Removal of malathion from various waters by advanced oxidation processes

Summary: The degradation of malathion was investigated under various conditions, including ultrasound (US) irradiation, ultraviolet (UV) irradiation, and the combination of US/UV, UV/ZnO, UV/H2O2, and US/UV/ZnO/H2O2. In addition, the effect of the operational parameters, such as the initial concentration of the catalyst, the initial malathion concentration, the initial salt concentration (NaHCO3 and Na2SO4), and pH, were studied. Analyses were performed by a gas chromatography-mass spectroscopy instrument. The k values were in the following order: US/UV/H2O2/ZnO > US/UV > UV/ZnO > UV/H2O2 > UV > US. ZnO concentration of 100 mg/l, malathion initial concentration of 200 μg/l, H2O2 concentration of 30 mg/l, pH of 9, and irradiation time of 105 min were the optimum conditions for degrading malathion by the US/UV/H2O2/ZnO system. Additionally, the optimized parameters were also tested for the treatment of an actual water sample containing the pesticide. As a result, the efficiency of the US/UV/H2O2/ZnO system was higher in the distilled water sample than in the actual water sample. © 2015, Chemical Society of Pakistan. All rights reserved

PHOTOCATALYTIC DEGRADATION OF CHLORPYRIFOS IN WATER USING TITANIUM DIOXIDE AND ZINC OXIDE

In the present work, degradation of chlorpyrifos in water was investigated using semiconductor oxide catalysts, i.e. zinc oxide (ZnO) and titanium dioxide (TiO2). The influence of various parameters, such as type of the catalyst, irradiation time, catalyst concentrations, pH, and sodium bicarbonate salt was also studied. Results indicated that the optimal concentration of the catalyst was 0.15 g/L. It was also found that TiO2 is a better catalyst than ZnO under the same photocatalytic reaction conditions. The highest removal efficiency was achieved at pH 9. Results from the present study suggested that the photodegradation efficiency of pesticides increases with the increase of the illumination time. The photodegradation efficiency of chlorpyrifos was found to be 80% and 90% for UV/ZnO and UV/TiO2, respectively. Photodegradation in the presence of sodium bicarbonate was slower in comparison to that without the salt. In addition, the efficiency of photocatalytic degradation in distilled water was higher than in natural water

Assessment of hospitals medical waste management in Chaharmahal and Bakhtiari Province in Iran

The hospital wastes could threaten the surface waters, ground waters, soil, air environment and humans’ health. This study was intended to investigate the management of medical waste generated in hospitals of Charharmahal and Bakhtiari province, located in south west of Iran. The samples came from all 9 province’s hospitals with 1156 beds. The data forms and questionnaires were completed. The questionnaire contained questions about the generation of waste and practices related to separation, collection, storage, transport, treatment and final disposal, and training and awareness. The highest generation rate on a bed basis of 3.22±0.4 kg/bed/day was found in Shohada hospital, and the lowest rate was 1.37±0.2 kg/bed/day for Sina hospital. There was significant variation (P<0.05). The average general waste production rate was 2.12±0.37 kg/bed/day at all the surveyed hospitals. The highest percentage (63%) of total medical wastes were general, 36.05% were infectious wastes. About 44.44% of the hospitals have used autoclave to disinfect their infectious medical waste prior to disposal, while incineration is used in 33.33% of the hospitals. All hospitals (100%) indicated their needs and willingness to participate in future specialized training programs in medical waste management. It has been suggested that enhancing the education, awareness and promoting programs about medical waste management for cleaning workers, doctors, nurses, and technicians

Removal of malathion insecticide from water by employing acoustical wave technology

