The Ozone Monitoring Instrument: Overview of 14 years in space

This overview paper highlights the successes of the Ozone Monitoring Instrument (OMI) on board the Aura satellite spanning a period of nearly 14 years. Data from OMI has been used in a wide range of applications and research resulting in many new findings. Due to its unprecedented spatial resolution, in combination with daily global coverage, OMI plays a unique role in measuring trace gases important for the ozone layer, air quality, and climate change. With the operational very fast delivery (VFD; direct readout) and near real-time (NRT) availability of the data, OMI also plays an important role in the development of operational services in the atmospheric chemistry domain

Satellite detection of volcanic ash from Eyjafjallajökull and the threat to aviation

Earth orbiting satellites provide an excellent means for monitoring and measuring emissions from volcanic eruptions. The recent eruption of Eyjafjallajökull in Iceland on 14 April, 2010 and the subsequent movement of the ash clouds were tracked using a variety of satellite instruments as they moved over Europe. Data from the rapid sampling (every 15 minutes) SEVIRI on Meteosat Second Generation were especially useful during this event as the thermal channels between 10–12 micron could be used to detect the ash signal and perform quantitative ash retrievals of mass loadings, optical depths and effective particle size. Higher-spatial resolution ( 1 km2) information from the MODIS sensors on NASA’s Terra and Aqua platforms were also analysed to determine ash microphysics and also to provide ash cloud top height. High-spectral resolution data from the IASI and AIRS sensors showed that initially quantities of ice, potentially with ash cores, were present, and that multi-species retrievals could be performed by exploiting the spectral content of the data. Vertically resolved ash layers were detected using the Caliop lidar on board the Calipso platform. Ash was clearly detected over Europe using the infra-red sensors with mass loadings typically in the range 0.1–5 gm-2, which for layers of 500–1000 m thickness, suggests ash concentrations in the range 0.1–10 mg m-3, and therefore represent a potential hazard to aviation.Little SO2 was detected at the start of the eruption, although both OMI and AIRS detected upper-level SO2 on 15 April. By late April and early May, 0.1–0.3 Tg (SO2) could be detected using these sensors. The wealth of satellite data available, some in near real-time, and the ability of infrared and ultra-violet sensors to detect volcanic ash and SO2 are emphasised in this presentation. The ash/aviation problem can be addressed using remote sensing measurements, validated with ground-based and air-borne, and combined with dispersion modelling. The volcanic ash threat to aviation can be ameliorated by utilising these space-based resources

Satellite detection of volcanic ash from Eyjafjallajökull and the threat to aviation

Earth orbiting satellites provide an excellent means for monitoring and measuring emissions from volcanic eruptions. The recent eruption of Eyjafjallajökull in Iceland on 14 April, 2010 and the subsequent movement of the ash clouds were tracked using a variety of satellite instruments as they moved over Europe. Data from the rapid sampling (every 15 minutes) SEVIRI on Meteosat Second Generation were especially useful during this event as the thermal channels between 10–12 micron could be used to detect the ash signal and perform quantitative ash retrievals of mass loadings, optical depths and effective particle size. Higher-spatial resolution ( 1 km2) information from the MODIS sensors on NASA’s Terra and Aqua platforms were also analysed to determine ash microphysics and also to provide ash cloud top height. High-spectral resolution data from the IASI and AIRS sensors showed that initially quantities of ice, potentially with ash cores, were present, and that multi-species retrievals could be performed by exploiting the spectral content of the data. Vertically resolved ash layers were detected using the Caliop lidar on board the Calipso platform. Ash was clearly detected over Europe using the infra-red sensors with mass loadings typically in the range 0.1–5 gm-2, which for layers of 500–1000 m thickness, suggests ash concentrations in the range 0.1–10 mg m-3, and therefore represent a potential hazard to aviation.Little SO2 was detected at the start of the eruption, although both OMI and AIRS detected upper-level SO2 on 15 April. By late April and early May, 0.1–0.3 Tg (SO2) could be detected using these sensors. The wealth of satellite data available, some in near real-time, and the ability of infrared and ultra-violet sensors to detect volcanic ash and SO2 are emphasised in this presentation. The ash/aviation problem can be addressed using remote sensing measurements, validated with ground-based and air-borne, and combined with dispersion modelling. The volcanic ash threat to aviation can be ameliorated by utilising these space-based resources

