$ the cell perimeter, expressed as a function $R(\phi)$ of the polar angle $\phi$, satisfies $d^2 R/d\phi^2 = F(\phi)$, where $F$ is known Gaussian noise; we deduce from it the probability law for the perimeter's long wavelength deviations from circularity. Many other quantities related to the asymptotic cell shape become accessible to calculation.Comment: 54 pages, 3 figure

From one cell to the whole froth: a dynamical map

We investigate two and three-dimensional shell-structured-inflatable froths, which can be constructed by a recursion procedure adding successive layers of cells around a germ cell. We prove that any froth can be reduced into a system of concentric shells. There is only a restricted set of local configurations for which the recursive inflation transformation is not applicable. These configurations are inclusions between successive layers and can be treated as vertices and edges decorations of a shell-structure-inflatable skeleton. The recursion procedure is described by a logistic map, which provides a natural classification into Euclidean, hyperbolic and elliptic froths. Froths tiling manifolds with different curvature can be classified simply by distinguishing between those with a bounded or unbounded number of elements per shell, without any a-priori knowledge on their curvature. A new result, associated with maximal orientational entropy, is obtained on topological properties of natural cellular systems. The topological characteristics of all experimentally known tetrahedrally close-packed structures are retrieved.Comment: 20 Pages Tex, 11 Postscript figures, 1 Postscript tabl

The self-assessment INTERMED predicts healthcare and social costs of orthopaedic trauma patients with persistent impairments.

To use the self-assessment INTERMED questionnaire to determine the relationship between biopsychosocial complexity and healthcare and social costs of patients after orthopaedic trauma. Secondary prospective analysis based on the validation study cohort of the self-assessment INTERMED questionnaire. Inpatients orthopaedic rehabilitation with vocational aspects. In total, 136 patients with chronic pain and impairments were included in this study: mean (SD) age, 42.6 (10.7) years; 116 men, with moderate pain intensity (51/100); suffering from upper (n = 55), lower-limb (n = 51) or spine (n = 30) pain after orthopaedic trauma; with minor or moderate injury severity (severe injury for 25). Biopsychosocial complexity, assessed with the self-assessment INTERMED questionnaire, and other confounding variables collected prospectively during rehabilitation. Outcome measures (healthcare costs, loss of wage costs and time for fitness-to-work) were collected through insurance files after case settlements. Linear multiple regression models adjusted for age, gender, pain, trauma severity, education and employment contract were performed to measure the influence of biopsychosocial complexity on the three outcome variables. High-cost patients were older (+3.6 years) and more anxious (9.0 vs 7.3 points at HADS-A), came later to rehabilitation (+105 days), and showed higher biopsychosocial complexity (+3.2 points). After adjustment, biopsychosocial complexity was significantly associated with healthcare (ß = 0.02; P = 0.003; exp <sup>ß</sup> = 1.02) and social costs (ß = 0.03; P = 0.006, exp <sup>ß</sup> = 1.03) and duration before fitness-to-work (ß = 0.04; P < 0.001, exp <sup>ß</sup> = 1.04). Biopsychosocial complexity assessed with the self-assessment INTERMED questionnaire is associated with higher healthcare and social costs

Topological correlations in soap froths

Correlation in two-dimensional soap froth is analysed with an effective potential for the first time. Cells with equal number of sides repel (with linear correlation) while cells with different number of sides attract (with NON-bilinear) for nearest neighbours, which cannot be explained by the maximum entropy argument. Also, the analysis indicates that froth is correlated up to the third shell neighbours at least, contradicting the conventional ideas that froth is not strongly correlated.Comment: 10 Pages LaTeX, 6 Postscript figure

Validity and responsiveness of the French version of the Örebro musculoskeletal pain screening questionnaire in chronic low back pain

The assessment of a broad range of biopsychosocial aspects is important in the rehabilitation of patients with chronic low back pain (CLBP) for the prediction of outcome as well as for evaluation. The objective of this study was to test the responsiveness, construct validity and predictive value of the A-rebro Musculoskeletal Pain Screening Questionnaire (OMPSQ) compared to other instruments widely used to assess biopsychosocial aspects in patients with CLBP. 111 patients with CLBP admitted to an inpatient rehabilitation completed a set of questionnaires on biopsychosocial aspects at baseline and at discharge. Ninety-eight patients responded at three months for an assessment of the return to work status. Responsiveness of the OMPSQ, the ability to detect change in the construct of interest, was investigated by a set of hypotheses on correlations with widely used questionnaires. We tested the hypothesis that the changes in the OMPSQ would vary along with the responses in the Patient's Global Impression of Change. Prediction of disability at discharge, work status at three months and time to return to work was evaluated with linear, logistic and cox regression models. The OMPSQ showed good predictive values for disability and return to work and construct validity of the instrument was corroborated. Seventy-nine percent of our hypotheses for responsiveness could be confirmed, with the OMPSQ showing the second highest change during the rehabilitation. The OMPSQ can also be applied in patients with CLBP, but for the assessment of change in psychosocial variables one should add specific questionnaires

Protein quality of amaranth grains cultivated in Ethiopia as affected by popping and fermentation

The effect of popping and fermentation on protein quality of three different varieties of amaranth grains cultivated in Ethiopia was evaluated. Total lysine content of the grains was higher than that of commonly available cereals but close to that of legumes. Methionine and cysteine contents in the grains were also higher than that found in cereal and legume proteins. Percentage of total indispensable amino acids, excluding tryptophan, was 43% - 49%, which was higher than WHO reference pattern (31%). Popping resulted in 36% and 37% reduction in total lysine and cysteine contents, respectively, whereas fermentation reduced cysteine, lysine and methionine contents by 16%, 20% and 20%, respectively. From the free amino acids, histidine was the major indispensable amino acid but threonine was not detected. During popping, all free amino acids, except threonine, were reduced. On the other hand, fermentation significantly increased (p < 0.01) most amino acids except arginine, which was significantly decreased (p < 0.01), and tyrosine and glutamic acid, for which no change was observed. Popping decreased in vitro protein digestibility (IVPD) by 8.3% - 17.1% while fermentation increased IVPD by 4.8% - 7.5%. Substitution of amaranth for wheat and/or maize during complementary food formulation could contribute much to the daily requirements of indispensable amino acids of young children