Background: Organophosphorus pesticides are one of the most prevalent usages for pest control in the country. Such pesticides enter into water sources by different routes. Since drinking of contaminated water at the higher doses than the standard level, may causes undesirable effects to human health and ecosystem. The object of this research was to investigate the effect of various parameters including time, power and concentration on sonodecomposition of malathion insecticide in the water. Methods: The sonochemical degradation of malathion was investigated using acoustic wave technology (AWT). AWT with 130 kHz was used to study the decomposition of insecticide solution. Samples were analyzed using HPLC at different intervals times. Effectiveness of AWT at different times (20, 40, 60, 80, 100, and 120 minutes), concentrations of malathion at 2, 4 and 8 mg/L as well as powers of device (300W, 400W, 500W) are compared. Results: These findings showed that the degradation of the malathion insecticide at lower concentrations was greater in comparison to higher concentrations. Also, there was positive correlation between power increasing and the ability to malathion degradation Conclusion: The sonodegradation of malathion at different concentrations and powers was successfully achieved. It has been shown that acoustical wave technology can be used to reduce the concentration of dissolved insecticide using high frequency

Numerical Detection of Cavitation Damage on Dam Spillway

The present paper deals with the numerical detection of cavitation damage level and location on dam spillways. At first, flow over a spillway was simulated using the computational fluid dynamics method. The flow characteristics such as pressure, velocity and depth through the spillway have been calculated for five different flow rates. Since the actual flow is turbulent, the RNG turbulence model has been used for simulation. The numerical results of flow characteristics including flow depth, velocity and pressure were compared with the available results of the hydraulic model tests. The numerical results agreed well with the experimental data, and reasonable values for the normalized root mean square error (NRMSE= 0.0476) and coefficient of determination (r2=0.8354) indicated that the numerical model is accurate. Finally occurrence of cavitation damage to the Doosti dam spillway was investigated. Based on cavitation index, five different damage levels from no damage to major damage have been considered. Results showed that the spillway may be at the risk of cavitation damage, and the serious damage can occur at ending parts of the structure

Coping With Stress in Iranian School-Age Children

Background: Methods learnt by children to cope with stress will be used in their adolescence. Failure to learn adaptive coping strategies causes some mental, physical and behavioral problems which continue until adulthood. Objectives: The current study was conducted to investigate the methods of coping with stress among Iranian school-age children. Patients and Methods: A descriptive study was conducted in which a randomly selected sample of 839 students of third to fifth grade of primary school in Tabriz, Iran participated. The data were collected using the Schoolagers` Coping Strategies Inventory questionnaire. SPSS software was employed to analyze the data by percentage, absolute frequency, and linear regression test. Results: All coping methods inserted in the questionnaire were used by students. More than 70% of students mentioned “pray”, “say I’m sorry or tell the truth”, and “try to relax, stay calm” out of 26 cases of coping strategies. According to more than 60% of children, “pray”, “say I’m sorry or tell the truth”, and “draw, write, or read something” were the most useful coping methods and “pick on someone” and “yell or scream” were not mostly used by the children under study. Conclusions: Children use variable methods to cope with their stress. Therefore, parents, health trainers and school authorities should distinguish non-adaptive methods of children and teach them the adaptive coping strategies

Physical and psychological scars: The impact of breast cancer on women's body image

Whilst breast cancer remains the most common cancer amongst women in the United Kingdom, advances in medicine have seen survival rates improve over the years and the number of women living with the residual consequences of the disease and its treatment is growing. Women are likely to undergo a number of treatments at once, or in succession of one another, each of which brings about various changes to appearance, e.g. hair loss. These wide ranging appearance alterations can impose an adverse impact on body image, causing substantial distress for many women (Dahl et al., 2010). This article reviews research exploring the body image of women with breast cancer, a group who experience a wide range of changes to their appearance as a side effect of treatment for the disease

Ensemble Classification and Extended Feature Selection for Credit Card Fraud Detection

