Structure and electronic properties of porous manganese oxides.

Manganese oxides with varying pore sizes from ~2 to ~7 have been prepared by standard solid-state techniques and by low temperature hydrothermal methods. These materials have an open framework composed exclusively of manganese oxide, which in simple tunnel and layered structures is built up exclusively of edge and corner shared MnO6 octahedra. In more complex structures, such as that exhibited by Na0.44MnO2, this framework is built up of MnO6 octahedra and MnO5 square pyramids, where Mn3+ and Mn4+ are ordered on crystallographically distinct sites. The size of the tunnels or layer gap is dependent on the size of the cation used as a template. This thesis shows that it is possible to remove the 'template' ion from within many framework materials without destroying the structural integrity, this is due primarily to the ready conversion between the various manganese oxidation states to maintain charge balance. This makes it possible to tune the properties by incorporating varying amounts of foreign cations and/or small molecules into the vacant pore sites. These intercalation reactions result in small changes in the average manganese oxidation state, which in turn leads to differences in the thermal stability, observed magnetic and transport properties. We have also shown that it is possible to intercalate conducting polymers into the framework of some layered materials. Whilst the mechanism is not known, it can be seen that the oxidation state of the framework plays an important part in the ordering of the monomer/polymer units within the layers. Incorporation of these polymers leads to large changes in the magnitude of the observed magnetic moment as well as in the magnetic ordering. This work shows that these materials have a versatile framework, which leads to the real possibility of tuning the properties of a material to achieve desired effects leading to many possible uses for these types of materials

Considerations and future perspectives for the vibrational spectroscopic analysis of forensic cosmetic evidence

Cosmetics such as makeup or other personal products are widely used and easily transferred upon physical contact. As such, they may be used as trace evidence to link people to each other or to places in criminal investigations. To maximize their probative value, it is important to understand the variability among representative market products and the way in which they transfer to, or persist on various surfaces. Additionally, it is required that analysis techniques be non-destructive, readily available and relatively inexpensive. Raman spectroscopy and attenuated total reflectance--Fourier transform infrared (ATR-FTIR) are powerful tools for probing the chemistry of trace cosmetics. As well as fitting the criteria above, they offer the capability of studying a wide range of sample types with minimal prior preparation. The complementary information derived from these techniques can help analysts to understand and visualize spectral variability, potentially enabling discrimination between samples. However, the move from academic research toward forensic casework is not without challenges. In this article, we provide a focused exploration of the current state-of-the-art in forensic cosmetic research; providing context for how we may begin to address these challenges to more effectively exploit cosmetic traces for criminal investigation. This article is categorized under: Forensic Chemistry and Trace Evidence > Emerging Technologies and Methods Forensic Chemistry and Trace Evidence > Trace Evidenc

Transverse-mode selection of rotating mirror Q-switched lasers

The TEMoo-mode has been selected in a rotating-mirror Q-switched Nd3+:CaWO4 laser by insertion of a slit and an edge into the resonator. Shot-to-shot repeatability was enhanced, and multiple pulsing was suppressed. The same technique has been successfully applied to a CO2 laser

African economic development : possible model and role of a new multilateral organization

M.I.T. Center for International Development handwritten on title page"International Cooperation Administration Conference of Mission Directors and Program Staffs, African and European Area, December 12, 1957, Washington, D.C.""African Project.""L2-699"--handwritten on coverIncludes bibliographical reference

A novel mouse model of in situ stenting

AIMS: Animal models of stenting are mostly limited to larger animals or involve substantial abdominal surgery in rodents. We aimed to develop a simple, direct model of murine stenting. METHODS AND RESULTS: We designed a miniature, self-expanding, nitinol wire coil stent that was pre-loaded into a metal stent sheath. This was advanced into the abdominal aorta of the mouse, via femoral access, and the stent deployed. In-stent restenosis was investigated at 1, 3, 7, and 28 days post-stenting. The model was validated by investigation of neointima formation in mice deficient in signalling via the interleukin-1 receptor (IL-1R1), compared with other injury models. Ninety-two per cent of mice undergoing the procedure were successfully stented. All stented vessels were patent. Inflammatory cells were seen in the adventitia and around the stent strut up to 3 days post-stenting. At 3 days, an early neointima was present, building to a mature neointima at 28 days. In mice lacking IL-1R1, the neointima was 64% smaller than that in wild-type controls at the 28-day timepoint, in agreement with other models. CONCLUSION: This is the first description of a successful model of murine in situ stenting, using a stent specifically tailored for use in small thin-walled arteries. The procedure can be undertaken by a single operator without the need for an advanced level of microsurgical skill and is reliable and reproducible. The utility of this model is demonstrated by a reduction in in-stent restenosis in IL-1R1-deficient mice

