The mechanism of thickness selection in the Sadler-Gilmer model of polymer crystallization

Recent work on the mechanism of polymer crystallization has led to a proposal for the mechanism of thickness selection which differs from those proposed by the surface nucleation theory of Lauritzen and Hoffman and the entropic barrier model of Sadler and Gilmer. This has motivated us to reexamine the model used by Sadler and Gilmer. We again find a fixed-point attractor which describes the dynamical convergence of the crystal thickness to a value just larger than the minimum stable thickness, l_min. This convergence arises from the combined effect of two constraints on the length of stems in a layer: it is unfavourable for a stem to be shorter than l_min and for a stem to overhang the edge of the previous layer. The relationship between this new mechanism and the explanation given by Sadler and Gilmer in terms of an entropic barrier is discussed. We also examine the behaviour of the Sadler-Gilmer model when an energetic contribution from chain folds is included.Comment: 15 pages, 13 figures, revte

On the Infrared Behavior of the Pressure in Thermal Field Theories

We study non-perturbatively, via the Schwinger-Dyson equations, the leading infrared behavior of the pressure in the ladder approximation. This problem is discussed firstly in the context of a thermal scalar field theory, and the analysis is then extended to the Yang-Mills theory at high temperatures. Using the Feynman gauge, we find a system of two coupled integral equations for the gluon and ghost self-energies, which is solved analytically. The solutions of these equations show that the contributions to the pressure, when calculated in the ladder approximation, are finite in the infrared domain.Comment: 20 pages plus 4 figures available by request, IFUSP/P-100