New insights into the magmatic-hydrothermal system and volatile budget of Lastarria volcano, Chile: Integrated results from the 2014 IAVCEI CCVG 12th Volcanic Gas Workshop.

Recent geophysical evidence for large-scale regional crustal inflation and localized crustal magma intrusion has made Lastarria volcano (northern Chile) the target of numerous geological, geophysical, and geochemical studies. The chemical composition of volcanic gases sampled during discrete campaigns from Lastarria volcano indicated a well-developed hydrothermal system from direct fumarole samples in A.D. 2006, 2008, and 2009, and shallow magma degassing using measurements from in situ plume sampling techniques in 2012. It is unclear if the differences in measured gas compositions and resulting interpretations were due to artifacts of the different sampling methods employed, short-term excursions from baseline due to localized changes in stress, or a systematic change in Lastarria's magmatic-hydrothermal system between 2009 and 2012. Integrated results from a two-day volcanic gas sampling and measurement campaign during the 2014 International Association of Volcanology and Chemistry of the Earth's Interior (IAVCEI) Commission on the Chemistry of Volcanic Gases (CCVG) 12th Gas Workshop are used here to compare and evaluate current gas sampling and measurement techniques, refine the existing subsurface models for Lastarria volcano, and provide new constraints on its magmatic-hydrothermal system and total degassing budget. While compositional differences among sampling methods are present, distinct compositional changes are observed, which if representative of longterm trends, indicate a change in Lastarria's overall magmatic-hydrothermal system. The composition of volcanic gases measured in 2014 contained high proportions of relatively magma- and water-soluble gases consistent with degassing of shallow magma, and in agreement with the 2012 gas composition. When compared with gas compositions measured in 2006-2009, higher relative H2O/CO2 ratios combined with lower relative CO2/St and H2O/St and stable HCl/St ratios (where St is total S [SO2 + H2S]) are observed in 2012 and 2014. These compositional changes suggest variations in the magmatic-hydrothermal system between 2009 and 2012, with possible scenarios to explain these trends including: (1) decompression-induced degassing due to magma ascent within the shallow crust; (2) crystallization-induced degassing of a stalled magma body; (3) depletion of the hydrothermal system due to heating, changes in local stress, and/or minimal precipitation; and/or (4) acidification of the hydrothermal system. These scenarios are evaluated and compared against the geophysical observations of continuous shallow inflation at ~8 km depth between 1997 and 2016, and near-surface ( < 1 km) inflation between 2000 and 2008, to further refine the existing subsurface models. Higher relative H2O/CO2 observed in 2012 and 2014 is not consistent with the depletion or acidification of a hydrothermal system, while all other observations are consistent with the four proposed models. Based on these observations, we find that scenarios 1 or 2 are the most likely to explain the geochemical and geophysical observations, and propose that targeted shallow interferometric synthetic-aperture radar (InSAR) studies could help discriminate between these two scenarios. Lastly, we use an average SO2 flux of 604 \ub1 296 t/d measured on 22 November 2014, along with the average gas composition and diffuse soil CO2 flux measurements, to estimate a total volatile flux from Lastarria volcano in 2014 of ~12,400 t/d, which is similar to previous estimates from 2012

Gas emissions from five volcanoes in northern Chile, and implications for the volatiles budget of the Central Volcanic Zone

