Supporting Information.doc

<div>Supporting Information for "Zero-valent iron (ZVI) activation of persulfate (PS) for degradation of Para-chloronitrobenzene in soil"</div><div><br></div

Assessment of EDTA heap leaching of an agricultural soil highly contaminated with heavy metals

The efficiency of heavy metal removal from soil by EDTA leaching was assessed in a column leaching experiment at the laboratory scale and field heap leaching at the pilot scale using a sandy loam sierozem agricultural soil contaminated with Cd, Cu, Pb, and Zn. Soil amendment and aging were conducted to recover leaching soils. The percentages of Cd, Cu, Pb, and Zn removed by column leaching were 90%, 88%, 90%, and 67%, respectively, when 3.9 bed volumes of 50 mM EDTA were used. At the pilot scale, on-site metal removal efficiencies using the selected leaching procedure were 80%, 69%, 73% and 62% for Cd, Cu, Pb and Zn, respectively. EDTA leaching decreased soil CEC, total P, total K and available K concentrations but increased organic matter and total Kjeldahl N concentrations. The subsequent amendment and soil aging further reduced the DTPA-extractable heavy metals in the leached soils. Growth of the first crop of pak choi in the leached soil was inhibited but the second crop grew well after the soil was aged for one year and the concentrations of Cd and Pb in the edible parts were below the Chinese statutory limits. The results demonstrate the potential feasibility of the field leaching technique using EDTA combined with subsequent amendment and soil aging for the remediation of heavy metal-contaminated agricultural soils. (C) 2014 Elsevier Ltd. All rights reserved.The efficiency of heavy metal removal from soil by EDTA leaching was assessed in a column leaching experiment at the laboratory scale and field heap leaching at the pilot scale using a sandy loam sierozem agricultural soil contaminated with Cd, Cu, Pb, and Zn. Soil amendment and aging were conducted to recover leaching soils. The percentages of Cd, Cu, Pb, and Zn removed by column leaching were 90%, 88%, 90%, and 67%, respectively, when 3.9 bed volumes of 50 mM EDTA were used. At the pilot scale, on-site metal removal efficiencies using the selected leaching procedure were 80%, 69%, 73% and 62% for Cd, Cu, Pb and Zn, respectively. EDTA leaching decreased soil CEC, total P, total K and available K concentrations but increased organic matter and total Kjeldahl N concentrations. The subsequent amendment and soil aging further reduced the DTPA-extractable heavy metals in the leached soils. Growth of the first crop of pak choi in the leached soil was inhibited but the second crop grew well after the soil was aged for one year and the concentrations of Cd and Pb in the edible parts were below the Chinese statutory limits. The results demonstrate the potential feasibility of the field leaching technique using EDTA combined with subsequent amendment and soil aging for the remediation of heavy metal-contaminated agricultural soils. (C) 2014 Elsevier Ltd. All rights reserved