Coefficient of thermal expansion of nanostructured tungsten based coatings assessed by thermally induced substrate curvature method

The in plane coefficient of thermal expansion (CTE) and the residual stress of nanostructured W based coatings are extensively investigated. The CTE and the residual stresses are derived by means of an optimized ad-hoc developed experimental setup based on the detection of the substrate curvature by a laser system. The nanostructured coatings are deposited by Pulsed Laser Deposition. Thanks to its versatility, nanocrystalline W metallic coatings, ultra-nano-crystalline pure W and W-Tantalum coatings and amorphous-like W coatings are obtained. The correlation between the nanostructure, the residual stress and the CTE of the coatings are thus elucidated. We find that all the samples show a compressive state of stress that decreases as the structure goes from columnar nanocrystalline to amorphous-like. The CTE of all the coatings is higher than the one of the corresponding bulk W form. In particular, as the grain size shrinks, the CTE increases from 5.1 10$^{-6}$ K$^{-1}$ for nanocrystalline W to 6.6 10$^{-6}$ K$^{-1}$ in the ultra-nano-crystalline region. When dealing with amorphous W, the further increase of the CTE is attributed to a higher porosity degree of the samples. The CTE trend is also investigated as function of materials stiffness. In this case, as W coatings become softer, the easier they thermally expand.Comment: The research leading to these results has also received funding from the European Research Council Consolidator Grant ENSURE (ERC-2014-CoG No. 647554

Thermomechanical properties of amorphous metallic tungsten-oxygen and tungsten-oxide coatings

In this work, we investigate the correlation between morphology, composition, and the mechanical properties of metallic amorphous tungsten-oxygen and amorphous tungsten-oxide films deposited by Pulsed Laser Deposition. This correlation is investigated by the combined use of Brillouin Spectroscopy and the substrate curvature method. The stiffness of the films is strongly affected by both the oxygen content and the mass density. The elastic moduli show a decreasing trend as the mass density decreases and the oxygen-tungsten ratio increases. A plateaux region is detected in correspondence of the transition between metallic and oxide films. The compressive residual stresses, moderate stiffness and high local ductility that characterize compact amorphous tungsten-oxide films make them promising for applications involving thermal or mechanical loads. The coefficient of thermal expansion is quite high (i.e. 8.9 $\cdot$ 10$^{-6}$ K$^{-1}$), being strictly correlated to the amorphous structure and stoichiometry of the films. Under thermal treatments they show a quite low relaxation temperature (i.e. 450 K). They crystallize into the $\gamma$ monoclinic phase of WO$_3$ starting from 670 K, inducing an increase by about 70\% of material stiffness.Comment: The research leading to these results has also received funding from the European Research Council Consolidator Grant ENSURE (ERC-2014-CoG No. 647554). The views and opinions expressed herein do not necessarily reflect those of the European Commissio

Low-Cost Uas Photogrammetry for Road Infrastructures' Inspection

Abstract. All over the world, road infrastructures are getting closer to their life cycle and need to be constantly inspected: a consistent number of bridges are structurally deficient, and the risk of collapse can no longer be excluded. In contrast with the past, the interest in structure durability has recently grown rapidly. In order to make bridges durable, it is necessary to carry out ordinary maintenance, preceded by inspection activities, which can be traditionally divided in two categories: destructive and non-destructive (NDT). All the NDT inspections (visual, IR thermography, GPR) can be conducted by using UAS (Unmanned Aerial Systems), a technology that makes bridges inspections quicker, cheaper, objective and repeatable. This study presents the visual inspection and survey of two bridges by using a UAS DJI Mavic 2 Pro, equipped with a 20Mpixel Hasselblad camera that records 60fps 4K video and a 10bit radiometric resolution. Starting from the acquired data, a 3D model of each structure was built by using Structure from Motion (SfM) principles and software. To validate the two models, each of them characterized by a centimetric accuracy, the UAS camera generated cloud of points and was co-registered with the point cloud of a terrestrial laser-scanner using Ground Control Points (GCPs). To make this, CloudCompare comparison software was used; the plugin M3C2 automatically calculates the distance between the points of two compared clouds. Finally, some general rules concerning the UAS main characteristics for inspection of bridges and software for data processing are proposed

