On the degenerated soft-mode instability

We consider instabilities of a single mode with finite wavenumber in inversion symmetric spatially one dimensional systems, where the character of the bifurcation changes from sub- to supercritical behaviour. Starting from a general equation of motion the full amplitude equation is derived systematically and formulas for the dependence of the coefficients on the system parameters are obtained. We emphasise the importance of nonlinear derivative terms in the amplitude equation for the behaviour in the vicinity of the bifurcation point. Especially the numerical values of the corresponding coefficients determine the region of coexistence between the stable trivial solution and stable spatially periodic patterns. Our approach clearly shows that similar considerations fail for the case of oscillatory instabilities.Comment: 16 pages, uses iop style files, manuscript also available at ftp://athene.fkp.physik.th-darmstadt.de/pub/publications/wolfram/jpa_97/ or at http://athene.fkp.physik.th-darmstadt.de/public/wolfram_publ.html. J. Phys. A in pres

Comparison of OCO-2 target observations to MUCCnet – is it possible to capture urban XCO2_{CO2} gradients from space?

In this paper, we compare Orbiting Carbon Observatory 2 (OCO-2) measurements of column-averaged dry-air mole fractions (DMF) of CO$_{2}$ (X$_{CO2}$) and its urban–rural differences against ground-based remote sensing data measured by the Munich Urban Carbon Column network (MUCCnet). Since April 2020, OCO-2 has regularly conducted target observations in Munich, Germany. Its target-mode data provide high-resolution X$_{CO2}$ within a 15 km × 20 km target field of view that is greatly suited for carbon emission studies from space in cities and agglomerated areas. OCO-2 detects urban X$_{CO2}$ with a root mean square different (RMSD) of less than 1 ppm when compared to the MUCCnet reference site. OCO-2 target X$_{CO2}$ is biased high against the ground-based measurements. The close proximity of MUCCnet\u27s five fully automated remote sensing sites enables us to compare spaceborne and ground-based X$_{CO2}$ in three urban areas of Munich separately (center, north, and west) by dividing the target field into three smaller comparison domains. Due to this more constrained collocation, we observe improved agreement between spaceborne and ground-based X$_{CO2}$ in all three comparison domains. For the first time, X$_{CO2}$ gradients within one OCO-2 target field of view are evaluated against ground-based measurements. We compare X$_{CO2}$ gradients in the OCO-2 target observations to gradients captured by collocated MUCCnet sites. Generally, OCO-2 detects elevated X$_{CO2}$ in the same regions as the ground-based monitoring network. More than 90 % of the observed spaceborne gradients have the same orientation as the X$_{CO2}$ gradients measured by MUCCnet. During our study, urban–rural enhancements are found to be in the range of 0.1 to 1 ppm. The low urban–rural gradients of typically well below 1 ppm in Munich during our study allow us to test OCO-2\u27s lower detection limits for intra-urban X$_{CO2}$ gradients. Urban X$_{CO2}$ gradients recorded by the OCO-2 instruments and MUCCnet are strongly correlated (R$^{2}$=0.68) with each other and have an RMSD of 0.32 ppm. A case study, which includes a comparison of one OCO-2 target overpass to WRF-GHG modeled X$_{CO2}$ , reveals a similar distribution of enhanced CO$_{2}$ column abundances in Munich. In this study, we address OCO-2\u27s capability to detect small-scale spatial X$_{CO2}$ differences within one target observation. Our results suggest OCO-2\u27s potential to assess anthropogenic emissions from space

Tropospheric water vapour isotopologue data (H₂¹⁶O, H₂¹⁸O, and HD¹⁶O) as obtained from NDACC/FTIR solar absorption spectra

We report on the ground-based FTIR (Fourier transform infrared) tropospheric water vapour isotopologue remote sensing data that have been recently made available via the database of NDACC (Network for the Detection of Atmospheric Composition Change; ftp://ftp.cpc.ncep.noaa.gov/ndacc/MUSICA/) and via doi:10.5281/zenodo.48902. Currently, data are available for 12 globally distributed stations. They have been centrally retrieved and quality-filtered in the framework of the MUSICA project (MUlti-platform remote Sensing of Isotopologues for investigating the Cycle of Atmospheric water). We explain particularities of retrieving the water vapour isotopologue state (vertical distribution of H216O, H218O, and HD16O) and reveal the need for a new metadata template for archiving FTIR isotopologue data. We describe the format of different data components and give recommendations for correct data usage. Data are provided as two data types. The first type is best-suited for tropospheric water vapour distribution studies disregarding different isotopologues (comparison with radiosonde data, analyses of water vapour variability and trends, etc.). The second type is needed for analysing moisture pathways by means of H2O, δD-pair distributions

