Unusual, basin-scale, fluid–rock interaction in the Palaeoproterozoic Onega basin from Fennoscandia : Preservation in calcite δ18O of an ancient high geothermal gradient

Acknowledgements We acknowledge financial support from ICDP for the drilling programme. AEF, ATB and ARP thank NERC for financial support through NE/G00398X/1. VAM thanks the Norwegian Research Council for financial support through 191530/V30. We are grateful for sample preparation and analyses to all the personnel at NGU lab. At SUERC we enjoyed exceptional analytical support from Julie Dougans. Anonymous reviewers and the editor provided comments that improved the final manuscript.Peer reviewedPostprin

Job-Hopping in Silicon Valley: Some Evidence Concerning the Micro-Foundations of a High Technology Cluster

Observers of Silicon Valley’s computer cluster report that employees move rapidly between competing firms, but evidence supporting this claim is scarce. Job-hopping is important in computer clusters because it facilitates the reallocation of talent and resources toward firms with superior innovations. Using new data on labor mobility, we find higher rates of job-hopping for college-educated men in Silicon Valley’s computer industry than in computer clusters located out of the state. Mobility rates in other California computer clusters are similar to Silicon Valley’s, suggesting some role for features of California law that make non-compete agreements unenforceable. Consistent with our model of innovation, mobility rates outside of computer industries are no higher in California than elsewhere.agglomerations, clusters, non-compete agreements, human capital, innovation, Silicon Valley, modular production.

The structural and diagenetic evolution of injected sandstones: examples from the Kimmeridgian of NE Scotland

Abstract: Injected sandstones occurring in the Kimmeridgian of NE Scotland along the bounding Great Glen and Helmsdale faults formed when basinal fluids moved upward along the fault zones, fluidizing Oxfordian sands encountered at shallow depth and injecting them into overlying Kimmeridgian strata. The orientation of dykes, in addition to coeval faults and fractures, was controlled by a stress state related to dextral strike-slip along the bounding fault zones. Diagenetic studies of cements allow the reconstruction of the fluid flow history. The origin of deformation bands in sandstone dykes and sills was related to the contraction of the host-rocks against dyke and sill walls following the initial stage of fluidized flow, and these deformation bands are the earliest diagenetic imprint. Early non-ferroan calcite precipitated in injection structures at temperatures between 70 and 100 8C, indicating that it precipitated from relatively hot basinal fluids that drove injection. Coeval calcite-filled fractures show similar temperatures, suggesting that relatively hot fluids were responsible for calcite precipitation in any permeable pathway created by dextral simple shear along the faults. During progressive burial, percolating sea water was responsible for completely cementing the still relatively porous injected sandstones with a second generation of ferroan calcite, which contains fluid inclusions with homogenization temperatures below 50 8C. During this phase, depositional host sandstones were also cemented

"Job-Hopping in Silicon Valley: Some Evidence Concerning the Micro-Foundations of a High Technology Cluster"

Observers of Silicon Valley's computer cluster report that employees move rapidly between competing firms, but evidence supporting this claim is scarce. Job-hopping is important in computer clusters because it facilitates the reallocation of talent and resources toward firms with superior innovations. Using new data on labor mobility, we find higher rates of job-hopping for college-educated men in Silicon Valley's computer industry than in computer clusters located out of the state. Mobility rates in other California computer clusters are similar to Silicon Valley's, suggesting some role for features of California law that make non-compete agreements unenforceable. Consistent with our model of innovation, mobility rates outside of computer industries are no higher in California than elsewhere.

Ocean acidification in the aftermath of the Marinoan glaciation

Boron isotope patterns preserved in cap carbonates deposited in the aftermath of the younger Cryogenian (Marinoan, ca. 635 Ma) glaciation confirm a temporary ocean acidification event on the continental margin of the southern Congo craton, Namibia. To test the significance of this acidification event and reconstruct Earth’s global seawater pH states at the Cryogenian-Ediacaran transition, we present a new boron isotope data set recorded in cap carbonates deposited on the Yangtze Platform in south China and on the Karatau microcontinent in Kazakhstan. Our compiled δ11B data reveal similar ocean pH patterns for all investigated cratons and confirm the presence of a global and synchronous ocean acidification event during the Marinoan deglacial period, compatible with elevated postglacial pCO2 concentrations. Differences in the details of the ocean acidification event point to regional distinctions in the buffering capacity of Ediacaran seawater

Petrography and geochemistry of carbonate rocks of the Paleoproterozoic Zaonega Formation, Russia : Documentation of C-13-depleted non-primary calcite

The Norwegian Research Council grant 191530/V30 to V.A. Melezhik fully funded the work of AEC, VAM and AL. ATB was supported by NERC grant NE/G00398X/1 to AEF and ARP. We are grateful for sample preparation and analyses to all the personnel at NGU lab. We appreciate the work on carbon and oxygen isotope analyses by Julie Dougans and Chris Taylor. Bojan Otoničar organized and helped with the CL work at the Karst Research Institute at Postojna. Arrangement of TOC, IC, and TC analyses at University of Münster is acknowledged to Harald Strauss.Peer reviewedPostprin

