Determination and Occurrence of Phenoxyacetic Acid Herbicides and Their Transformation Products in Groundwater Using Ultra High Performance Liquid Chromatography Coupled to Tandem Mass Spectrometry

This research is funded by the National Development Plan, through the Research Stimulus Fund, administered by the Department of Agriculture, Food and Marine (RS-544) and the Teagasc Walsh Fellowship Scheme.peer-reviewedA sensitive method was developed and validated for ten phenoxyacetic acid herbicides, six of their main transformation products (TPs) and two benzonitrile TPs in groundwater. The parent compounds mecoprop, mecoprop-p, 2,4-D, dicamba, MCPA, triclopyr, fluroxypr, bromoxynil, bentazone, and 2,3,6-trichlorobenzoic acid (TBA) are included and a selection of their main TPs: phenoxyacetic acid (PAC), 2,4,5-trichloro-phenol (TCP), 4-chloro-2-methylphenol (4C2MP), 2,4-dichlorophenol (DCP), 3,5,6-trichloro-2-pyridinol (T2P), and 3,5-dibromo-4-hydroxybenzoic acid (BrAC), as well as the dichlobenil TPs 2,6-dichlorobenzamide (BAM) and 3,5-dichlorobenzoic acid (DBA) which have never before been determined in Irish groundwater. Water samples were analysed using an efficient ultra-high performance liquid chromatography (UHPLC) method in an 11.9 min separation time prior to detection by tandem mass spectrometry (MS/MS). The limit of detection (LOD) of the method ranged between 0.00008 and 0.0047 µg·L−1 for the 18 analytes. All compounds could be detected below the permitted limits of 0.1 µg·L−1 allowed in the European Union (EU) drinking water legislation [1]. The method was validated according to EU protocols laid out in SANCO/10232/2006 with recoveries ranging between 71% and 118% at the spiked concentration level of 0.06 µg·L−1. The method was successfully applied to 42 groundwater samples collected across several locations in Ireland in March 2012 to reveal that the TPs PAC and 4C2MP were detected just as often as their parent active ingredients (a.i.) in groundwater

Doctrina perpetua: brokering change, promoting innovation and transforming marginalisation in university learning and teaching [Editors introduction]

Doctrina perpetua—translated variously as “forever learning” (Cryle, 1992, p. 27), “lifelong learning” and “lifelong education”—is the Latin motto of Central Queensland University (CQU), an Australian regional university with campuses in Central Queensland and the metropolitan and provincial cities of Brisbane, the Gold Coast, Melbourne and Sydney and with centres in China, Fiji, Hong Kong and Singapore. During its early development the institution was small and regional; in many ways it was an institution at the margins of higher education. For only a third of its 40-year life has it been recognised as a university. However, the vision of both its founders and its continuing staff has been that of an institution that actively brokers change, promotes innovation and seeks to transform marginalisation— for students, for its community and for itself. Its short life on the edge of the universe of higher education has promoted a culture of innovation and an acceptance that change is a necessary and positive aspect of life on the edge. Embracing change, CQU has become a complex institution, a notion well expressed in a speech in August 1999 by former Vice-Chancellor Lauchlan Chipman on Visioning Our Future: I have often remarked that I do not see CQU as “the last university of the old millennium” but rather as “the first university of the new millennium”. One of our greatest strengths in making the transition is our relative immaturity as a university. The more mature a university, especially if it is successful, the less agile it is when it comes to the need to change. So far as the future of universities and change is concerned, my position is unequivocally Heraclitean: change is the only thing that is permanent. Applying to itself the motto “doctrina perpetua” over its short life, the agile University has become a “complex and diverse organisation” (Danaher, Harreveld, Luck & Nouwens, 2004, p. 13). This overview of CQU seeks to provide readers with a short description of the current state of the institution and the story of its development to provide a context for understanding the chapters that follow, and to assist readers to reflect on how these developments at CQU relate to higher education generally, and to the universities with which they are more familiar

Programming with Exceptions in JCilk

JCilk extends the Java language to provide call-return semantics for multithreading, much as Cilk does for C. Java's built-in thread model does not support the passing of exceptions or return values from one thread back to the "parent" thread that created it. JCilk imports Cilk's fork-join primitives spawn and sync into Java to provide procedure-call semantics for concurrent subcomputations. This paper shows how JCilk integrates exception handling with multithreading by defining semantics consistent with the existing semantics of Java's try and catch constructs, but which handle concurrency in spawned methods. JCilk's strategy of integrating multithreading with Java's exception semantics yields some surprising semantic synergies. In particular, JCilk extends Java's exception semantics to allow exceptions to be passed from a spawned method to its parent in a natural way that obviates the need for Cilk's inlet and abort constructs. This extension is "faithful" in that it obeys Java's ordinary serial semantics when executed on a single processor. When executed in parallel, however, an exception thrown by a JCilk computation signals its sibling computations to abort, which yields a clean semantics in which only a single exception from the enclosing try block is handled. The decision to implicitly abort side computations opens a Pandora's box of subsidiary linguistic problems to be resolved, however. For instance, aborting might cause a computation to be interrupted asynchronously, causing havoc in programmer understanding of code behavior. To minimize the complexity of reasoning about aborts, JCilk signals them "semisynchronously" so that abort signals do not interrupt ordinary serial code. In addition, JCilk propagates an abort signal throughout a subcomputation naturally with a built-in CilkAbort exception, thereby allowing programmers to handle clean-up by simply catching the CilkAbort exception. The semantics of JCilk allow programs with speculative computations to be programmed easily. Speculation is essential for parallelizing programs such as branch-and-bound or heuristic search. We show how JCilk's linguistic mechanisms can be used to program a solution to the "queens" problem and an implemention of a parallel alpha-beta search.Singapore-MIT Alliance (SMA

