697 research outputs found
Oxygen diffusion and reactivity at low temperature on bare amorphous olivine-type silicate
The mobility of O atoms at very low temperatures is not generally taken into
account, despite O diffusion would add to a series of processes leading to the
observed rich molecular diversity in space. We present a study of the mobility
and reactivity of O atoms on an amorphous silicate surface. Our results are in
the form of RAIRS and temperature-programmed desorption spectra of O2 and O3
produced via two pathways: O + O and O2 + O, investigated in a submonolayer
regime and in the range of temperature between 6.5 and 30 K. All the
experiments show that ozone is formed efficiently on silicate at any surface
temperature between 6.5 and 30 K. The derived upper limit for the activation
barriers of O + O and O2 + O reactions is 150 K/kb. Ozone formation at low
temperatures indicates that fast diffusion of O atoms is at play even at 6.5 K.
Through a series of rate equations included in our model, we also address the
reaction mechanisms and show that neither the Eley Rideal nor the Hot atom
mechanisms alone can explain the experimental values. The rate of diffusion of
O atoms, based on modeling results, is much higher than the one generally
expected, and the diffusive process proceeds via the Langmuir-Hinshelwood
mechanism enhanced by tunnelling. In fact, quantum effects turn out to be a key
factor that cannot be neglected in our simulations. Astrophysically, efficient
O3 formation on interstellar dust grains would imply the presence of huge
reservoirs of oxygen atoms. Since O3 is a reservoir of elementary oxygen, and
also of OH via its hydrogenation, it could explain the observed concomitance of
CO2 and H2O in the ices.Comment: 28 pages, 14 figure
Limits on the use of cobalt sulfide as anode of p-type dye-sensitized solar cells
Thin films of cobalt sulfide (CoS) of thickness l < 10m have been employed as anodes of p-type dye-sensitized solar cells (p-DSCs) when P1-sensitized nickel oxide (NiO) was the photoactive cathode and /I - constituted the redox mediator. In the role of counter electrode for p-DSCs, CoS was preferred over traditional platinized fluorine-doped indium oxide (Pt-FTO) due to the lower cost of the starting materials (Co salts) and the easier procedure of deposition onto large area substrates. The latter process was carried out via direct precipitation of CoS from aqueous solutions. The photoconversion efficiency (η) of the corresponding device was 0.07%. This value is about 35% less than the efficiency that is obtained with the analogous p-DSC employing the Pt-FTO anode (η = 0.11). Unlike p-DSCs based on Pt-FTO anodes, the photoelectrochemical cells employing CoS electrodes showed that this anodic material was not able to sustain the photocurrent densities generated by P1-sensitized NiO at a given photopotential. Illumination of the p-DSCs with CoS anodes and P1-sensitized NiO cathodes actually induced the reverse bias of the photoelectrochemical cell with CoS behaving like a p-type semiconductor with no degeneracy. © 2017 IOP Publishing Ltd
High resolution spectroscopy of the extended narrow-line region of IC 5063 and NGC 7212
We studied the properties of the gas of the extended narrow line region
(ENLR) of two Seyfert 2 galaxies: IC 5063 and NGC 7212. We analysed high
resolution spectra to investigate how the main properties of this region depend
on the gas velocity. We divided the emission lines in velocity bins and we
calculated several line ratios. Diagnostic diagrams and SUMA composite models
(photo-ionization + shocks), show that in both galaxies there might be evidence
of shocks significantly contributing in the gas ionization at high |V|, even
though photo-ionization from the active nucleus remains the main ionization
mechanism. In IC 5063 the ionization parameter depends on V and its trend might
be explained assuming an hollow bi-conical shape for the ENLR, with one of the
edges aligned with the galaxy disk. On the other hand, NGC 7212 does not show
any kind of dependence. The models show that solar O/H relative abundances
reproduce the observed spectra in all the analysed regions. They also revealed
an high fragmentation of the gas clouds, suggesting that the complex kinematics
observed in these two objects might be caused by interaction between the ISM
and high velocity components, such as jets.Comment: 29 pages, 32 figures, accepted for publication in MNRA
Spatio-Temporal Changes of Extracellular Matrix (ECM) Stiffness in the Development of the Leech Hirudo verbana
The invertebrate leech Hirudo verbana represents a powerful experimental animal model for improving the knowledge about the functional interaction between the extracellular matrix (ECM) and cells within the tissue microenvironment (TME), and the key role played by ECM stiffness during development and growth. Indeed, the medicinal leech is characterized by a simple anatomical organization reproducing many aspects of the basic biological processes of vertebrates and in which a rapid spatiotemporal development is well established and easily assessed. Our results show that ECM structural organization, as well as the amount of fibrillar and non-fibrillar collagen are deeply different from hatching leeches to adult ones. In addition, the changes in ECM remodelling occurring during the different leech developmental stages, leads to a gradient of stiffness regulating both the path of migratory cells and their fates. The ability of cells to perceive and respond to changes in ECM composition and mechanics strictly depend on nuclear or cytoplasmic expression of Yes-Associated Protein 1 (YAP1), a key mediator converting mechanical signals into transcriptional outputs, expression, and activation
Scanning electron microscopy study of bone intracortical vessels using an injection and fractured surfaces technique
The intracortical canal/vessel systems of long bones are not yet completely understood in terms of their morphology and physiology, mainly because of the difficulty of injecting the small calibre vessels and cutting the calcified matrix. Here, we apply a novel method combining perfusion of the vessels and fracture of the cortical bone to enlighten the architecture of this system. The femurs of ten rabbits were perfused with a water-soluble dye (China ink) or alcoholic glycerol solution, and the fractured cortex specimens were then examined by scanning electron microscopy (SEM). The results document: (1) the fibrillar structure of the canal surfaces; (2) the perivascular environment with cellular components in different phases of incorporation within the bone matrix; (3) previously unreported filamentous structures on the outer surface of vessels, which could be interpreted as non-myelinic nerve fibres; (4) the inner organisation of the cutting cones. Although based exclusively on morphology, these observation have some relevance to increasing knowledge of bone circulation physiology in the cortical bone