Job-hopping in Silicon Valley: some evidence concerning the micro-foundations of a high technology cluster

Observers of Silicon Valley's computer cluster report that employees move rapidly between competing firms, but evidence supporting this claim is scarce. Job-hopping is important in computer clusters because it facilitates the reallocation of talent and resources toward firms with superior innovations. Using new data on labor mobility, we find higher rates of job-hopping for college-educated men in Silicon Valley's computer industry than in computer clusters located out of the state. Mobility rates in other California computer clusters are similar to Silicon Valley's, suggesting some role for features of California law that make non-compete agreements unenforceable. Consistent with our model of innovation, mobility rates outside of computer industries are no higher in California than elsewhere

Frictional Wage Dispersion in Search Models: A Quantitative Assessment

We propose a new measure of frictional wage dispersion: the mean-min wage ratio. For a large class of search models, we show that this measure is independent of the wage-offer distribution but depends on statistics of labor-market turnover and on preferences. Under plausible preference parameterizations, observed magnitudes for worker flows imply that in the basic search model, and in most of its extensions, frictional wage dispersion is very small. Notable exceptions are some of the most recent models of on-the-job search. Our new measure allows us to rationalize the diverse empirical findings in the large literature estimating structural search models. (JEL D81, D83, J31, J41, J64)

Factors influencing the stable carbon isotopic composition of suspended and sinking organic matter in the coastal Antarctic sea ice environment

A high resolution time-series analysis of stable carbon isotopic signatures in particulate organic carbon (δ<sup>13</sup>C<sub>POC</sub>) and associated biogeochemical parameters in sea ice and surface waters provides an insight into the factors affecting δ<sup>13</sup>C<sub>POC</sub> in the coastal western Antarctic Peninsula sea ice environment. The study covers two austral summer seasons in Ryder Bay, northern Marguerite Bay between 2004 and 2006. A shift in diatom species composition during the 2005/06 summer bloom to near-complete biomass dominance of <i>Proboscia inermis</i> is strongly correlated with a large ~10 ‰ negative isotopic shift in δ<sup>13</sup>C<sub>POC</sub> that cannot be explained by a concurrent change in concentration or isotopic signature of CO<sub>2</sub>. We hypothesise that the δ<sup>13</sup>C<sub>POC</sub> shift may be driven by the contrasting biochemical mechanisms and utilisation of carbon-concentrating mechanisms (CCMs) in different diatom species. Specifically, very low δ<sup>13</sup>C<sub>POC</sub> in <i>P. inermis</i> may be caused by the lack of a CCM, whilst some diatom species abundant at times of higher δ<sup>13</sup>C<sub>POC</sub> may employ CCMs. These short-lived yet pronounced negative δ<sup>13</sup>C<sub>POC</sub> excursions drive a 4 ‰ decrease in the seasonal average δ<sup>13</sup>C<sub>POC</sub> signal, which is transferred to sediment traps and core-top sediments and consequently has the potential for preservation in the sedimentary record. This 4 ‰ difference between seasons of contrasting sea ice conditions and upper water column stratification matches the full amplitude of glacial-interglacial Southern Ocean δ<sup>13</sup>C<sub>POC</sub> variability and, as such, we invoke phytoplankton species changes as a potentially important factor influencing sedimentary δ<sup>13</sup>C<sub>POC</sub>. We also find significantly higher δ<sup>13</sup>C<sub>POC</sub> in sea ice than surface waters, consistent with autotrophic carbon fixation in a semi-closed environment and possible contributions from post-production degradation, biological utilisation of HCO<sub>3</sub><sup>−</sup> and production of exopolymeric substances. This study demonstrates the importance of surface water diatom speciation effects and isotopically heavy sea ice-derived material for δ<sup>13</sup>C<sub>POC</sub> in Antarctic coastal environments and underlying sediments, with consequences for the utility of diatom-based δ<sup>13</sup>C<sub>POC</sub> in the sedimentary record

Contemporaneous late cretaceous calc-alkaline and alkaline magmatism in Central Anatolia, Turkey: oxygen isotope constraints on petrogenesis

A wide variety of rock types were produced by the latest Cretaceous magmatism in the Central Anatolian Crystalline Complex. These rocks can be divided into three distinct units: (i) calc-alkaline, (ii) subalkaline/transitional, and (iii) alkaline. The calc-alkaline rocks are mainly metaluminous (I-type) ranging from monzodiorite to granite. The subalkaline/transitional rocks are also metaluminous (I-type) ranging from monzonite to granite. The alkaline rocks are mainly peralkaline (A-type), ranging from feldspathoid-bearing monzosyenite to granite. Whole-rock oxygen isotope data from the complex have a considerable range of δ18O values between 6.5‰ and 14.8‰. Initial 87Sr/86Sr versus 143Nd/144Nd ratios, and both ratios versus δ18O values diagrams show that the intrusive rocks are derived from a subduction-modified mantle and also have experienced fractional crystallisation coupled with crustal assimilation. Delamination of a thermal boundary layer, and/or slab breakoff is the likely mechanisms for the initiation of the diverse magmatism in the complex