15,687 research outputs found
Insights into the Structure of Dot@Rod and Dot@Octapod CdSe@CdS Heterostructures
CdSe@CdS dot@rods with diameter around 6 nm and length of either
20, 27, or 30 nm and dot@octapods with pod diameters of ?15 nm and lengths of ?50
nm were investigated by X-ray absorption spectroscopy. These heterostructures are
prepared by seed-mediated routes, where the structure, composition, and morphology of
the CdSe nanocrystals used as a seed play key roles in directing the growth of the second
semiconducting domain. The local structural environment of all the elements in the
CdSe@CdS heterostructures was investigated at the Cd, S, and Se K-edges by taking
advantage of the selectivity of X-ray absorption spectroscopy, and was compared to pure
reference compounds. We found that the structural features of dot@rods are
independent of the size of the rods. These structures can be described as made of a
CdSe dot and a CdS rod, both in the wurtzite phase with a high crystallinity of both the
core and the rod. This result supports the effectiveness of high temperature colloidal
synthesis in promoting the formation of core@shell nanocrystals with very low
defectivity. On the other hand, data on the CdSe@CdS with octapod morphology suggest the occurrence of a core composed of
a CdSe cubic sphalerite phase with eight pods made of CdS wurtzite phase. Our findings are compared to current models
proposed for the design of functional heterostructures with controlled nanoarchitecture
Cancellation of vorticity in steady-state non-isentropic flows of complex fluids
In steady-state non-isentropic flows of perfect fluids there is always
thermodynamic generation of vorticity when the difference between the product
of the temperature with the gradient of the entropy and the gradient of total
enthalpy is different from zero. We note that this property does not hold in
general for complex fluids for which the prominent influence of the material
substructure on the gross motion may cancel the thermodynamic vorticity. We
indicate the explicit condition for this cancellation (topological transition
from vortex sheet to shear flow) for general complex fluids described by
coarse-grained order parameters and extended forms of Ginzburg-Landau energies.
As a prominent sample case we treat first Korteweg's fluid, used commonly as a
model of capillary motion or phase transitions characterized by diffused
interfaces. Then we discuss general complex fluids. We show also that, when the
entropy and the total enthalpy are constant throughout the flow, vorticity may
be generated by the inhomogeneous character of the distribution of material
substructures, and indicate the explicit condition for such a generation. We
discuss also some aspects of unsteady motion and show that in two-dimensional
flows of incompressible perfect complex fluids the vorticity is in general not
conserved, due to a mechanism of transfer of energy between different levels.Comment: 12 page
Larval anatomy of Dendropsophus decipiens (A. Lutz 1925) (Anura: Hylidae: Dendropsophini) with considerations to larvae of this genus
The Dendropsophus decipiens clade comprises four species: D. berthalutzae, D. decipiens, D. haddadi, and D. oliveirai. Tadpoles of these species were described, but data on their internal morphology are lacking. We provide the first description of the buccopharyngeal anatomy, chondrocranial morphology, and cranial, hyoid and hyobranchial musculature of the tadpole of D. decipiens. Larvae of D. decipiens are characterized by the absence of lingual papillae, presence of fan-like papilla on the buccal floor, presence of a single-element suprarostral cartilage, presence of a small triangular process at the basis of the processus muscularis, m. levator mandibulae lateralis inserted on the nasal sac, and m. subarcualis rectus II-IV with a single, continuous slip. Tadpoles are likely macrophagous, although not as specialized as those of other species of the genus, suggesting some degree of diversification on the feeding habits within Dendropsophus.Fil: Dias, Pedro H. S.. Universidade de Sao Paulo; BrasilFil: de Araujo Vieira, Katyuscia. Consejo Nacional de Investigaciones CientÃficas y Técnicas. Oficina de Coordinación Administrativa Parque Centenario. Museo Argentino de Ciencias Naturales "Bernardino Rivadavia"; ArgentinaFil: de Carvalho-e-Silva, Ana Maria P. T.. Universidade Federal do Rio de Janeiro; BrasilFil: Orrico, Victor G. D.. Universidade Estadual de Santa Cruz; Brasi
New results on rewrite-based satisfiability procedures
Program analysis and verification require decision procedures to reason on
theories of data structures. Many problems can be reduced to the satisfiability
of sets of ground literals in theory T. If a sound and complete inference
system for first-order logic is guaranteed to terminate on T-satisfiability
problems, any theorem-proving strategy with that system and a fair search plan
is a T-satisfiability procedure. We prove termination of a rewrite-based
first-order engine on the theories of records, integer offsets, integer offsets
modulo and lists. We give a modularity theorem stating sufficient conditions
for termination on a combinations of theories, given termination on each. The
above theories, as well as others, satisfy these conditions. We introduce
several sets of benchmarks on these theories and their combinations, including
both parametric synthetic benchmarks to test scalability, and real-world
problems to test performances on huge sets of literals. We compare the
rewrite-based theorem prover E with the validity checkers CVC and CVC Lite.
Contrary to the folklore that a general-purpose prover cannot compete with
reasoners with built-in theories, the experiments are overall favorable to the
theorem prover, showing that not only the rewriting approach is elegant and
conceptually simple, but has important practical implications.Comment: To appear in the ACM Transactions on Computational Logic, 49 page
Chaos and Synchronized Chaos in an Earthquake Model
We show that chaos is present in the symmetric two-block Burridge-Knopoff
model for earthquakes. This is in contrast with previous numerical studies, but
in agreement with experimental results. In this system, we have found a rich
dynamical behavior with an unusual route to chaos. In the three-block system,
we see the appearance of synchronized chaos, showing that this concept can have
potential applications in the field of seismology.Comment: To appear in Physical Review Letters (13 pages, 6 figures
- …