26 research outputs found

    Analytical model to predict the effect of a finite impedance surface on the propagation properties of a 2D Sonic Crystal

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    The use of Sonic Crystals as environmental noise barriers has certain advantages from the acoustical and the constructive point of view with regard to conventional ones. One aspect do not studied yet is the acoustic interaction between the Sonic Crystals and the ground due to, up to now, this latter is not included in the analytical models used to characterize these Sonic Crystals. We present here an analytical model, based on multiple scattering theory, to study this interaction considering the ground as a finite impedance surface. Using this model we have obtained interesting conclusions that allow to design more effectively noise screens based on Sonic Crystals. The obtained results have been compared with experimental and numerical, finding a good agreement between them

    Fate and Toxicity of Carbamazepine and Its Degradation By-Products During Coupling of Ozonation and Nanofiltration for Urban Wastewater Reuse

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    Occurrence of emerging organic micropollutants in water bodies and their effects are a concern related to quality of reused water. Advanced oxidation processes have demonstrated promising results to address this challenge. Nonetheless, these processes may lead to the generation of more toxic oxidation by-products. The aim of this study was to investigate the coupling of ozonation and nanofiltration (NF) applied to carbamazepine (CBZ). It consisted in monitoring the degradation and fate of CBZ and its subsequent by-products, their fate and toxicity. CBZ was completely degraded after 5 min of ozonation and six identified transformation by-products were formed: I (hydroxycarbamazepine), BQM [1-(2-benzaldehyde)-4-hydro-(1H, 3H)-quinazoline-2-one], II (2-(1H)-quinazolinone), BaQM [1-(2-benzoic acid)-4-hydro-(1H, 3H)-quinazoline-2-one], BQD [1-(2-benzaldehyde)-(1H, 3H)-quinazoline-2,4-dione] and BaQD [1-(2-benzoic acid)-(1H, 3H)-quinazoline-2,4-dione]. Mineralization rate of ozonation never exceeded 12% even with high ozone dose. Bioassays with Vibrio fischeri revealed that BQM and BQD are responsible for toxicity. NF is able to remove total organic carbon with removal rate up to 93% at 85% of permeate recovery rate. CBZ and its different ozonation by-products were almost completely retained by NF, except the II, which had an MW slightly lower than the membrane molecular weight cut-off, for which the removal rate was still between 80 and 96% depending on the recovery rate

    Full advanced membrane wastewater treatment (MBR- NF/RO) for direct onboard reuse

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    Brewery wastewater treatment using MBR coupled with nanofiltration or electrodialysis: biomass acclimation and treatment efficiency

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    International audienceBreweries release significant amounts of wastewater loaded with various organic and mineral materials. Prior studies of membrane bioreactor (MBR) wastewater treatment have been conducted with very little interest granted to the conditions of biomass acclimation. This study displays biomass behavior during brewery wastewater treatment by an aerobic MBR. In addition, nanofiltration and electrodialysis have been studied as potential post-treatment to decrease mineral concentrations and permit further water reuse for agriculture. An anoxic/aerobic laboratory MBR, associated with a flat sulfonated polyether membrane was used for synthetic brewery wastewater treatment. Biomass acclimation was performed using a feeding substrate. Organic concentrations in the MBR influent varied from 700 mg COD/L to 10,600 mg COD/L (COD: chemical oxygen demand) for 110 days. The results indicate a good acclimation to effluent with high salts and organic matter loads. Steady evolution of biomass concentration and activities was achieved after 90 days of operation. A reduction of COD of around 95% was obtained with MBR and up to 99% with nanofiltration post-treatment for the reconstructed brewery effluent with an organic loading rate of 7 g COD/L.d and a solid and hydraulic retention time of 30 days and 36 hours. A good reduction of the salt content was also recorded primarily with the nanofiltration and electrodialysis processes
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