Negative electrode catalyst for the iron chromium redox energy storage system

A redox cell which operates at elevated temperatures and which utilizes the same two metal couples in each of the two reactant fluids is disclosed. Each fluid includes a bismuth salt and may also include a lead salt. A low cost, cation permselective membrane separates the reactant fluids

The discrete flavor symmetry D5

We consider the standard model (SM) extended by the flavor symmetry D5 and search for a minimal model leading to viable phenomenology. We find that it contains four Higgs fields apart from the three generations of fermions whose left- and left-handed conjugate parts do not transform in the same way under D5. We provide two numerical fits for the case of Dirac and Majorana neutrinos to show the viability of our low energy model. The fits can accommodate all data with the neutrinos being normally ordered. For Majorana neutrinos two of the right-handed neutrinos are degenerate. Concerning the Higgs sector we find that all potentials constructed with three SM-like Higgs doublets transforming as 1+2 under D5 have a further unwanted global U(1) symmetry. Therefore we consider the case of four Higgs fields forming two D5 doublets and show that this potential leads to viable solutions in general, however it does not allow spontaneous CP-violation (SCPV) for an arbitrary vacuum expectation value (VEV) configuration. Finally, we discuss extensions of our model to grand unified theories (GUTs) as well as embeddings of D5 into the continuous flavor symmetries SO(3)_f and SU(3)_f.Comment: 22 page

Superadiabatic transitions in quantum molecular dynamics

We study the dynamics of a molecule’s nuclear wave function near an avoided crossing of two electronic energy levels for one nuclear degree of freedom. We derive the general form of the Schrödinger equation in the nth superadiabatic representation for all n є N. Using these results, we obtain closed formulas for the time development of the component of the wave function in an initially unoccupied energy subspace when a wave packet travels through the transition region. In the optimal superadiabatic representation, which we define, this component builds up monotonically. Finally, we give an explicit formula for the transition wave function away from the avoided crossing, which is in excellent agreement with high-precision numerical calculations

Quantum Collective QCD String Dynamics

The string breaking model of particle production is extended in order to help explain the transverse momentum distribution in elementary collisions. Inspired by an idea of Bialas', we treat the string using a collective coordinate approach. This leads to a chromo-electric field strength which fluctuates, and in turn implies that quarks are produced according to a thermal distribution.Comment: 6 pages. Presented at SQM 2006. Submitted to J. Phys. G for publication in proceedings. Vers. 2: Minor revisions; final hadron spectrum calculation include

Micro-canonical pentaquark production in \ee annihilations

The existence of pentaquarks, namely baryonic states made up of four quarks and one antiquark, became questionable, because the candidates, i.e. the $\Theta^+$ peak, are seen in certain reactions, i.e. p+p collisions, but not in others, i.e. \ee annihilations. In this paper, we estimate the production of $\Theta ^{+}(1540)$ and $\Xi^{--} (1860)$ in \ee annihilations at different energies using Fermi statistical model as originally proposed in its microcanonical form. The results is compared with that from pp collisions at SPS and RHIC energies. We find that, if pentaquark states exist, the production is highly possible in \ee annihilations. For example, at LEP energy $\sqrt{s}$=91.2 GeV, both $\Theta ^{+}(1540)$ and $\Xi^{--} (1860)$ yield more than in pp collisions at SPS and RHIC energy.Comment: 7 pages 2 figure

Single cell performance studies on the Fe/Cr Redox Energy Storage System using mixed reactant solutions at elevated temperature

Experimental studies in a 14.5 sq cm single cell system using mixed reactant solutions at 65 C are described. Systems were tested under isothermal conditions i.e., reactants and the cell were at the same temperature. Charging and discharging performance were evaluted by measuring watt-hour and coulombic efficiencies, voltage-current relationships, hydrogen evolution and membrane resistivity. Watt-hour efficiencies ranged from 86% at 43 ma/sq cm to 75% at 129 ma/sq cm with corresponding coulombic efficiencies of 92% and 97%, respectively. Hydrogen evolution was less than 1% of the charge coulombic capacity during charge-discharge cycling. Bismuth and bismuth-lead catalyzed chromium electrodes maintained reversible performance and low hydrogen evolution under normal and adverse cycling conditions. Reblending of the anode and cathode solutions was successfully demonstrated to compensate for osmotic volume changes. Improved performance was obtained with mixed reactant systems in comparison to the unmixed reactant systems