This study performed the first assessment of the volcanic gas output from the Central Volcanic Zone (CVZ) of northern Chile. We present the fluxes and compositions of volcanic gases (H2O, CO2, H2, HCl, HF, and HBr) from five of the most actively degassing volcanoes in this region—Láscar, Lastarria, Putana, Ollagüe, and San Pedro—obtained during field campaigns in 2012 and 2013. The inferred gas plume compositions for Láscar and Lastarria (CO2/Stot = 0.9–2.2; Stot/HCl = 1.4–3.4) are similar to those obtained in the Southern Volcanic Zone of Chile, suggesting uniform magmatic gas fingerprint throughout the Chilean arc. Combining these compositions with our own UV spectroscopy measurements of the SO2 output (summing to ~1800 t d−1 for the CVZ), we calculate a cumulative CO2 output of 1743–1988 t d−1 and a total volatiles output of >20,200 t d−1

Validation of SO2 retrievals from the Ozone Monitoring Instrument (OMI) over NE China

The Ozone Monitoring Instrument (OMI) launched on the NASA Aura satellite in July 2004 offers unprecedented spatial resolution, coupled with contiguous daily global coverage, for space-based UV measurements of sulfur dioxide (SO2). We present a first validation of the OMI SO2 data with in-situ aircraft measurements in NE China in April 2005. The study demonstrates that OMI can distinguish between background SO2 conditions and heavy pollution on a daily basis. The noise (expressed as the standard deviation, σ) in the PBL SO2 data is ~1.5DU (Dobson Unit, 2.691016 molecules/cm2) for instantaneous field of view (IFOV) data. By looking at the pristine South Pacific under optimal conditions we have determined that temporal and spatial averaging can improve the resolution of the instrument to σ ~ 0.3 DU; the long term average over this remote location was within 0.1 DU of zero. Under polluted conditions, however, Collection 2 data are higher than aircraft measurements by a factor of two in most cases. Parameterization of the airmass factor (AMF) appears to enhance the accuracy of the SO2 data. Improved calibrations of the radiance and irradiance data (Collection 3) result in better agreement with aircraft measurements on polluted days. The re-processed and AMF-corrected Collection 3 data still show positive bias and sensitivity to UV absorbing aerosols. The difference between the in situ data and the OMI daily PBL SO2 measurements within 30 km of the aircraft profiles was about 1 DU, equivalent to ~5 ppb from 0 to 3000 m altitude. Quantifying the SO2 profile and spectral dependence of aerosol absorption between 310 and 330 nm are critical for accurate estimates of SO2 from satellite UV measurements

Sources of increase in lowermost stratospheric sulphurous and carbonaceous aerosol background concentrations during 1999–2008 derived from CARIBIC flights

This study focuses on sulphurous and carbonaceous aerosol, the major constituents of particulate matter in the lowermost stratosphere (LMS), based on in situ measurements from 1999 to 2008. Aerosol particles in the size range of 0.08–2 µm were collected monthly during intercontinental flights with the CARIBIC passenger aircraft, presenting the first long-term study on carbonaceous aerosol in the LMS. Elemental concentrations were derived via subsequent laboratory-based ion beam analysis. The stoichiometry indicates that the sulphurous fraction is sulphate, while an O/C ratio of 0.2 indicates that the carbonaceous aerosol is organic. The concentration of the carbonaceous component corresponded on average to approximately 25% of that of the sulphurous, and could not be explained by forest fires or biomass burning, since the average mass ratio of Fe to K was 16 times higher than typical ratios in effluents from biomass burning. The data reveal increasing concentrations of particulate sulphur and carbon with a doubling of particulate sulphur from 1999 to 2008 in the northern hemisphere LMS. Periods of elevated concentrations of particulate sulphur in the LMS are linked to downward transport of aerosol from higher altitudes, using ozone as a tracer for stratospheric air. Tropical volcanic eruptions penetrating the tropical tropopause are identified as the likely cause of the particulate sulphur and carbon increase in the LMS, where entrainment of lower tropospheric air into volcanic jets and plumes could be the cause of the carbon increase