5,049 research outputs found
Charge transfer and weak bonding between molecular oxygen and graphene zigzag edges at low temperatures
Electron paramagnetic resonance (EPR) study of air-physisorbed defective
carbon nano-onions evidences in favor of microwave assisted formation of
weakly-bound paramagnetic complexes comprising negatively-charged O2- ions and
edge carbon atoms carrying pi-electronic spins. These complexes being located
on the graphene edges are stable at low temperatures but irreversibly
dissociate at temperatures above 50-60 K. These EPR findings are justified by
density functional theory (DFT) calculations demonstrating transfer of an
electron from the zigzag edge of graphene-like material to oxygen molecule
physisorbed on the graphene sheet edge. This charge transfer causes changing
the spin state of the adsorbed oxygen molecule from S = 1 to S = 1/2 one. DFT
calculations show significant changes of adsorption energy of oxygen molecule
and robustness of the charge transfer to variations of the graphene-like
substrate morphology (flat and corrugated mono- and bi-layered graphene) as
well as edges passivation. The presence of H- and COOH- terminated edge carbon
sites with such corrugated substrate morphology allows formation of ZE-O2-
paramagnetic complexes characterized by small (<50 meV) binding energies and
also explains their irreversible dissociation as revealed by EPR.Comment: 28 pages, 8 figures, 2 tables, accepted in Carbon journa
Persistent Currents in the Presence of a Transport Current
We have considered a system of a metallic ring coupled to two electron
reservoirs. We show that in the presence of a transport current, the persistent
current can flow in a ring, even in the absence of magnetic field. This is
purely a quantum effect and is related to the current magnification in the
loop. These persistent currents can be observed if one tunes the Fermi energy
near the antiresonances of the total transmission coefficient or the two port
conductance.Comment: To appear in Phys. Rev. B. Three figures available on reques
Observation of Magnetic Edge State and Dangling Bond State on Nanographene in Activated Carbon Fibers
The electronic structure of nanographene in pristine and fluorinated
activated carbon fibers (ACFs) have been investigated with near-edge x-ray
absorption fine structure (NEXAFS) and compared with magnetic properties we
reported on previously. In pristine ACFs in which magnetic properties are
governed by non-bonding edge states of the \pi-electron, a pre-peak assigned to
the edge state was observed below the conduction electron {\pi}* peak close to
the Fermi level in NEXAFS. Via the fluorination of the ACFs, an extra peak,
which was assigned to the \sigma-dangling bond state, was observed between the
pre-peak of the edge state and the {\pi}* peak in the NEXAFS profile. The
intensities of the extra peak correlate closely with the spin concentration
created upon fluorination. The combination of the NEXAFS and magnetic
measurement results confirms the coexistence of the magnetic edge states of
\pi-electrons and dangling bond states of \sigma-electrons on fluorinated
nanographene sheets.Comment: 4 figures, to appear in Phys. Rev.
Conductance and persistent current of a quantum ring coupled to a quantum wire under external fields
The electronic transport of a noninteracting quantum ring side-coupled to a
quantum wire is studied via a single-band tunneling tight-binding Hamiltonian.
We found that the system develops an oscillating band with antiresonances and
resonances arising from the hybridization of the quasibound levels of the ring
and the coupling to the quantum wire. The positions of the antiresonances
correspond exactly to the electronic spectrum of the isolated ring. Moreover,
for a uniform quantum ring the conductance and the persistent current density
were found to exhibit a particular odd-even parity related with the ring-order.
The effects of an in-plane electric field was also studied. This field shifts
the electronic spectrum and damps the amplitude of the persistent current
density. These features may be used to control externally the energy spectra
and the amplitude of the persistent current.Comment: Revised version, 7 pages and 9 figures. To appear in Phys. Rev.
Novel electronic wave interference patterns in nanographene sheets
Superperiodic patterns with a long distance in a nanographene sheet observed
by STM are discussed in terms of the interference of electronic wave functions.