Status of the BELLE II Pixel Detector

The Belle II experiment at the super KEK B-factory (SuperKEKB) in Tsukuba, Japan, has been collecting $e^+e^−$ collision data since March 2019. Operating at a record-breaking luminosity of up to $4.7×10^{34} cm^{−2}s^{−1}$, data corresponding to $424 fb^{−1}$ has since been recorded. The Belle II VerteX Detector (VXD) is central to the Belle II detector and its physics program and plays a crucial role in reconstructing precise primary and decay vertices. It consists of the outer 4-layer Silicon Vertex Detector (SVD) using double sided silicon strips and the inner two-layer PiXel Detector (PXD) based on the Depleted P-channel Field Effect Transistor (DePFET) technology. The PXD DePFET structure combines signal generation and amplification within pixels with a minimum pitch of $(50×55) μm^2$. A high gain and a high signal-to-noise ratio allow thinning the pixels to $75 μm$ while retaining a high pixel hit efficiency of about $99$. As a consequence, also the material budget of the full detector is kept low at $≈0.21$$\frac{X}{X_0}$ per layer in the acceptance region. This also includes contributions from the control, Analog-to-Digital Converter (ADC), and data processing Application Specific Integrated Circuits (ASICs) as well as from cooling and support structures. This article will present the experience gained from four years of operating PXD; the first full scale detector employing the DePFET technology in High Energy Physics. Overall, the PXD has met the expectations. Operating in the intense SuperKEKB environment poses many challenges that will also be discussed. The current PXD system remains incomplete with only 20 out of 40 modules having been installed. A full replacement has been constructed and is currently in its final testing stage before it will be installed into Belle II during the ongoing long shutdown that will last throughout 2023

Raman spectroscopy: techniques and applications in the life sciences

Raman spectroscopy is an increasingly popular technique in many areas including biology and medicine. It is based on Raman scattering, a phenomenon in which incident photons lose or gain energy via interactions with vibrating molecules in a sample. These energy shifts can be used to obtain information regarding molecular composition of the sample with very high accuracy. Applications of Raman spectroscopy in the life sciences have included quantification of biomolecules, hyperspectral molecular imaging of cells and tissue, medical diagnosis, and others. This review briefly presents the physical origin of Raman scattering explaining the key classical and quantum mechanical concepts. Variations of the Raman effect will also be considered, including resonance, coherent, and enhanced Raman scattering. We discuss the molecular origins of prominent bands often found in the Raman spectra of biological samples. Finally, we examine several variations of Raman spectroscopy techniques in practice, looking at their applications, strengths, and challenges. This review is intended to be a starting resource for scientists new to Raman spectroscopy, providing theoretical background and practical examples as the foundation for further study and exploration

Exposure assessment of process-related contaminants in food by biomarker monitoring

Exposure assessment is a fundamental part of the risk assessment paradigm, but can often present a number of challenges and uncertainties. This is especially the case for process contaminants formed during the processing, e.g. heating of food, since they are in part highly reactive and/or volatile, thus making exposure assessment by analysing contents in food unreliable. New approaches are therefore required to accurately assess consumer exposure and thus better inform the risk assessment. Such novel approaches may include the use of biomarkers, physiologically based kinetic (PBK) modelling-facilitated reverse dosimetry, and/or duplicate diet studies. This review focuses on the state of the art with respect to the use of biomarkers of exposure for the process contaminants acrylamide, 3-MCPD esters, glycidyl esters, furan and acrolein. From the overview presented, it becomes clear that the field of assessing human exposure to process-related contaminants in food by biomarker monitoring is promising and strongly developing. The current state of the art as well as the existing data gaps and challenges for the future were defined. They include (1) using PBK modelling and duplicate diet studies to establish, preferably in humans, correlations between external exposure and biomarkers; (2) elucidation of the possible endogenous formation of the process-related contaminants and the resulting biomarker levels; (3) the influence of inter-individual variations and how to include that in the biomarker-based exposure predictions; (4) the correction for confounding factors; (5) the value of the different biomarkers in relation to exposure scenario’s and risk assessment, and (6) the possibilities of novel methodologies. In spite of these challenges it can be concluded that biomarker-based exposure assessment provides a unique opportunity to more accurately assess consumer exposure to process-related contaminants in food and thus to better inform risk assessment

Portrayals of the Holocaust in English history textbooks, 1991–2016: continuities, challenges and concerns

This study examines portrayals of the Holocaust in a sample of 21 secondary school history textbooks published in England between 1991 and 2016. Evaluated against internationally recognized criteria and guidelines, the content of most textbooks proved very problematic. Typically, textbooks failed to provide clear chronological and geographical frameworks and adopted simplistic Hitler-centric, perpetrator-oriented narratives. Furthermore, textbooks paid limited attention to pre-war Jewish life, the roots of antisemitism, the complicity of local populations and collaborationist regimes, and the impact of the Holocaust on people across Europe. Based on these critical findings, the article concludes by offering initial recommendations for textbook improvement