Cycling Performance of the Iron-Chromium Redox Energy Storage System

Extended charge-discharge cycling of this electrochemical storage system at 65 C was performed on 14.5 sq cm single cells and a four cell, 867 sq cm bipolar stack. Both the anolyte and catholyte reactant fluids contained 1 molar concentrations of iron and chromium chlorides in hydrochloric acid and were separated by a low-selectivity, cation-exchange membrane. The effect of cycling on the chromium electrode and the cation-exchange membrane was determined. Bismuth and bismuth-lead catalyzed chromium electrodes and a radiation-grafted polyethylene membrane were evaluated by cycling between 5 and 85 percent state-of-charge at 80 mA/sq cm and by periodic charge-discharge polarization measurements to 140 mA/sq cm. Gradual performance losses were observed during cycling but were recoverable by completely discharging the system. Good scale-up to the 867 sq cm stack was achieved. The only difference appeared to be an unexplained resistive-type loss which resulted in a 75 percent W-hr efficiency (at 80 mA/sq cm versus 81 percent for the 14.5 sq cm cell). A new rebalance cell was developed to maintain reactant ionic balance. The cell successfully reduced ferric ions in the iron reactant stream to ferrous ions while chloride ions were oxidized to chlorine gas

Crossover transition in bag-like models

We formulate a simple model for a gas of extended hadrons at zero chemical potential by taking inspiration from the compressible bag model. We show that a crossover transition qualitatively similar to lattice QCD can be reproduced by such a system by including some appropriate additional dynamics. Under certain conditions, at high temperature, the system consist of a finite number of infinitely extended bags, which occupy the entire space. In this situation the system behaves as an ideal gas of quarks and gluons.Comment: Corresponds to the published version. Added few references and changed the titl

The QCD phase diagram: A comparison of lattice and hadron resonance gas model calculations

We compare the lattice results on QCD phase diagram for two and three flavors with the hadron resonance gas model (HRGM) calculations. Lines of constant energy density $\epsilon$ have been determined at different baryo-chemical potentials $\mu_B$. For the strangeness chemical potentials $\mu_S$, we use two models. In one model, we explicitly set $\mu_S=0$ for all temperatures and baryo-chemical potentials. This assignment is used in lattice calculations. In the other model, $\mu_S$ is calculated in dependence on $T$ and $\mu_B$ according to the condition of vanishing strangeness. We also derive an analytical expression for the dependence of $T_c$ on $\mu_B/T$ by applying Taylor expansion of $\epsilon$. In both cases, we compare HRGM results on $T_c-\mu_B$ diagram with the lattice calculations. The agreement is excellent, especially when the trigonometric function of $\epsilon$ is truncated up to the same order as done in lattice simulations. For studying the efficiency of the truncated Taylor expansion, we calculate the radius of convergence. For zero- and second-order radii, the agreement with lattice is convincing. Furthermore, we make predictions for QCD phase diagram for non-truncated expressions and physical masses. These predictions are to be confirmed by heavy-ion experiments and future lattice calculations with very small lattice spacing and physical quark masses.Comment: 25 pages, 8 eps figure

The ideal relativistic spinning gas: polarization and spectra

We study the physics of the ideal relativistic rotating gas at thermodynamical equilibrium and provide analytical expressions of the momentum spectra and polarization vector for the case of massive particles with spin 1/2 and 1. We show that the finite angular momentum J entails an anisotropy in momentum spectra, with particles emitted orthogonally to J having, on average, a larger momentum than along its direction. Unlike in the non-relativistic case, the proper polarization vector turns out not to be aligned with the total angular momentum with a non-trivial momentum dependence.Comment: Final published version. Minor corrections to formula