Growing LaAlO3/SrTiO3 interfaces by sputter deposition

Sputter deposition of oxide materials in a high-pressure oxygen atmosphere is a well-known technique to produce thin films of perovskite oxides in particular. Also interfaces can be fabricated, which we demonstrated recently by growing LaAlO3 on SrTiO3 substrates and showing that the interface showed the same high degree of epitaxy and atomic order as is made by pulsed laser deposition. However, the high pressure sputtering of oxides is not trivial and number of parameters are needed to be optimized for epitaxial growth. Here we elaborate on the earlier work to show that only a relatively small parameter window exists with respect to oxygen pressure, growth temperature, radiofrequency power supply and target to substrate distance. In particular the sensitivity to oxygen pressure makes it more difficult to vary the oxygen stoichiometry at the interface, yielding it insulating rather than conducting

A triclinic polymorph of N-[4-(4-methyl­benzene­sulfonamido)­phenyl­sulfon­yl]acetamide

In the asymmetric unit of the title compound, C15H16N2O5S2, there are two symmetry-independent mol­ecules which adopt similar conformations, with dihedral angles between the aromatic rings of 59.30 (8) and 61.81 (8)°, and dihedral angles between acetamide group and the benzene ring of 77.08 (10) and 78.40 (10)°. Each type of mol­ecule forms similar one-dimensional polymeric structures extending along the b axis via N—H⋯O hydrogen bonds. These hydrogen bonds generate two types of centrosymmetric motifs, R 2 2(8) and R 2 2(20). Moreover C—H⋯O inter­actions assemble the mol­ecules into a three-dimensional framework. The crystal structure was determined from a non-merohedral twin [ratio of the twin components = 0.322 (4):0.678 (4)]

A Cross-sectional Study of Clinical Characteristics and Outcomes among Adults with Laboratory-confirmed SARS-CoV-2 Infection with Omicron Variant

The emergence of the SARS-CoV-2 Omicron variant has raised concerns due to its increased transmissibility and potential implications on clinical characteristics and outcomes in infected individuals. The aims of this report were to study the profile of SARS-CoV-2 infection with omicron variant, investigate the infection outcome, reinfection rates with associated factors, antibody levels, and explore the associations between biochemical markers and disease severity. This prospective cohort study was conducted in Duhok city in the Northern of Iraq. All volunteers with confirmed SARS-CoV-2 RT–PCR and confirmed Omicron infection who were older than 18 years old and agreed to participate were recruited for this study. The study was carried out from January to April 2022. There were 234 cases of confirmed SARS-CoV-2 RT–PCR Omicron infection. The mean age was 48.12±17.3 years, 43.2% were vaccinated, and 40.2% were male. Among the recruited patients, 99.1% recovered and did not need hospitalization. In this study, (38.9%) had a history of previously confirmed COVID-19 infection. Reinfection was significantly higher in females than males (p=0.04; OR= 0.56). It was found that the IgG antibody levels were higher in patients who received Pfizer-BioNTech than in those who received other vaccines (p=0.001). The levels of IgG were also significantly higher in patients with mild infection (p=0.046), whereas the levels of D-dimer were significantly higher in patients with severe cases of the infection compared to those with mild or moderate cases (p=0.001). Additionally, the levels of C-reactive protein (CRP) were observed to be higher in individuals with moderate cases of infection than in mild and severe cases (0.001). Individuals who contracted the Omicron strain generally had positive outcomes. Reinfection with the Omicron variant was relatively high. IgG levels were higher in patients with mild disease, implying that they were associated with decreased disease severity. We found significant associations between D-dimer levels and the severity of the disease. Additional research is required to investigate the long-term effects of Omicron infection

Magnetic rotating flow of a hybrid nano-materials Ag-MoS2 and Go-MoS2 in C2H6O2-H2O hybrid base fluid over an extending surface involving activation energy : FE simulation

Numeric simulations are performed for a comparative study of magnetohydrodynamic (MHD) rotational flow of hybrid nanofluids (MoS2-Ag/ethyleneglycol-water (50–50%) and MoS2-Go/ethyleneglycol-water (50–50%)) over a horizontally elongated plane sheet. The principal objective is concerned with the enhancement of thermal transportation. The three-dimensional formulation governing the conservation of mass, momentum, energy, and concentration is transmuted into two-dimensional partial differentiation by employing similarity transforms. The resulting set of equations (PDEs) is then solved by variational finite element procedure coded in Matlab script. An intensive computational run is carried out for suitable ranges of the particular quantities of influence. The primary velocity component decreases monotonically and the magnitude of secondary velocity component diminishes significantly when magnetic parameter, rotational parameter, and unsteadiness parameter are incremented. Both the primary and secondary velocities are smaller in values for the hybrid phase Ag-MoS2 than that of hybrid phase Go-MoS2 but the nanoparticle concentration and temperature are higher for hybrid phase Ag-MoS2. The increased values of parameters for thermophoresis, Brownian motion, shape factor, and volume fraction of ϕ2 made significant improvement in the temperature of the two phases of nano liquids. Results are also computed for the coefficients of skin friction(x, y-directions), Nusselt number, and Sherwood number. The present findings manifest reasonable comparison to their existing counterparts. Some of the practical engineering applications of the present analysis may be found in high-temperature nanomaterial processing technology, crystal growing, extrusion processes, manufacturing and rolling of polymer sheets, academic research, lubrication processes, and polymer industry.Published versio

Antileishmanial, Antimicrobial and Antifungal Activities of Some New Aryl Azomethines

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