Preparation, Characterization and NO-CO Redox Reaction Studies over Palladium and Rhodium Oxides Supported on Manganese Dioxide

The catalytic activity of PdO/MnO2 and Rh2O3/MnO2 is investigated for NO-CO redox reaction. Supported catalysts are prepared by wet impregnation method. Among the tested catalysts, PdO/MnO2 shows higher activity for this reaction. Active metal dispersion on MnO2 enhances the selectivity for N2 over N2O in this reaction. The XRD substantiate the formation of MnO2 monophasic phase. SEM images show the formation of elongated particles. TEM images indicate nano-size rod-like morphologies. An increase in the catalytic activity is observed on supported Pd and Rh oxides on MnO2. Temperature programed desorption studies with NO and CO are undertaken to investigate the catalytic surface studies. © 2015 BCREC UNDIP. All rights reserve

Microscale application of column theory for high resolution force and displacement sensing

We present the design, fabrication and experimental validation of a novel device that exploits the amplification of displacement and attenuation of structural stiffness in the post-buckling deformation of slender columns to obtain pico-Newton force and nanometer displacement resolution even under an optical microscope. The extremely small size, purely mechanical sensing scheme and vacuum compatibility of the instrument makes it compatible with existing visualization tools of nanotechnology. The instrument has a wide variety of potential applications ranging from electro-mechanical characterization of one dimensional solids to single biological cells

Quantifying the effects of harvesting on carbon fluxes and stocks in northern temperate forests

Harvest disturbance has substantial impacts on forest carbon (C) fluxes and stocks. The quantification of these effects is essential for the better understanding of forest C dynamics and informing forest management in the context of global change. We used a process-based forest ecosystem model, PnET-CN, to evaluate how, and by what mechanisms, clear-cuts alter ecosystem C fluxes, aboveground C stocks (AGC), and leaf area index (LAI) in northern temperate forests. We compared C fluxes and stocks predicted by the model and observed at two chronosequences of eddy covariance flux sites for deciduous broadleaf forests (DBF) and evergreen needleleaf forests (ENF) in the Upper Midwest region of northern Wisconsin and Michigan, USA. The average normalized root mean square error (NRMSE) and the Willmott index of agreement (d) for carbon fluxes, LAI, and AGC in the two chronosequences were 20% and 0.90, respectively. Simulated gross primary productivity (GPP) increased with stand age, reaching a maximum (1200–1500 g C m−2 yr−1) at 11–30 years of age, and leveled off thereafter (900–1000 g C m−2 yr−1). Simulated ecosystem respiration (ER) for both plant functional types (PFTs) was initially as high as 700–1000 g C m−2 yr−1 in the first or second year after harvesting, decreased with age (400–800 g C m−2 yr−1) before canopy closure at 10–25 years of age, and increased to 800–900 g C m−2 yr−1 with stand development after canopy recovery. Simulated net ecosystem productivity (NEP) for both PFTs was initially negative, with net C losses of 400–700 g C m−2 yr−1 for 6–17 years after clear-cuts, reaching peak values of 400–600 g C m−2 yr−1 at 14–29 years of age, and eventually stabilizing in mature forests (\u3e 60 years old), with a weak C sink (100–200 g C m−2 yr−1). The decline of NEP with age was caused by the relative flattening of GPP and gradual increase of ER. ENF recovered more slowly from a net C source to a net sink, and lost more C than DBF. This suggests that in general ENF may be slower to recover to full C assimilation capacity after stand-replacing harvests, arising from the slower development of photosynthesis with stand age. Our model results indicated that increased harvesting intensity would delay the recovery of NEP after clear-cuts, but this had little effect on C dynamics during late succession. Future modeling studies of disturbance effects will benefit from the incorporation of forest population dynamics (e.g., regeneration and mortality) and relationships between age-related model parameters and state variables (e.g., LAI) into the model

Diffuse gamma-ray background and cosmic-ray positrons from annihilating dark matter