Thermal desorption characteristics of CO, O2 and CO2 on non-porous water, crystalline water and silicate surfaces at sub-monolayer and multilayer coverages
The desorption characteristics of molecules on interstellar dust grains are
important for modelling the behaviour of molecules in icy mantles and,
critically, in describing the solid-gas interface. In this study, a series of
laboratory experiments exploring the desorption of three small molecules from
three astrophysically relevant surfaces are presented. The desorption of CO, O2
and CO2 at both sub-monolayer and multilayer coverages was investigated from
non-porous water, crystalline water and silicate surfaces. Experimental data
was modelled using the Polanyi-Wigner equation to produce a mathematical
description of the desorption of each molecular species from each type of
surface, uniquely describing both the monolayer and multilayer desorption in a
single combined model. The implications of desorption behaviour over
astrophysically relevant timescales are discussed.Comment: 13 pages, 5 figures, accepted for publication in Monthly Notices of
the Royal Astronomical Society Main Journa
Within-plant variation in rosmarinus officinalis l. Terpenes and phenols and their antimicrobial activity against the rosemary phytopathogens alternaria alternata and pseudomonas viridiflava
This study investigated within-plant variability of the main bioactive compounds in rosemary (Rosmarinus officinalis L.). Volatile terpenes, including the enantiomeric distribution of monoterpenes, and phenols were analyzed in young and mature foliar, cortical and xylem tissues. In addition, antimicrobial activity of rosmarinic acid and selected terpenes was evaluated against two rosemary pathogens, Alternaria alternata and Pseudomonas viridiflava. Data showed that total concentration and relative contents of terpenes changed in relation to tissue source and age. Their highest total concentration was observed in the young leaves, followed by mature leaves, cortical and xylem tissues. Rosmarinic acid and carnosic acid contents did not show significant differences between leaf tissues of different ages, while young and mature samples showed variations in the content of four flavonoids. These results are useful for a more targeted harvesting of rosemary plants, in order to produce high-quality essential oils and phenolic extracts. Microbial tests showed that several terpenes and rosmarinic acid significantly inhibited the growth of typical rosemary pathogens. Overall, results on antimicrobial activity suggest the potential application of these natural compounds as biochemical markers in breeding programs aimed to select new chemotypes less susceptible to pathogen attacks, and as eco-friendly chemical alternatives to synthetic pesticides
Expression pattern analysis of odorant-binding proteins in the pea aphid Acyrthosiphon pisum
Odorant-binding proteins (OBPs) are soluble proteins mediating chemoreception in insects. In previous research, we investigated the molecular mechanisms adopted by aphids to detect the alarm pheromone (E)-\u3b2-farnesene and we found that the recognition of this and structurally related molecules is mediated by OBP3 and OBP7. Here, we show the differential expression patterns of 5 selected OBPs (OBP1, OBP3, OBP6, OBP7, OBP8) obtained performing quantitative RT-PCR and immunolocalization experiments in different body parts of adults and in the 5 developmental instars, including winged and unwinged morphs, of the pea aphid Acyrthosiphon pisum. The results provide an overall picture that allows us to speculate on the relationship between the differential expression of OBPs and their putative function. The expression of OBP3, OBP6, and OBP7 in the antennal sensilla suggests a chemosensory function for these proteins, whereas the constant expression level of OBP8 in all instars could suggest a conserved role. Moreover, OBP1 and OBP3 are also expressed in nonsensory organs. A light and scanning electron microscopy study of sensilla on different body parts of aphid, in particular antennae, legs, mouthparts, and cornicles-cauda, completes this research providing a guide to facilitate the mapping of OBP expression profiles
Exploring the parent population of beamed NLS1s: from the black hole to the jet
The aim of this work is to understand the nature of the parent population of
beamed narrow-line Seyfert 1 galaxies (NLS1s), by studying the physical
properties of three parent candidates samples: steep-spectrum radio-loud NLS1s,
radio-quiet NLS1s and disk-hosted radio-galaxies. In particular, we focused on
the black hole mass and Eddington ratio distribution and on the interactions
between the jet and the narrow-line region.Comment: 6 pages, 2 figures, to appear in Proceedings of High Energy Phenomena
in Relativistic Outflows (HEPRO) V, Workshop Series of the Argentinian
Astronomical Societ
Unveiling the parent population of beamed narrow-line Seyfert 1s
Narrow-line Seyfert 1 galaxies (NLS1s) are active galactic nuclei (AGN)
recently identified as a new class of -ray sources. The high energy
emission is explained by the presence of a relativistic jet observed at small
angles, just like in the case of blazars. When the latter are observed at
larger angles they appear as radio-galaxies, but an analogue parent population
for beamed NLS1s has not yet been determined. In this work we analyze this
problem by studying the physical properties of three different samples of
parent sources candidates: steep-spectrum radio-loud NLS1s, radio-quiet NLS1s,
and disk-hosted radio-galaxies, along with compact steep-spectrum sources. In
our approach, we first derived black hole mass and Eddington ratio from the
optical spectra, then we investigated the interaction between the jet and the
narrow-line region from the [O III] 4959,5007 lines. Finally,
the radio luminosity function allowed us to compare their jet luminosity and
hence determine the relations between the samples.Comment: 6 pages, no figures. Proceedings of the 28th Texas Symposium, Geneva,
December 13-18, 201
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