The period and the amplitude of the oscillations decrease spatially in one
direction. We explain the superperiodic patterns with a static linear potential
theoretically. In the k-p model, the oscillation period decreases, and agrees
with experiments. The spatial difference of the static potential is estimated
as 1.3 eV for 200 nm in distance, and this value seems to be reasonable in
order that the potential difference remains against perturbations, for example,
by phonon fluctuations and impurity scatterings. It turns out that the
long-distance oscillations come from the band structure of the two-dimensional
graphene sheet.Comment: Published as a LETTER in J. Phys.: Condens. Matter; 8 pages; 6
figures; Online version at
http://www.iop.org/EJ/S/3/1256/0hJAmc5sCL6d.7sOO.BtLw/abstract/0953-8984/14/3
6/10
Metacarpophalangeal pattern profile analysis of a sample drawn from a North Wales population
This is tha author's PDF version of an article published in Annals of human biology© 2001. The definitive version is available at http://www.tandf.co.uk/journalsSexual dimorphism and population differences were investigated using metacarpophalangeal pattern profile (MCPP) analysis. Although it is an anthropmetric technique, MCPP analysis is more frequently used in genetic syndrome analysis and has been under-used in the study of human groups. The present analysis used a series of hand radiographics from Gwynedd, North Wales, to make comparisons, first, between the sexes within the sample and then with previously reported data from Japan. The Welsh sexes showed MCPP analyses that indicated size and shape differences but certain similarities in shape were also evident. Differences with the Japanese data were more marked. MCPP anlysis is a potentially useful anthropmetric technique but requires further statistical development
On the Lipschitz continuity of spectral bands of Harper-like and magnetic Schroedinger operators
We show for a large class of discrete Harper-like and continuous magnetic
Schrodinger operators that their band edges are Lipschitz continuous with
respect to the intensity of the external constant magnetic field. We generalize
a result obtained by J. Bellissard in 1994, and give examples in favor of a
recent conjecture of G. Nenciu.Comment: 15 pages, accepted for publication in Annales Henri Poincar
See What You Feel: A Crossmodal Tool for Measuring Haptic Size Illusions
The purpose of this research is to present the employment of a simple-to-use crossmodal method for measuring haptic size illusions. The method, that we call See what you feel, was tested by employing Uznadze’s classic haptic aftereffect in which two spheres physically identical (test spheres) appear different in size after that the hands holding them underwent an adaptation session with other two spheres (adapting spheres), one bigger and the other smaller than the two test spheres. To measure the entity of the illusion, a three-dimensional visual scale was created and participants were asked to find on it the spheres that corresponded in size to the spheres they were holding in their hands out of sight. The method, tested on 160 right-handed participants, is robust and easily understood by participants
Magneto-transport in periodic and quasiperiodic arrays of mesoscopic rings
We study theoretically the transmission properties of serially connected
mesoscopic rings threaded by a magnetic flux. Within a tight-binding formalism
we derive exact analytical results for the transmission through periodic and
quasiperiodic Fibonacci arrays of rings of two different sizes. The role played
by the number of scatterers in each arm of the ring is analyzed in some detail.
The behavior of the transmission coefficient at a particular value of the
energy of the incident electron is studied as a function of the magnetic flux
(and vice versa) for both the periodic and quasiperiodic arrays of rings having
different number of atoms in the arms. We find interesting resonance properties
at specific values of the flux, as well as a power-law decay in the
transmission coefficient as the number of rings increases, when the magnetic
field is switched off. For the quasiperiodic Fibonacci sequence we discuss
various features of the transmission characteristics as functions of energy and
flux, including one special case where, at a special value of the energy and in
the absence of any magnetic field, the transmittivity changes periodically as a
function of the system size.Comment: 9 pages with 7 .eps figures included, submitted to PR
Habitable Climates: The Influence of Eccentricity
In the outer regions of the habitable zone, the risk of transitioning into a
globally frozen "snowball" state poses a threat to the habitability of planets
with the capacity to host water-based life. We use a one-dimensional energy
balance climate model (EBM) to examine how obliquity, spin rate, orbital
eccentricity, and ocean coverage might influence the onset of such a snowball
state. For an exoplanet, these parameters may be strikingly different from the
values observed for Earth. Since, for constant semimajor axis, the annual mean
stellar irradiation scales with (1-e^2)^(-1/2), one might expect the greatest
habitable semimajor axis (for fixed atmospheric composition) to scale as
(1-e^2)^(-1/4). We find that this standard ansatz provides a reasonable lower
bound on the outer boundary of the habitable zone, but the influence of
obliquity and ocean fraction can be profound in the context of planets on
eccentric orbits. For planets with eccentricity 0.5, our EBM suggests that the
greatest habitable semimajor axis can vary by more than 0.8 AU (78%!) depending
on obliquity, with higher obliquity worlds generally more stable against
snowball transitions. One might also expect that the long winter at an
eccentric planet's apoastron would render it more susceptible to global
freezing. Our models suggest that this is not a significant risk for Earth-like
planets around Sun-like stars since such planets are buffered by the thermal
inertia provided by oceans covering at least 10% of their surface. Since
planets on eccentric orbits spend much of their year particularly far from the
star, such worlds might turn out to be especially good targets for direct
observations with missions such as TPF-Darwin. Nevertheless, the extreme
temperature variations achieved on highly eccentric exo-Earths raise questions
about the adaptability of life to marginally or transiently habitable
conditions.Comment: References added, text and figures updated, accepted by Ap
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