We study the annihilating dark matter contribution to the extra-galactic diffuse gamma-ray background spectrum, motivated by the recent observations of cosmic-ray positron/electron anomalies. The observed diffuse gamma-ray flux provides stringent constraint on dark matter models and we present upper bounds on the annihilation cross section of the dark matter. It is found that for the case of cored dark matter halo profile, the diffuse gamma-rays give more stringent bound compared with gamma-rays from the Galactic center. The Fermi satellite will make the bound stronger.Comment: 20 pages, 11 figures; references added; to appear in PR

A γ\gamma-ray determination of the Universe's star-formation history

The light emitted by all galaxies over the history of the Universe produces the extragalactic background light (EBL) at ultraviolet, optical, and infrared wavelengths. The EBL is a source of opacity for $\gamma$ rays via photon-photon interactions, leaving an imprint in the spectra of distant $\gamma$-ray sources. We measure this attenuation using {739} active galaxies and one gamma-ray burst detected by the {\it Fermi} Large Area Telescope. This allows us to reconstruct the evolution of the EBL and determine the star-formation history of the Universe over 90\% of cosmic time. Our star-formation history is consistent with independent measurements from galaxy surveys, peaking at redshift $z\sim2$. Upper limits of the EBL at the epoch of re-ionization suggest a turnover in the abundance of faint galaxies at $z\sim 6$.Comment: Published on Science. This is the authors' version of the manuscrip

GIS-based Earthquake Disaster Management A case study for Solapur city (Maharashtra, India)

This paper aims to demonstrate a Geographic Information System (GIS)-based study on development of City Disaster Management System for earthquake for Solapur city (India).An approach has been designed to explore the scope for the combination of Disaster Management and GIS. The disaster-prone areas have been identified and their positions are marked using ArcView 9.1. GIS has been exploited to obtain the spatial information for the effective disaster management for earthquake-affected areas. ArcView 9.1 has been used as a tool for storing all types of relevant data for analysis and decision making. The various thematic maps include road network map, drinking water sources map, land use map, population density map, ward boundaries and location of slums. The paper proposes development of a GIS-based early response system, and an emergency preparedness plan for the Solapur city and also analysis of the impact of earthquake disasters in the region and its relationship to infrastructure development with a view to identifying how local governing bodies could be helped in addressing these issues. The proposed GIS-based flood mitigation and management program would improve the current practices of disaster management process. If implemented properly, it would result in proper and quick decisions for the rescue and safetyof the general public, which in turn would help in minimizing loss of life and propert

Diffusion Coefficients Of D-glucose In Aqueous Carboxymethylcellulose And Carboxypolymethylene Solutions

A micro interferometric method was used to determine pseudo-binary, molecular diffusion coefficients for diffusion of D-glucose in aqueous carboxymethylcellulose (CMC) and aqueous carboxypolymethylene (Carbopol) solutions. An initial solute concentration of about 9 wt. % D-glucose in the aqueous polymer solutions was used. The polymer concentrations for the CMC solutions ranged from 1.2 to 2.2 wt. % and for the Carbopol solutions from 0.18 to 0.28 wt. %. Diffusion coefficients were determined as a function of reduced solute concentration, both with and without the effect of solution volume change during diffusion being considered. © 1969, American Chemical Society. All rights reserved

New limits on top squark NLSP from ATLAS 4.7 fb−1fb^{-1} data

Using the ATLAS 4.7 $fb^{-1}$ data on new physics search in the jets + \met channel, we obtain new limits on the lighter top squark ($\tilde t_1$) considering all its decay modes assuming that it is the next to lightest supersymmetric particle (NLSP). If the decay \lstop \ra c \lspone dominates and the production of dark matter relic density is due to NLSP - LSP co-annihilation then the lower limit on \mlstop is 240 GeV. The limit changes to 200 GeV if the decay \lstop \ra b W \lspone dominates. Combining these results it follows that \lstop NLSP induced baryogenesis is now constrained more tightly.Comment: 9 pages, 2 figures, published in MPL