9,954 research outputs found

    Bimodules over Cartan MASAs in von Neumann Algebras, Norming Algebras, and Mercer's Theorem

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    In a 1991 paper, R. Mercer asserted that a Cartan bimodule isomorphism between Cartan bimodule algebras A_1 and A_2 extends uniquely to a normal *-isomorphism of the von Neumann algebras generated by A_1 and A_2 [13, Corollary 4.3]. Mercer's argument relied upon the Spectral Theorem for Bimodules of Muhly, Saito and Solel [15, Theorem 2.5]. Unfortunately, the arguments in the literature supporting [15, Theorem 2.5] contain gaps, and hence Mercer's proof is incomplete. In this paper, we use the outline in [16, Remark 2.17] to give a proof of Mercer's Theorem under the additional hypothesis that the given Cartan bimodule isomorphism is weak-* continuous. Unlike the arguments contained in [13, 15], we avoid the use of the Feldman-Moore machinery from [8]; as a consequence, our proof does not require the von Neumann algebras generated by the algebras A_i to have separable preduals. This point of view also yields some insights on the von Neumann subalgebras of a Cartan pair (M,D), for instance, a strengthening of a result of Aoi [1]. We also examine the relationship between various topologies on a von Neumann algebra M with a Cartan MASA D. This provides the necessary tools to parametrize the family of Bures-closed bimodules over a Cartan MASA in terms of projections in a certain abelian von Neumann algebra; this result may be viewed as a weaker form of the Spectral Theorem for Bimodules, and is a key ingredient in the proof of our version of Mercer's theorem. Our results lead to a notion of spectral synthesis for weak-* closed bimodules appropriate to our context, and we show that any von Neumann subalgebra of M which contains D is synthetic. We observe that a result of Sinclair and Smith shows that any Cartan MASA in a von Neumann algebra is norming in the sense of Pop, Sinclair and Smith.Comment: 21 pages, paper is a completely reworked and expanded version of an earlier preprint with a similar titl

    Trends in wintertime climate in the northeastern United States: 1965–2005

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    Humans experience climate variability and climate change primarily through changes in weather at local and regional scales. One of the most effective means to track these changes is through detailed analysis of meteorological data. In this work, monthly and seasonal trends in recent winter climate of the northeastern United States (NE-US) are documented. Snow cover and snowfall are important components of the region\u27s hydrological systems, ecosystems, infrastructure, travel safety, and winter tourism and recreation. Temperature, snowfall, and snow depth data were collected from the merged United States Historical Climate Network (USHCN) and National Climatic Data Center Cooperative Network (COOP) data set for the months of December through March, 1965–2005. Monthly and seasonal time series of snow-covered days (snow depth \u3e2.54 cm) are constructed from daily snow depth data. Spatial coherence analysis is used to address data quality issues with daily snowfall and snow depth data, and to remove stations with nonclimatic influences from the regional analysis. Monthly and seasonal trends in mean, minimum, and maximum temperature, total snowfall, and snow-covered days are evaluated over the period 1965–2005, a period during which global temperature records and regional indicators exhibit a shift to warmer climate conditions. NE-US regional winter mean, minimum, and maximum temperatures are all increasing at a rate ranging from 0.42° to 0.46°C/decade with the greatest warming in all three variables occurring in the coldest months of winter (January and February). The regional average reduction in number of snow-covered days in winter (−8.9 d/decade) is also greatest during the months of January and February. Further analysis with additional regional climate modeling is required to better investigate the causal link between the increases in temperature and reduction in snow cover during the coldest winter months of January and February. In addition, regionally averaged winter snowfall has decreased by about 4.6 cm/decade, with the greatest decreases in snowfall occurring in December and February. These results have important implications for the impacts of regional climate change on the northeastern United States hydrology, natural ecosystems, and economy

    Stability and placement of Ag/AgCl quasi-reference counter electrodes in confined electrochemical cells

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    Nanoelectrochemistry is an important and growing branch of electrochemistry that encompasses a number of key research areas, including (electro)catalysis, energy storage, biomedical/environmental sensing, and electrochemical imaging. Nanoscale electrochemical measurements are often performed in confined environments over prolonged experimental time scales with nonisolated quasi-reference counter electrodes (QRCEs) in a simplified two-electrode format. Herein, we consider the stability of commonly used Ag/AgCl QRCEs, comprising an AgCl-coated wire, in a nanopipet configuration, which simulates the confined electrochemical cell arrangement commonly encountered in nanoelectrochemical systems. Ag/AgCl QRCEs possess a very stable reference potential even when used immediately after preparation and, when deployed in Cl– free electrolyte media (e.g., 0.1 M HClO4) in the scanning ion conductance microscopy (SICM) format, drift by only ca. 1 mV h–1 on the several hours time scale. Furthermore, contrary to some previous reports, when employed in a scanning electrochemical cell microscopy (SECCM) format (meniscus contact with a working electrode surface), Ag/AgCl QRCEs do not cause fouling of the surface (i.e., with soluble redox byproducts, such as Ag+) on at least the 6 h time scale, as long as suitable precautions with respect to electrode handling and placement within the nanopipet are observed. These experimental observations are validated through finite element method (FEM) simulations, which consider Ag+ transport within a nanopipet probe in the SECCM and SICM configurations. These results confirm that Ag/AgCl is a stable and robust QRCE in confined electrochemical environments, such as in nanopipets used in SICM, for nanopore measurements, for printing and patterning, and in SECCM, justifying the widespread use of this electrode in the field of nanoelectrochemistry and beyond

    Truthmakers and modality

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    This paper attempts to locate, within an actualist ontology, truthmakers for modal truths: truths of the form or . In section 1 I motivate the demand for substantial truthmakers for modal truths. In section 2 I criticise Armstrong’s account of truthmakers for modal truths. In section 3 I examine essentialism and defend an account of what makes essentialist attributions true, but I argue that this does not solve the problem of modal truth in general. In section 4 I discuss, and dismiss, a theistic account of the source of modal truth proposed by Alexander Pruss. In section 5 I offer a means of (dis)solving the problem

    Shaped nozzles for cryogenic buffer gas beam sources

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    Cryogenic buffer gas beams are important sources of cold molecules. In this work we explore the use of a converging-diverging nozzle with a buffer-gas beam. We find that, under appropriate circumstances, the use of a nozzle can produce a beam with improved collimation, lower transverse temperatures, and higher fluxes per solid angle
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