An adaptive inelastic magnetic mirror for Bose-Einstein condensates

We report the reflection and focussing of a Bose-Einstein condensate by a new pulsed magnetic mirror. The mirror is adaptive, inelastic, and of extremely high optical quality. The deviations from specularity are less than 0.5 mrad rms, making this the best atomic mirror demonstrated to date. We have also used the mirror to realize the analog of a beam-expander, producing an ultra-cold collimated fountain of matter wavesComment: 4 pages, 4 figure

The internal structure of a debris-covered glacier on Mars revealed by gully incision

Viscous flow features (VFFs) in Mars' mid latitudes are analogous to debris-covered glaciers on Earth. They have complex, often curvilinear patterns on their surfaces, which probably record histories of ice flow. As is the case for glaciers on Earth, patterns on the surfaces of VFFs are likely to reflect complexities in their subsurface structure. Until now, orbital observations of VFF-internal structures have remained elusive. We present observations of internal structures within a small, kilometer-scale VFF in the Nereidum Montes region of Mars' southern mid latitudes, using images from the Context Camera (CTX) and High Resolution Imaging Science Experiment (HiRISE) instruments on Mars Reconnaissance Orbiter. The VFF-internal structures are revealed by a gully incision, which extends from the VFF headwall to its terminus and intersects curvilinear undulations and a crevasse field on the VFF surface. Near to the VFF terminus, the curvilinear VFF-surface undulations connect to the VFF-internal layers, which are inclined and extend down to the VFF's deep interior, and possibly all the way to the bed. Similar structures are common near to the termini of glaciers on Earth; they form under ice flow compression where ice thins and slows approaching the ice margin, and ice flow is forced up towards the surface. We performed 3D ice flow modeling which supports this analogy, revealing that the inclined VFF-internal structures, and associated curvilinear structures on the VFF surface, are located in a zone of strong ice flow compression where ice flow deviates upwards away from the bed. The inclined VFF-internal structures we observe could represent up-warped VFF-internal layering transported up to the surface from the VFF's deep interior, or thrust structures representing debris transport pathways between the VFF's bed and its surface. Our observations raise numerous considerations for future surface missions targeting Mars' mid-latitude subsurface ice deposits. Inclined layers formed under flow compression could reduce the requirement for high-cost, high-risk deep drilling to address high-priority science questions. They could allow futures missions to (a) access ice age sequences for palaeoenvironmental reconstruction via shallow sampling along transects of ice surfaces where layers of progressively older age outcrop, and/or (b) access samples of ice/lithics transported to shallow/surface positions from environments of astrobiological interest at/near glacier beds. However, our observations also raise considerations for potential drilling hazards associated with structural complexities and potential dust/debris layers within subsurface ice deposits on Mars. They highlight the importance of characterizing VFF-surface structures, and their relationships to VFF-internal structure and ice flow histories ahead of ice access missions to Mars

Computer‐aided photo‐identification of a rare stingray, Megatrygon microps

We have defined protocol for photo‐identification to identify individual Megatrygon microps. 104 identification photographs were taken between 2005 and 2019. Spot patterns on the dorsal surface were used to identify individuals. Unique scarring on 8 re‐observed M. microps provided an independent confirmation of pattern stability of up to 761 days. Previously, studies have lacked statistical testing to validate photo‐identification approach. The I3S photo‐matching software was proven to successfully match images, identifying 69 individuals. A photo‐matching software facilitates an open‐source platform for identifying individual M. microps, allowing for better population assessments

Geometrothermodynamics of black holes

The thermodynamics of black holes is reformulated within the context of the recently developed formalism of geometrothermodynamics. This reformulation is shown to be invariant with respect to Legendre transformations, and to allow several equivalent representations. Legendre invariance allows us to explain a series of contradictory results known in the literature from the use of Weinhold's and Ruppeiner's thermodynamic metrics for black holes. For the Reissner-Nordstr\"om black hole the geometry of the space of equilibrium states is curved, showing a non trivial thermodynamic interaction, and the curvature contains information about critical points and phase transitions. On the contrary, for the Kerr black hole the geometry is flat and does not explain its phase transition structure.Comment: Revised version, to be published in Gen.Rel.Grav.(Mashhoon's Festschrift

Minimum Energy Configurations in the NN-Body Problem and the Celestial Mechanics of Granular Systems

Minimum energy configurations in celestial mechanics are investigated. It is shown that this is not a well defined problem for point-mass celestial mechanics but well-posed for finite density distributions. This naturally leads to a granular mechanics extension of usual celestial mechanics questions such as relative equilibria and stability. This paper specifically studies and finds all relative equilibria and minimum energy configurations for $N=1,2,3$ and develops hypotheses on the relative equilibria and minimum energy configurations for $N\gg 1$ bodies.Comment: Accepted for publication in Celestial Mechanics and Dynamical Astronom