Synthesis of various highly halogenated monomers and polymers

Halogenated polyurethane and polycarbonate are synthesized and found to be LOX compatible but dependent upon the type nitrogen bonding

Intermittency in a catalytic random medium

In this paper, we study intermittency for the parabolic Anderson equation $\partial u/\partial t=\kappa\Delta u+\xi u$, where $u:\mathbb{Z}^d\times [0,\infty)\to\mathbb{R}$, $\kappa$ is the diffusion constant, $\Delta$ is the discrete Laplacian and $\xi:\mathbb{Z}^d\times[0,\infty)\to\mathbb {R}$ is a space-time random medium. We focus on the case where $\xi$ is $\gamma$ times the random medium that is obtained by running independent simple random walks with diffusion constant $\rho$ starting from a Poisson random field with intensity $\nu$. Throughout the paper, we assume that $\kappa,\gamma,\rho,\nu\in (0,\infty)$. The solution of the equation describes the evolution of a ``reactant'' $u$ under the influence of a ``catalyst'' $\xi$. We consider the annealed Lyapunov exponents, that is, the exponential growth rates of the successive moments of $u$, and show that they display an interesting dependence on the dimension $d$ and on the parameters $\kappa,\gamma,\rho,\nu$, with qualitatively different intermittency behavior in $d=1,2$, in $d=3$ and in $d\geq4$. Special attention is given to the asymptotics of these Lyapunov exponents for $\kappa\downarrow0$ and $\kappa \to\infty$.Comment: Published at http://dx.doi.org/10.1214/009117906000000467 in the Annals of Probability (http://www.imstat.org/aop/) by the Institute of Mathematical Statistics (http://www.imstat.org

Stretched Exponential Relaxation in the Biased Random Voter Model

We study the relaxation properties of the voter model with i.i.d. random bias. We prove under mild condions that the disorder-averaged relaxation of this biased random voter model is faster than a stretched exponential with exponent $d/(d+\alpha)$, where $0<\alpha\le 2$ depends on the transition rates of the non-biased voter model. Under an additional assumption, we show that the above upper bound is optimal. The main ingredient of our proof is a result of Donsker and Varadhan (1979).Comment: 14 pages, AMS-LaTe

Torsional rigidity for cylinders with a Brownian fracture

We obtain bounds for the expected loss of torsional rigidity of a cylinder $\Omega_L=(-L/2,L/2) \times \Omega\subset \R^3$ of length $L$ due to a Brownian fracture that starts at a random point in $\Omega_L,$ and runs until the first time it exits $\Omega_L$. These bounds are expressed in terms of the geometry of the cross-section $\Omega \subset \R^2$. It is shown that if $\Omega$ is a disc with radius $R$, then in the limit as $L \rightarrow \infty$ the expected loss of torsional rigidity equals $cR^5$ for some $c\in (0,\infty)$. We derive bounds for $c$ in terms of the expected Newtonian capacity of the trace of a Brownian path that starts at the centre of a ball in $\R^3$ with radius $1,$ and runs until the first time it exits this ball.Comment: 18 page

Intermittency on catalysts

The present paper provides an overview of results obtained in four recent papers by the authors. These papers address the problem of intermittency for the Parabolic Anderson Model in a \emph{time-dependent random medium}, describing the evolution of a ``reactant'' in the presence of a ``catalyst''. Three examples of catalysts are considered: (1) independent simple random walks; (2) symmetric exclusion process; (3) symmetric voter model. The focus is on the annealed Lyapunov exponents, i.e., the exponential growth rates of the successive moments of the reactant. It turns out that these exponents exhibit an interesting dependence on the dimension and on the diffusion constant.Comment: 11 pages, invited paper to appear in a Festschrift in honour of Heinrich von Weizs\"acker, on the occasion of his 60th birthday, to be published by Cambridge University Pres

Intermittency on catalysts: three-dimensional simple symmetric exclusion

We continue our study of intermittency for the parabolic Anderson model $\partial u/\partial t = \kappa\Delta u + \xi u$ in a space-time random medium $\xi$, where $\kappa$ is a positive diffusion constant, $\Delta$ is the lattice Laplacian on $\Z^d$, $d \geq 1$, and $\xi$ is a simple symmetric exclusion process on $\Z^d$ in Bernoulli equilibrium. This model describes the evolution of a \emph{reactant} $u$ under the influence of a \emph{catalyst} $\xi$. In G\"artner, den Hollander and Maillard (2007) we investigated the behavior of the annealed Lyapunov exponents, i.e., the exponential growth rates as $t\to\infty$ of the successive moments of the solution $u$. This led to an almost complete picture of intermittency as a function of $d$ and $\kappa$. In the present paper we finish our study by focussing on the asymptotics of the Lyaponov exponents as $\kappa\to\infty$ in the \emph{critical} dimension $d=3$, which was left open in G\"artner, den Hollander and Maillard (2007) and which is the most challenging. We show that, interestingly, this asymptotics is characterized not only by a \emph{Green} term, as in $d\geq 4$, but also by a \emph{polaron} term. The presence of the latter implies intermittency of \emph{all} orders above a finite threshold for $\kappa$.Comment: 38 page