U.ph.o and mago: Two useful instruments in support of photogrammetric uav survey

In emergency and critical scenarios, the UAV could play a key role in accessing unreachable sites in a safe and rapid way, guaranteeing at the same time the necessary accuracy and precision of the survey. In this context, UAV survey campaigns have been performed by the authors in Norcia (Italy), hit by tragic seismic events in August and October 2016. The surveys were motivated by the artistic and historical value of monuments, the need to plan and design the restoring and retrofitting of buildings, and also to quantify and manage the ruins. Goal of such surveys was the description of the structures geometry with a centimetric precision and a high level of reliability. Recently, the authors have conceived two tools, U.Ph.O (Unmanned Photogrammetric Office) and MAGO (Adaptive Mesh for Orthophoto Generation), dedicated to the planning and restitution phases of the survey, respectively. U.Ph.O. and MAGO are here applied to two different buildings in Norcia, i.e. the Civic Tower of Norcia and San Salvatore Church of Campi di Norcia. The former is a standing-out structure, surrounded by the complex of the historical centre, while the latter is located in an isolated site in the countryside. These features make the survey planning and the orthophoto reconstruction completely different, mainly due to the different optimal shooting geometry and the presence or absence of obstructions

Identifying key denning habitat to conserve brown bear (Ursus arctos) in Croatia

CONTEXT: The preservation of denning habitat is paramount to the recovery of threatened bear populations because of the effect that den site disturbance can have on cub mortality. Understanding habitat suitability for denning can allow management efforts to be directed towards the regions where conservation interventions would be most effective. AIM: We sought to identify the environmental and anthropogenic habitat variables associated with the presence of Eurasian brown bear (Ursus arctos) den sites in Croatia. Based on these associations, in order to inform future conservation decisions, we also sought to identify regions of high suitability for denning across Croatia. METHODS: Using the locations of 91 dens inhabited by bears between 1982 and 2011, we opted for the presence-only modelling option in software Maxent to determine the most important predictors of den presence, and thus predict the distribution of high-value denning habitat across Croatia. KEY RESULTS: We found that structural elements were the most important predictors, with ruggedness and elevation both relating positively to den presence. However, distance to nearest settlement was also positively associated with den presence. CONCLUSION: We determine that there is considerable denning habitat value in areas with high and rugged terrain as well as areas with limited human activity. We suspect that high and rugged terrain contains a greater concentration of the karstic formations used for denning than lower-lying regions. IMPLICATIONS: Our study presents the first habitat suitability model for brown bears in Croatia, and identifies core areas suitable for denning both within and outside the species’ current range. As such, it provides useful evidence for conservation decision making and the development of scientifically-based management plans. Our results also support the need for finer spatial scale studies that can reveal specific denning preferences of subpopulations

Laser cleaning of diagnostic mirrors from tokamak-like carbon contaminants

This paper presents a laboratory-scale experimental investigation of laser cleaning of diagnostic First Mirrors (FMs). Redeposition of contaminants sputtered from tokamak first wall onto FMs surface could dramatically decrease their reflectivity in an unacceptable way for the functioning of the plasma diagnostic systems. Laser cleaning is a promising solution to tackle this issue. In this work, pulsed laser deposition was exploited to produce rhodium films functional as FMs and to deposit onto them carbon contaminants with tailored features, resembling those found in tokamaks. The same laser system was also used to perform laser cleaning experiments by means of a sample handling procedure that allows to clean some cm(2) in few minutes. The cleaning effectiveness was evaluated in terms of specular reflectivity recovery and mirror surface integrity. The effect of different laser wavelengths (lambda = 1064, 266 nm) on the cleaning process is also addressed

Bulk Cr tips for scanning tunneling microscopy and spin-polarized scanning tunneling microscopy

A simple, reliable method for preparation of bulk Cr tips for Scanning Tunneling Microscopy (STM) is proposed and its potentialities in performing high-quality and high-resolution STM and Spin Polarized-STM (SP-STM) are investigated. Cr tips show atomic resolution on ordered surfaces. Contrary to what happens with conventional W tips, rest atoms of the Si(111)-7x7 reconstruction can be routinely observed, probably due to a different electronic structure of the tip apex. SP-STM measurements of the Cr(001) surface showing magnetic contrast are reported. Our results reveal that the peculiar properties of these tips can be suited in a number of STM experimental situations

Thermal annealing and exposure to divertor-like deuterium plasma of tailored tungsten oxide coatings

In this work we produced tungsten (W) and W oxide (WOx) films by pulsed laser deposition (PLD) with the aim of the addressing modifications of structure and morphology that occur after annealing treatments and high-flux deuterium plasma. Thanks to the high flexibility of PLD we produced nanostructured W containing non-bounded oxygen, different types of WOx and multilayered films. W coatings are dense, non-porous and exhibit a nanocrystalline structure, resembling the coatings used as first wall in tokamaks. The oxide films are nearly stoichiometric amorphous WOx (x = 3) with different morphology from compact to porous. Depending on annealing temperature, nucleation of different crystalline phases (e.g. WO3, W18O49) occurs. Exposure of films to high-flux (similar to 10(24) m(-2) s(-1)) deuterium plasmas in Magnum-PSI at different surface temperatures (T-max = 580 K) determines material modifications at the nanoscale (e.g. nanometric defects) but no delamination. In addition preliminary deuterium retention results are reported