980 research outputs found
Stimulated Raman Adiabatic Passage (STIRAP) as a Route to Achieving Optical Control in Plasmonics
Optical properties of ensembles of three-level quantum emitters coupled to
plasmonic systems are investigated employing a self-consistent model. It is
shown that stimulated Raman adiabatic passage (STIRAP) technique can be
successfully adopted to control optical properties of hybrid materials with
collective effects present and playing an important role in light-matter
interactions. We consider a core-shell nanowire comprised of a silver core and
a shell of coupled quantum emitters and utilize STIRAP scheme to control
scattering efficiency of such a system in a frequency and spatial dependent
manner. After the STIRAP induced population transfer to the final state takes
place, the core-shell nanowire exhibits two sets of Rabi splittings with Fano
lineshapes indicating strong interactions between two different atomic
transitions driven by plasmon near-fields.Comment: 11 pages, 6 figures, accepted, Physical Review
On the Experimental Estimation of Surface Enhanced Raman Scattering (SERS) Cross Sections by Vibrational Pumping
We present an in-depth analysis of the experimental estimation of cross
sections in Surface Enhanced Raman Scattering (SERS) by vibrational pumping.
The paper highlights the advantages and disadvantages of the technique,
pinpoints the main aspects and limitations, and provides the underlying
physical concepts to interpret the experimental results. Examples for several
commonly used SERS probes are given, and a discussion on future possible
developments is also presented.Comment: To be submitted to J. Phys. Chem.
Enhancement factor distribution around a single SERS Hot-spot and its relation to Single Molecule detection
We provide the theoretical framework to understand the phenomenology and
statistics of single-molecule (SM) signals arising in Surface-Enhanced Raman
Scattering (SERS) under the presence of so-called electromagnetic hot-spots
(HS's). We show that most characteristics of the SM-SERS phenomenon can be
tracked down to the presence of tail-like (power law) distribution of
enhancements and we propose a specific model for it. We analyze, in the light
of this, the phenomenology of SM-SERS and show how the different experimental
manifestations of the effect reported in the literature can be analyzed and
understood under a unified ``universal'' framework with a minimum set of
parameters.Comment: 13 pages, 4 figures, submitted to J. Chem. Phy
Surface plasmon lifetime in metal nanoshells
The lifetime of localized surface plasmon plays an important role in many
aspects of plasmonics and its applications. In small metal nanostructures, the
dominant mechanism restricting plasmon lifetime is size-dependent Landau
damping. We performed quantum-mechanical calculations of Landau damping for the
bright surface plasmon mode in a metal nanoshell. In contrast to the
conventional model based on the electron surface scattering, we found that the
damping rate decreases as the nanoshell thickness is reduced. The origin of
this behavior is traced to the spatial distribution of plasmon local field
inside the metal shell. We also found that, due to interference of electron
scattering amplitudes from nanoshell's two metal surfaces, the damping rate
exhibits pronounced quantum beats with changing shell thickness.Comment: 9 pages, 4 Figure
- …