28 research outputs found

    Evaluation of thermo-hydrological performance in support of the thermal loading systems study

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    Heat generated as a result of emplacing spent nuclear fuel will significantly affect the pre- and post-closure performance of the Mined Geological Disposal System (MGDS) at the potential repository site in Yucca Mountain. Understanding thermo-hydrological behavior under repository thermal loads is essential in (a) planning and conducting the site characterization and testing program, (b) designing the repository and engineered barrier system, and (c) assessing performance. The greatest concern for hydrological performance is source of water that would contact a waste package, accelerate its failure rate, and eventually transport radionuclides to the water table. The primary sources of liquid water are: (1) natural infiltration, (2) condensate generated under boiling conditions, and (3) condensate generated under sub-boiling conditions. Buoyant vapor flow, occurring either on a sub-repository scale or on a mountain scale, any affect the generation of the second and third sources of liquid water. A system of connected fractures facilitates repository-heat-driven gas and liquid flow as well as natural infiltration. With the use of repository-scale and sub-repository-scale models, the authors analyze thermo-hydrological behavior for Areal Mass Loadings (AMLs) of 24.2, 35.9, 55.3, 83.4, and 110.5 MTU/acre for a wide range of bulk permeability. They examine the temporal and spatial extent of the temperature and saturation changes during the first 100,000 yr. They also examine the sensitivity of mountain scale moisture redistribution to a range of AMLs and bulk permeabilities. In addition, they investigate how boiling and buoyant, gas-phase convection influence thermo-hydrological behavior in the vicinity of emplacement drifts containing spent nuclear fuel

    Aquifer thermal energy storage: An attempt to counter free thermal convection

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    This is the published version. Copyright 1983 American Geophysical UnionIn previous Aquifer Thermal Energy Storage (ATES) experiments, appreciable free thermal convection was observed. In an attempt to counter the detrimental effects of convection, a dual recovery well system was constructed at the Mobile site and a third injection-storage-recovery cycle performed. Using a partially penetrating well, cycle 3-3 injection began on April 7, 1982. A total of 56,680 m3 of 79°C water were injected. After 57 days of storage, production began with a dual recovery well system. Due to the dominating effect of nonhomogeneities, the dual well system did not work particularly well, and a recovery factor of 0.42 was achieved. The degree of aquifer heterogeneity at the location of the present experiments was not apparent during previous experiments at a location only 109 m away, although pumping tests indicated similar values of transmissivity. Therefore aquifers with the same transmissivity can behave quite differently in a thermal sense. Heat conduction to the upper aquitard was a major energy loss mechanism. Water sample analyses indicated that there were no important changes in the chemical constituents during the third set of experiments. There was a 19% increase in total dissolved solids. At the end of injection, the land surface near the injection well had risen 1.39 cm with respect to bench marks located 70 m away

    Infiltration of Sulfate to Enhance Sulfate Reduction of Petroleum Hydrocarbons

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    The lack of sufficient electron acceptors, particularly sulfate, can limit the rate of biodegradation of petroleum hydrocarbons (PHCs). Hence there is a growing interest by remediation practitioners to deliver sulfate to a PHC impacted saturated zone to enhance biodegradation. When shallow contamination is present in a relatively permeable aquifer and site constraints allow, a cost-effective approach is to apply sulfate on the ground surface. In this investigation a pilot-scale experiment was conducted to increase our understanding of the delivery of sulfate using a surface-based method and the resulting impact on a shallow PHC contaminated aquifer. A surficial infiltration pond positioned on the ground surface above a well-characterized residual PHC source zone was used to control sulfate dosing. A high-resolution network near the infiltration pond and downgradient of the source zone was employed to monitor relevant geochemical indicators and PHC concentrations. Compound specific isotope analysis (CSIA) was used to identify biodegradation patterns and to investigate the occurrence of microbial sulfate reduction. Selected metabolites and reverse-transcriptase quantitative polymerase chain reaction analyses of expressed biodegradation genes (as mRNA) were also used to characterize the response of indigenous microorganisms (especially sulfate reducing bacteria) to the added sulfate. Three sulfate application episodes (5000 L each) at various Na 2 SO 4 concentrations were allowed to infiltrate under a constant hydraulic head. Although the applied sulfate solution was impacted by density driven advection, detailed monitoring data indicated that the sulfate-enriched water mixed with up-gradient groundwater as it migrated downward through the residual PHC zone and formed a co-mingled downgradient plume with the dissolved PHC compounds. The enrichment of δ 34 S of sulfate in conjunction with a decrease in sulfate concentration showed the occurrence of sulfate reduction due to the applied sulfate. Increased dissolved inorganic carbon (DIC) concentrations associated with a shift toward more depleted values of δ 13 C of DIC was indicative of an input of isotopically depleted DIC from biodegradation of benzene, toluene and o-xylene (BTX). Despite fluctuations in the BTX concentrations, the CSIA data for BTX showed that these compounds were biodegraded. The biomarker data provided supporting evidence that toluene and o-xylene were undergoing anaerobic biodegradation due to sulfate reduction. This study provides insight into factors controlling surface-based delivery of sulfate to shallow PHC impacted groundwater systems, and the value of isotopic and molecular-biological procedures to augment conventional monitoring tools

    Integrated Plume Treatment Using Persulfate Coupled with Microbial Sulfate Reduction

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    The integration or sequential use of different remediation technologies, also referred to as a combined remedy, has become an emerging strategy for the treatment of contaminated sites. Coupling chemical oxidation using persulfate with enhanced bioremediation (EBR) under sulfate reducing conditions is a plausible combined remedy. To characterize the role of the mass removal processes (e.g., chemical oxidation vs. sulfate reduction) and to quantify the impact of persulfate on indigenous microbial processes in a combined persulfate/EBR treatment system, a pilot-scale field experiment was conducted in a 24-m long sheet pile-walled gate over a period of approximately 400d. After dissolved benzene, toluene, and o-xylene (BTX) quasi steady-state plumes were developed, two persulfate injection episodes were performed 10d apart to create a chemical oxidation (ChemOx) zone. High-resolution monitoring was conducted to observe the migration of the ChemOx zone and transition into an EBR zone. Mass loss estimates and geochemical indicators were used to identify the distinct transition between the ChemOx and enhanced biological reactive zones. Compound specific isotope analysis (CSIA) was used to distinguish the dominant mass removal process, and to investigate the occurrence of microbial sulfate reduction. BTX metabolites and reverse-transcriptase quantitative polymerase chain reaction analyses of expressed biodegradation genes (as mRNA) were also used to characterize the response of indigenous microorganisms (especially sulfate-reducing bacteria) to the added persulfate. Multiple lines of evidence supported the conclusion that chemical oxidation was the dominant mass removal process in the vicinity of the injection zone, while enhanced biodegradation dominated BTX degradation in the downgradient portions of the system. The CSIA and supporting molecular biological data were critical in documenting temporally and spatially distinctive zones in this system that were dominated by either chemical-oxidation or anaerobic-biodegradation processes. Initially, persulfate had an inhibitory impact on the activity of the indigenous microbial community, but this was followed by a substantial rebound of microbial activity to above baseline levels. The results from this investigation demonstrate that the suite of diagnostic tools employed can be used to distinguish between chemical oxidation using persulfate and the subsequent effects of the produced sulfate
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