Due to the rise of technology, the possibility of fraud in different areas such as banking has been increased. Credit card fraud is a crucial problem in banking and its danger is over increasing. This paper proposes an advanced data mining method, considering both feature selection and decision cost for accuracy enhancement of credit card fraud detection. After selecting the best and most effective features, using an extended wrapper method, ensemble classification is performed. The extended feature selection approach includes a prior feature filtering and a wrapper approach using C4.5 decision tree. Ensemble classification, using cost sensitive decision trees is performed in a decision forest framework. A locally gathered fraud detection dataset is used to estimate the proposed method. The proposed method is assessed using accuracy, recall, and F-measure as evaluation metrics and compared with basic classification algorithms including ID3, J48, Naïve Bayes, Bayesian Network and NB tree. Experiments show that considering the F-measure as evaluation metric, the proposed approach yields 1.8 to 2.4 percent performance improvement compared to other classifiers

The association of circulating levels of complement-C1q TNF-related protein 5 (CTRP5) with nonalcoholic fatty liver disease and type 2 diabetes: A case-control study

Background: It is well-established that nonalcoholic fatty liver disease (NAFLD) is associated with type 2 diabetes mellitus (T2DM). Complement-C1q TNF-related protein 5 (CTRP5) is a novel adipokine involved in the regulation of lipid and glucose metabolism. We aimed to assess plasma levels of CTRP5 in patients with NAFLD (n = 22), T2DM (n = 22) and NAFLD with T2DM (NAFLD + T2DM) (n = 22) in comparison with healthy subjects (n = 21) and also to study the association between CTRP5 levels and NAFLD and diabetes-related parameters. Methods: All subjects underwent anthropometric assessment, biochemical evaluation and liver stiffness (LS) measurement. Insulin resistance (IR) was determined by the homeostasis model assessment (HOMA). Plasma CTRP5 levels were measured by enzyme-linked immunosorbent assay. Results: We found significantly lower plasma levels of CTRP5 in patients with NAFLD + T2DM, NAFLD and T2DM (122.52 ± 1.92, 124.7 ± 1.82 and 118.31 ± 1.99 ng/ml, respectively) in comparison with controls (164.96 ± 2.95 ng/ml). In the whole study population, there was a significant negative correlations between CTRP5 and body mass index (r = -0.337; p = 0.002), fasting blood glucose (FBG) (r = -0.488; p < 0.001), triglyceride (TG) (r = -0.245; p = 0.031), HOMA-IR (r = -0.492; p < 0.001), insulin(r = -0.338; p = 0.002), LS (r = -0.544; p < 0.001), alanine aminotransferase (ALT) (r = -0.251; p = 0.027), waist-to-hip ratio (WHR) (r = -0.352; p = 0.002) and waist circumference (WC) (r = -0.357; p = 0.001). After adjustment for BMI, decrease in circulating levels of CTRP5 remained as a significant risk factor for NAFLD, T2DM and NAFLD + T2DM. The receiver operating characteristic (ROC) curves of circulating CTRP5 in predicting NAFLD and T2DM demonstrated an area under the curve (AUC) of 0.763 in T2DM, and 0.659 in NAFLD + T2DM. Conclusions: It appears that the decreased levels of CTRP5 contribute to the increased risk of T2DM and NAFLD. © 2015 Emamgholipour et al

Degradation of Organophosphorus Pesticides in Water during UV/H2O2 Treatment: Role of Sulphate and Bicarbonate Ions

Abstract: The photodegradation of two organophosphorus pesticides, malathian and diazinon, by sulfate radicals and bicarbonate radicals in aqueous solution were studied. The effect of the operational parameters such as pH, salt concentration, water type, H2O2 concentration and initial concentration of pesticides was studied. Gas chromatography mass spectroscopy (GC-MS) was used for analyses of pesticides. When salt effect was studied, it was found that sodium bicarbonate was the most powerful inhibitor used, while sodium sulfate was the weakest one. The highest degradation in UV/H2O2 process for malathion was found in alkaline condition and for diazinon in acidic condition. The photodegradation in all waters used in this work exhibited first order kinetics. Photodegradation rate in distilled water was higher than real water. The degradation of pesticides increased with increasing of H2O2 concentration