15,076 research outputs found
Flow curves of colloidal dispersions close to the glass transition: Asymptotic scaling laws in a schematic model of mode coupling theory
The flow curves, viz. the curves of stationary stress under steady shearing,
are obtained close to the glass transition in dense colloidal dispersions using
asymptotic expansions in a schematic model of mode coupling theory. The shear
thinning of the viscosity in fluid states and the yielding of glassy states is
discussed. At the transition between fluid and shear-molten glass, simple and
generalized Herschel-Bulkley laws are derived with power law exponents that can
be computed for different particle interactions from the equilibrium structure
factor.Comment: 14 pages, 14 figures, 4 tables, Eur. Phys. J. E (submitted
Non--Newtonian viscosity of interacting Brownian particles: comparison of theory and data
A recent first-principles approach to the non-linear rheology of dense
colloidal suspensions is evaluated and compared to simulation results of
sheared systems close to their glass transitions. The predicted scenario of a
universal transition of the structural dynamics between yielding of glasses and
non-Newtonian (shear-thinning) fluid flow appears well obeyed, and calculations
within simplified models rationalize the data over variations in shear rate and
viscosity of up to 3 decades.Comment: 6 pages, 2 figures; J. Phys. Condens. Matter to be published (Jan.
2003
Quasiparticle band structure based on a generalized Kohn-Sham scheme
We present a comparative full-potential study of generalized Kohn-Sham
schemes (gKS) with explicit focus on their suitability as starting point for
the solution of the quasiparticle equation. We compare quasiparticle
band structures calculated upon LDA, sX, HSE03, PBE0, and HF functionals for
exchange and correlation (XC) for Si, InN and ZnO. Furthermore, the HSE03
functional is studied and compared to the GGA for 15 non-metallic materials for
its use as a starting point in the calculation of quasiparticle excitation
energies. For this case, also the effects of selfconsistency in the
self-energy are analysed. It is shown that the use of a gKS scheme as a
starting point for a perturbative QP correction can improve upon the
deficiencies found for LDA or GGA staring points for compounds with shallow
bands. For these solids, the order of the valence and conduction bands is often
inverted using local or semi-local approximations for XC, which makes
perturbative calculations unreliable. The use of a gKS starting point
allows for the calculation of fairly accurate band gaps even in these difficult
cases, and generally single-shot calculations following calculations
using the HSE03 functional are very close to experiment
Integration through transients for Brownian particles under steady shear
Starting from the microscopic Smoluchowski equation for interacting Brownian
particles under stationary shearing, exact expressions for shear-dependent
steady-state averages, correlation and structure functions, and
susceptibilities are obtained, which take the form of generalized Green-Kubo
relations. They require integration of transient dynamics. Equations of motion
with memory effects for transient density fluctuation functions are derived
from the same microscopic starting point. We argue that the derived formal
expressions provide useful starting points for approximations in order to
describe the stationary non-equilibrium state of steadily sheared dense
colloidal dispersions.Comment: 17 pages, Submitted to J. Phys.: Condens. Matter; revised version
with minor correction
Information Tradeoff Relations for Finite-Strength Quantum Measurements
In this paper we give a new way to quantify the folklore notion that quantum
measurements bring a disturbance to the system being measured. We consider two
observers who initially assign identical mixed-state density operators to a
two-state quantum system. The question we address is to what extent one
observer can, by measurement, increase the purity of his density operator
without affecting the purity of the other observer's. If there were no
restrictions on the first observer's measurements, then he could carry this out
trivially by measuring the initial density operator's eigenbasis. If, however,
the allowed measurements are those of finite strength---i.e., those
measurements strictly within the interior of the convex set of all
measurements---then the issue becomes significantly more complex. We find that
for a large class of such measurements the first observer's purity increases
the most precisely when there is some loss of purity for the second observer.
More generally the tradeoff between the two purities, when it exists, forms a
monotonic relation. This tradeoff has potential application to quantum state
control and feedback.Comment: 15 pages, revtex3, 3 eps figure
Nonlinear viscoelasticity of metastable complex fluids
Many metastable complex fluids such as colloidal glasses and gels show
distinct nonlinear viscoelasticity with increasing oscillatory-strain
amplitude; the storage modulus decreases monotonically as the strain amplitude
increases whereas the loss modulus has a distinct peak before it decreases at
larger strains. We present a qualitative argument to explain this ubiquitous
behavior and use mode coupling theory (MCT) to confirm it. We compare
theoretical predictions to the measured nonlinear viscoelasticity in a dense
hard sphere colloidal suspensions; reasonable agreement is obtained. The
argument given here can be used to obtain new information about linear
viscoelasticity of metastable complex fluids from nonlinear strain
measurements.Comment: 7 pages, 3 figures, accepted for publication in Europhys. Let
Structural relaxation in orthoterphenyl: a schematic mode coupling theory model analysis
Depolarized light scattering spectra of orthoterphenyl showing the emergence
of the structural relaxation below the oscillatory microscopic excitations are
described by solutions of a schematic mode--coupling--theory model
Quantum State Disturbance vs. Information Gain: Uncertainty Relations for Quantum Information
When an observer wants to identify a quantum state, which is known to be one
of a given set of non-orthogonal states, the act of observation causes a
disturbance to that state. We investigate the tradeoff between the information
gain and that disturbance. This issue has important applications in quantum
cryptography. The optimal detection method, for a given tolerated disturbance,
is explicitly found in the case of two equiprobable non-orthogonal pure states.Comment: 20 pages, standard LaTeX, four png figures (also available from the
authors: [email protected] and [email protected]
The mean-squared displacement of a molecule moving in a glassy system
The mean-squared displacement (MSD) of a hard sphere and of a dumbbell
molecule consisting of two fused hard spheres immersed in a dense hard-sphere
system is calculated within the mode-coupling theory for ideal liquid-glass
transitions. It is proven that the velocity correlator, which is the second
time derivative of the MSD, is the negative of a completely monotone function
for times within the structural-relaxation regime. The MSD is found to exhibit
a large time interval for structural relaxation prior to the onset of the
-process which cannot be described by the asymptotic formulas for the
mode-coupling-theory-bifurcation dynamics. The -process for molecules
with a large elongation is shown to exhibit an anomalously wide cross-over
interval between the end of the von-Schweidler decay and the beginning of
normal diffusion. The diffusivity of the molecule is predicted to vary
non-monotonically as function of its elongation.Comment: 18 pages, 12 figures, Phys. Rev. E, in prin
Identical Particles and Permutation Group
Second quantization is revisited and creation and annihilation operators
areshown to be related, on the same footing both to the algebra h(1), and to
the superalgebra osp(1|2) that are shown to be both compatible with Bose and
Fermi statistics.
The two algebras are completely equivalent in the one-mode sector but,
because of grading of osp(1|2), differ in the many-particle case.
The same scheme is straightforwardly extended to the quantum case h_q(1) and
osp_q(1|2).Comment: 8 pages, standard TEX, DFF 205/5/94 Firenz
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