Renormalisation-theoretic analysis of non-equilibrium phase transitions II: The effect of perturbations on rate coefficients in the Becker-Doring equations

We study in detail the application of renormalisation theory to models of cluster aggregation and fragmentation of relevance to nucleation and growth processes. In particular, we investigate the Becker-Doring (BD) equations, originally formulated to describe and analyse non-equilibrium phase transitions, but more recently generalised to describe a wide range of physicochemical problems. We consider here rate coefficients which depend on the cluster size in a power-law fashion, but now perturbed by small amplitude random noise. Power-law rate coefficients arise naturally in the theory of surface-controlled nucleation and growth processes. The noisy perturbations on these rates reflect the effect of microscopic variations in such mean-field coefficients, thermal fluctuations and/or experimental uncertainties. In the present paper we generalise our earlier work that identified the nine classes into which all dynamical behaviour must fall by investigating how random perturbations of the rate coefficients influence the steady-state and kinetic behaviour of the coarse-grained, renormalised system. We are hence able to confirm the existence of a set of up to nine universality classes for such BD systems.Comment: 30 pages, to appear in J Phys A Math Ge

Fluctuation-driven insulator-to-metal transition in an external magnetic field

We consider a model for a metal-insulator transition of correlated electrons in an external magnetic field. We find a broad region in interaction and magnetic field where metallic and insulating (fully magnetized) solutions coexist and the system undergoes a first-order metal-insulator transition. A global instability of the magnetically saturated solution precedes the local ones and is caused by collective fluctuations due to poles in electron-hole vertex functions.Comment: REVTeX 4 pages, 3 PS figure

Orbital-selective Mott transitions in the anisotropic two-band Hubbard model at finite temperatures

The anisotropic degenerate two-orbital Hubbard model is studied within dynamical mean-field theory at low temperatures. High-precision calculations on the basis of a refined quantum Monte Carlo (QMC) method reveal that two distinct orbital-selective Mott transitions occur for a bandwidth ratio of 2 even in the absence of spin-flip contributions to the Hund exchange. The second transition -- not seen in earlier studies using QMC, iterative perturbation theory, and exact diagonalization -- is clearly exposed in a low-frequency analysis of the self-energy and in local spectra.Comment: 4 pages, 5 figure

Renormalisation-theoretic analysis of non-equilibrium phase transitions I: The Becker-Doring equations with power law rate coefficients

We study in detail the application of renormalisation theory to models of cluster aggregation and fragmentation of relevance to nucleation and growth processes. We investigate the Becker-Dorging equations, originally formulated to describe and analyse non-equilibrium phase transitions, and more recently generalised to describe a wide range of physicochemical problems. In the present paper we analyse how the systematic coarse-graining renormalisation of the \BD system of equations affects the aggregation and fragmentation rate coefficients. We consider the case of power-law size-dependent cluster rate coefficients which we show lead to only three classes of system that require analysis: coagulation-dominated systems, fragmentation-dominated systems and those where coagulation and fragmentation are exactly balanced. We analyse the late-time asymptotics associated with each class.Comment: 18 pages, to appear in J Phys A Math Ge

Dynamic Scaling in One-Dimensional Cluster-Cluster Aggregation

We study the dynamic scaling properties of an aggregation model in which particles obey both diffusive and driven ballistic dynamics. The diffusion constant and the velocity of a cluster of size $s$ follow $D(s) \sim s^\gamma$ and $v(s) \sim s^\delta$, respectively. We determine the dynamic exponent and the phase diagram for the asymptotic aggregation behavior in one dimension in the presence of mixed dynamics. The asymptotic dynamics is dominated by the process that has the largest dynamic exponent with a crossover that is located at $\delta = \gamma - 1$. The cluster size distributions scale similarly in all cases but the scaling function depends continuously on $\gamma$ and $\delta$. For the purely diffusive case the scaling function has a transition from exponential to algebraic behavior at small argument values as $\gamma$ changes sign whereas in the drift dominated case the scaling function decays always exponentially.Comment: 6 pages, 6 figures, RevTeX, submitted to Phys. Rev.

Metal--Insulator Transitions in the Falicov--Kimball Model with Disorder

The ground state phase diagrams of the Falicov--Kimball model with local disorder is derived within the dynamical mean--field theory and using the geometrically averaged (''typical'') local density of states. Correlated metal, Mott insulator and Anderson insulator phases are identified. The metal--insulator transitions are found to be continuous. The interaction and disorder compete with each other stabilizing the metallic phase against occurring one of the insulators. The Mott and Anderson insulators are found to be continuously connected.Comment: 6 pages, 7 figure

Temperature dependence of antiferromagnetic order in the Hubbard model

We suggest a method for an approximative solution of the two dimensional Hubbard model close to half filling. It is based on partial bosonisation, supplemented by an investigation of the functional renormalisation group flow. The inclusion of both the fermionic and bosonic fluctuations leads in lowest order to agreement with the Hartree-Fock result or Schwinger-Dyson equation and cures the ambiguity of mean field theory . We compute the temperature dependence of the antiferromagnetic order parameter and the gap below the critical temperature. We argue that the Mermin-Wagner theorem is not practically applicable for the spontaneous breaking of the continuous spin symmetry in the antiferromagnetic state of the Hubbard model. The long distance behavior close to and below the critical temperature is governed by the renormalisation flow for the effective interactions of composite Goldstone bosons and deviates strongly from the Hartree-Fock result.Comment: New section on critical behavior 31 pages,17 figure

Effect of Particle-Hole Asymmetry on the Mott-Hubbard Metal-Insulator Transition

The Mott-Hubbard metal-insulator transition is one of the most important problems in correlated electron systems. In the past decade, much progress has been made on examining a particle-hole symmetric form of the transition in the Hubbard model with dynamical mean field theory where it was found that the electronic self energy develops a pole at the transition. We examine the particle-hole asymmetric metal-insulator transition in the Falicov-Kimball model, and find that a number of features change when the noninteracting density of states has a finite bandwidth. Since, generically particle-hole symmetry is broken in real materials, our results have an impact on understanding the metal-insulator transition in real materials.Comment: 5 pages, 3 figure

Phase Diagram of One-Dimensional Extended Hubbard Model at Half Filling

We reexamine the ground-state phase diagram of the one-dimensional half-filled Hubbard model with on-site and nearest-neighbor repulsive interactions. We calculate second-order corrections to coupling constants in the g-ology to show that the bond-charge-density-wave (BCDW) phase exists for weak couplings in between the charge density wave (CDW) and spin density wave (SDW) phases. We find that the umklapp scattering of parallel-spin electrons destabilizes the BCDW state and gives rise to a bicritical point where the CDW-BCDW and SDW-BCDW continuous-transition lines merge into the CDW-SDW first-order transition line.Comment: 4 pages, 3 figure

Magnetic phase diagram of the Hubbard model

The competition between commensurate and incommensurate spin-density-wave phases in the infinite-dimensional single-band Hubbard model is examined with quantum Monte Carlo simulation and strong and weak coupling approximations. Quantum fluctuations modify the weak-coupling phase diagram by factors of order unity and produce remarkable agreement with the quantum Monte Carlo data, but strong-coupling theories (that map onto effective Falicov-Kimball models) display pathological behavior. The single-band model can be used to describe much of the experimental data in Cr and its dilute alloys with V and Mn.Comment: 12 pages plus 3 uuencoded postscript figures, ReVTe