Doctrina perpetua: an initiative to enhance teaching and learning at Central Queensland University

• Proposal for an edited book about evidence and research - based teaching and learning at CQU, with implications for other universities in Australia and overseas. • Proposed publisher is Post Pressed (http://www.postpressed.com.au). • Hopefully to go to press in December 2005

Naturally occurring bisphenol F in plants used in traditional medicine

n/

Contesting ‘transitions’ and (re-)engaging with ‘subjectivities’: locating and celebrating the habitus in three versions of ‘the first year experience’ at Central Queensland University

Instead of the homogeneous and undifferentiated view of ‘the first year experience’ implied by the term ‘transitions’, we prefer to emphasise diversity and heterogeneity in mapping multiple experiences of university life, particularly in ‘the first year’. This mapping includes – in the context of Central Queensland University (CQU) – students in a pre-undergraduate preparatory program with rich life experiences but limited formal education; school leavers and mature age students in a first year undergraduate program; and students with industry and professional experience in a pre-service teacher education program with both undergraduate and graduate entry points. Despite the considerable differences among these ‘first year experiences’, they have in common a focus on the habitus (Bourdieu, 1977, 1990) as a framework for locating and celebrating student and staff subjectivities and hence for maximising student (re-)engagements with university life. The paper illustrates these crucial processes in each of these versions of ‘the first year experience’

Fate of eprinomectin in goat milk and cheeses with different ripening times following pour-on administration

The distribution of eprinomectin in goat milk and cheeses (cacioricotta, caciotta, caprilisco) with different ripening times following a pour-on administration at a single dose rate (500 microg/kg of body weight) and a double dose rate (1,000 microg/kg of body weight) to goats with naturally occurring infections of gastrointestinal nematodes was studied. Milk residues of eprinomectin reached a maximum of 0.55+/-0.18 microg/kg and 1.70+/-0.31 microg/kg at the single and double doses, respectively. The drug concentrations decreased progressively until the fifth day after treatment, when they were less than the detection limit at both dose rates. The eprinomectin levels measured in all cheese types (both treatments) were higher than those recovered in milk at all the sampling times. In caciotta cheeses, the eprinomectin residues levels were constantly higher than other cheeses. With the exception of cheeses made with milk the first day after treatment, eprinomectin concentrations were nearly constant up to the fourth day then decreased by the fifth and sixth days after treatment. In all cases, at both the single and double dosages, the maximum level of eprinomectin residues in goat milk and cheeses remained below the maximum residual level of 20 microg/liter permitted for lactating cattle

Futuring sustainable Australian teacher education through recent doctoral dissertations: a thematic analysis of alternative scenarios

Envisioning and enacting teacher education for sustainable futures require simultaneous attention to multiple influences and imperatives. One among several possible approaches to this task is to draw on alternative scenarios as recommended by futures researchers, thereby suggesting several different possible visions of teacher education and considering their likely impact on current policy-making and practice. This paper deploys scenarios of potential higher education futures in the United Kingdom (Blass, Jasman, & Shelley, 2010, in press) as a framework for addressing this research question: Which challenges and opportunities might shape the sustainability of Australian teacher education? In particular, the framework is employed to examine six recent doctoral dissertations supervised by the authors and dealing explicitly or implicitly with teacher education research issues, ranging from visual literacy and visual signifiers to students with learning difficulties and teaching for social justice. A thematic analysis elicits several opportunities and challenges attending the sustainability options for Australian teacher education generated by Blass et al.’s (2010, in press) scenarios. The paper presents the thematic analysis findings by clustering the opportunities and challenges around three key elements of contemporary theorising of sustainability: contexts, connections and capabilities (Holland, 2008; Lanzi, 2007). These elements are posited as robust conceptual resources for highlighting and interrogating sustainability options across multiple domains of educational experience and activity. They are also proposed as vital ingredients in the ongoing re-evaluation of Australian teacher education designed to ensure its sustainable futures and to maximise its effectiveness and relevance

Sex doll ownership: an agenda for research

Purpose of review: The topic of sex doll ownership is becoming an increasingly discussed issue from both a social and legal perspective. This review aims to examine the veracity of the existing psychological, sexological, and legal literature in relation to doll ownership. Recent findings: Strong views exist across the spectrum of potential socio-legal positions on sex doll ownership. However, there is an almost total lack of empirical analyses of the psychological characteristics or behavioral implications of doll ownership. As such, existing arguments appear to represent the philosophical positions of those scholars expressing them, rather than being rooted in any objective evidence base. Summary: Despite an absence of empirical data on the characteristics and subsequent effects of doll ownership, discussions about the ethical and legal status of doll ownership continue. This highlights a real and urgent need for a coherent research agenda to be advanced in this area of work