Spin excitations in K0.84_{0.84}Fe1.99_{1.99}Se2_2 superconductor as studied by M\"ossbauer spectroscopy

M\"ossbauer spectroscopy was used to probe the site specific information of the $K_{0.84}Fe_{1.99}Se_2$ superconductor. Possibility of coexistence of superconductivity and magnetism is discussed. A spin excitation gap, $\Delta E \approx$5\,meV, is observed by analyzing the temperature dependence of the hyperfine magnetic field (HMF) at the iron site within the spin wave theory. Using a simple model suggested in the literature, the temperature dependence of the HMF is well reproduced, suggesting that, below room temperature, the iron-selenide superconductors can be regarded as ferromagnetically coupled spin blocks that interact with each other antiferromagnetically to form the observed checkerboard-like magnetic structure

Charge redistribution at the antiferromagnetic phase transition in SrFeAsF compound

The relationship between spin, electron, and crystal structure has been one of the foremost issues in understanding the superconducting mechanism since the discovery of iron-based high temperature superconductors. Here, we report M\"ossbauer and first-principles calculations studies of the parent compound SrFeAsF with the largest temperature gap ($\sim$50\,K) between the structural and antiferromagnetic (AFM) transitions. Our results reveal that the structural transition has little effect on the electronic structure of the compound SrFeAsF while the development of the AFM order induces a redistribution of the charges near the Fermi level.Comment: 6 Pages, 7 Figure

M\"ossbauer spectroscopy study of magnetic fluctuations in superconducting RbGd2_2Fe4_4As4_4O2_2

$^{57}$Fe M\"ossbauer spectra were measured at different temperatures between 5.9 K and 300 K on the recently discovered self-doped superconducting RbGd$_2$Fe$_4$As$_4$O$_2$ with T$_c$ as high as 35 K. Singlet pattern was observed down to the lowest temperature measured in this work, indicating the absence of static magnetic order on the Fe site. The intermediate isomer shift in comparison with that of the samples RbFe$_2$As$_2$ and GdFeAsO confirms the self doping induced local electronic structure change. Surprisingly, we observe two magnetic fluctuation induced spectral broadenings below $\sim$15 K and $\sim$100 K which are believed to be originated from the transferred magnetic fluctuations of the Gd$^{3+}$ moments and that of the magnetic fluctuations of the Fe atoms, respectively.Comment: 6 pages, 6 figures, 1 tabl

Micrometer thick soft magnetic films with magnetic moments restricted strictly in plane by negative magnetocrystalline anisotropy

Stripe domains or any other type domain structures with part of their magnetic moments deviating from the film plane, which usually occur above a certain film thickness, are known problems that limit their potential applications for soft magnetic thin films (SMTFs). In this work, we report the growth of micrometer thick c-axis oriented hcp-Co84Ir16 SMTFs with their magnetic moments restricted strictly in plane by negative magnetocrystalline anisotropy. Extensive characterizations have been performed on these films, which show that they exhibit very good soft magnetic properties even for our micrometer thick films. Moreover, the anisotropy properties and high-frequency properties were thoroughly investigated and our results show very promising properties of these SMTFs for future applications.Comment: 11 pages, 6 figure

Magneto-structural coupling and harmonic lattice dynamics in CaFe2_2As2_2 probed by M\"ossbauer spectroscopy

In this paper we present detailed M\"ossbauer spectroscopy study of structural and magnetic properties of the undoped parent compound CaFe$_2$As$_2$ single crystal. By fitting the temperature dependence of the hyperfine magnetic field we show that the magneto-structural phase transition is clearly first-order in nature and we also deduced the compressibility of our sample to be $1.67\times10^{-2}\,GPa^{-1}$. Within the Landau's theory of phase transition, we further argue that the observed phase transition may stem from the strong magneto-structural coupling effect. Temperature dependence of the Lamb-M\"ossbauer factor show that the paramagnetic phase and the antiferromagnetic phase exhibit similar lattice dynamics in high frequency modes with very close Debye temperatures, $\Theta_D \sim$270\,K.Comment: 6 pages,5 figures Accepted by J. Phys.: Condens. Matte

Study of the rare earth effects on the magnetic fluctuations in RbLn2_2Fe4_4As4_4O2_2 (Ln = Tb, Dy and Ho) by M\"ossbauer spectroscopy

In the current work, we report the investigation of RbLn$_2$Fe$_4$As$_4$O$_2$ (Ln = Tb, Dy and Ho) and RbFe$_2$As$_2$ by $^{57}$Fe M\"ossbauer spectroscopy. Singlet pattern has been observed for all the samples indicating the absence of static magnetic ordering down to 5.9\,K on the Fe sublattice. The observed intermediate value of the isomer shift confirms the effective self charge transfer effect for the studied superconductors. Debye temperatures of these samples have been determined by the temperature dependence of the isomer shift. Most importantly, we observe different spectral line width broadening behaviors for samples with different rare earth elements, and no line width broadenings for samples Ln=Tb and Ho. These results suggest that the observed magnetic fluctuations at the Fe site might be sensitive to the magnetic behaviors of the rare earth magnetic moments.Comment: 5 pages, 4 figures, J Supercond Nov Magn (2018

BaFe12O19 single-particle-chain nanofibers : preparation, characterization, formation principle, and magnetization reversal mechanism

BaFe12O19 single-particle-chain nanofibers have been successfully prepared by an electrospinning method and calcination process, and their morphology, chemistry, and crystal structure have been characterized at the nanoscale. It is found that individual BaFe12O19 nanofibers consist of single nanoparticles which are found to stack along the nanofiber axis. The chemical analysis shows that the atomic ratio of Ba/Fe is 1:12, suggesting a BaFe12O19 composition. The crystal structure of the BaFe12O19 single-particle-chain nanofibers is proved to be M-type hexagonal. The single crystallites on each BaFe12O19 single-particlechain nanofibers have random orientations. A formation mechanism is proposed based on thermogravimetry/differential thermal analysis (TG-DTA), X-ray diffraction (XRD), and transmission electron microscopy (TEM) at six temperatures, 250, 400, 500, 600, 650, and 800 �C. The magnetic measurement of the BaFe12O19 single-particle-chain nanofibers reveals that the coercivity reaches a maximum of 5943 Oe and the saturated magnetization is 71.5 emu/g at room temperature. Theoretical analysis at the micromagnetism level is adapted to describe the magnetic behavior of the BaFe12O19 single-particle-chain nanofibers

Achievement of Diverse Domain Structures in Soft Magnetic Thin Film through Adjusting Intrinsic Magnetocrystalline Anisotropy

Oriented soft magnetic hcp-Co(1 − x)Ir(x) films with a fixed thickness of 120 nm were fabricated. All prepared films exhibit soft magnetic properties but various magnetocrystalline anisotropies with the variation of Ir content. The measured data shows that diverse domain structures including the Néel wall, Bloch wall, and stripe domains present in a fixed film thickness. It is singular for the single-layer soft magnetic film to possess diverse domains in a fixed thickness. This phenomenon was explained by introducing intrinsic magnetocrystalline anisotropy energy into soft magnetic films rather than the structural parameters of the film, inner stress, and microstructure effect